Phosphor dispersion liquid, and production method for LED device using same

Patent metadata

Field	Value
Publication number	US-9184352-B2
Application number	US-201214349172-A
Country	US
Kind code	B2
Filing date	Oct 5, 2012
Priority date	Oct 7, 2011
Publication date	Nov 10, 2015
Grant date	Nov 10, 2015

Abstract

The purpose is to provide a phosphor particle dispersion liquid in which the phosphor particles do not settle out when the phosphor dispersion liquid is left to stand. The phosphor dispersion liquid contains phosphor particles, clay mineral particles, inorganic particles, and a solvent. The phosphor dispersion liquid has viscosity η1 of 10 to 500 mPa·s at a shear rate of 1000 (1/s) at 25° C., and viscosity η2 of 1.0×10 3 to 1.0×10 5 mPa·s at a shear rate of 1 (1/s) at 25° C.

First claim

The invention claimed is:

1. A phosphor dispersion liquid comprising phosphor particles, clay mineral particles, inorganic particles, and a solvent, the phosphor dispersion liquid having
viscosity η1 of 10 mPa·s to 500 mPa·s at a shear rate of 1,000 (1/s) at 25° C., and
viscosity η2 of 1.0×10 3 mPa·s to 1.0×10 5 mPa·s at a shear rate of 1 (1/s) at 25° C.

2. The phosphor dispersion liquid according to claim 1 , wherein the clay mineral particles are a laminar silicate mineral.

3. The phosphor dispersion liquid according to claim 1 , wherein the solvent includes a monohydric alcohol and a polyol.

4. A method of manufacturing a light emitting devive (LED) device, the LED device including a LED chip and a phosphor layer that covers the LED chip and converts light having a predetermined wavelength emitted from the LED chip into light having another predetermined wavelength, the method comprising:
providing the LED;
applying the phosphor dispersion liquid according to claim 1 on the LED chip;
applying on the LED chip a binder precursor-containing liquid containing a light transmissive binder precursor; and
curing the light transmissive binder precursor.

5. The method according to claim 4 , wherein the light transmissive binder precursor is a light transmissive ceramic precursor.

6. A phosphor dispersion liquid comprising phosphor particles, clay mineral particles, inorganic particles, and a dispersion solvent containing water and an organic solvent, wherein
a content of the water is 0.1 wt % to 4 wt %.

7. The phosphor dispersion liquid according to claim 6 , wherein the phosphor dispersion liquid has a viscosity of 60 mPa·s to 400 mPa·s as measured using a vibration viscometer at 25° C.

8. The phosphor dispersion liquid according to claim 6 , wherein the organic solvent includes a monohydric alcohol and a polyol.

9. A method of manufacturing a light emitting device(LED) chip, comprising:
providing an LED chip; and
forming a phosphor layer by applying the phosphor dispersion liquid according to claim 6 on an emission surface of the LED chip.

10. The method according to claim 9 , further comprising applying a solution including an organometallic compound on the emission surface of the LED chip.

11. The method according to claim 9 , wherein
the phosphor dispersion liquid is applied using a spray applicator, and
the spray applicator includes a coating solution tank for storing therein the phosphor dispersion liquid, a head having a nozzle for discharging the phosphor dispersion liquid, and a connector tube for allowing communication between the coating solution tank and the head.

12. The method according to claim 9 , wherein the LED device is a white LED device.

13. A phosphor dispersion liquid comprising phosphor particles, clay mineral particles, inorganic particles, and a solvent,
the solvent including water,
a content of the water being 0.1 wt % to 4 wt % of a total amount of the phosphor dispersion liquid,
the phosphor dispersion liquid having
viscosity η1 of 10 mPa·s to 500 mPa·s at a shear rate of 1,000 (1/s) at 25° C., and
viscosity η2 of 1.0×10 3 mPa·s to 1.0×10 5 mPa·s at a shear rate of 1 (1/s) at 25° C.

Assignees

• Konica Minolta Inc

Inventors

• Kojima Takeshi

Classifications

• C09K11/025

  non-luminescent particle coatings or suspension media · CPC title

• C09K11/08

  containing inorganic luminescent materials · CPC title

• C09K11/02 Primary

  Use of particular materials as binders, particle coatings or suspension media therefor · CPC title

• H10H20/0361

  of wavelength conversion means · CPC title

• H10H20/8511

  characterised by their material, e.g. binder · CPC title