Processes to produce short-cut microfibers

Patent metadata

Field	Value
Publication number	US-9175440-B2
Application number	US-201414490084-A
Country	US
Kind code	B2
Filing date	Sep 18, 2014
Priority date	Jan 31, 2012
Publication date	Nov 3, 2015
Grant date	Nov 3, 2015

Abstract

A process for producing a microfiber product stream, the process comprises: (A) contacting cut multicomponent fibers having a length of less than 25 millimeters with a treated aqueous stream in a fiber slurry zone to produce a cut multicomponent fiber slurry; (B) contacting the cut multicomponent fiber slurry with a heated aqueous
stream in a mix zone to produce a heated multicomponent fiber slurry; (C) routing the heated multicomponent fiber slurry to a fiber opening zone to remove a portion of the water dispersible sulfopolyester to produce an opened microfiber slurry; wherein the opening zone comprises a pipe reactor; and (D) routing the opened microfiber slurry to a primary solid liquid separation zone to produce the microfiber product stream and a first mother liquor stream.

First claim

That which is claimed is:

1. A process for producing a microfiber product stream, said process comprising:
(A) contacting cut multicomponent fibers having a length of less than 25 millimeters with a treated aqueous stream in a fiber slurry zone to produce a cut multicomponent fiber slurry; wherein said cut multicomponent fibers comprise at least one water dispersible sulfopolyester and at least one water non-dispersible synthetic polymer immiscible with said water dispersible sulfopolyester; and wherein said treated aqueous stream is at a temperature of 40° C. or less;
(B) contacting said cut multicomponent fiber slurry with a heated aqueous stream in a mix zone to produce a heated multicomponent fiber slurry;
(C) routing said heated multicomponent fiber slurry to a fiber opening zone with sufficient mixing to remove a portion of said water dispersible sulfopolyester to produce an opened microfiber slurry with a temperature in the range of about of about 55° C. to about 100° C.; wherein the weight % of solids in said opened microfiber slurry ranges from 0.1 weight % to about 20 weight %; wherein said water non-dispersible polymer microfiber has a minimum transverse dimension of less than 10 microns; wherein said fiber opening zone comprises a pipe reactor;
(D) routing said opened microfiber slurry to a primary solid liquid separation zone to produce said microfiber product stream and a first mother liquor stream; wherein said first mother liquor stream comprises water and said water dispersible sulfopolyester; and
E) routing at least a portion of said first mother liquor stream to a second solid liquid separation zone to produce a secondary wet cake stream and a second mother liquor stream; wherein said second mother liquor stream comprises water and water dispersible sulfopolyester; and wherein said secondary wet cake stream comprises microfiber.

2. A process according to claim 1 wherein said cut multicomponent fibers have a length of less than 5 mm.

3. A process according to claim 1 wherein said heated aqueous stream comprises a treated aqueous stream produced by routing an untreated aqueous stream to an aqueous treatment zone; wherein said treated aqueous stream contains less than 50 ppm of divalent and multivalent cations; and routing said treated aqueous stream to a heat exchanger zone to produce said heated aqueous stream.

4. A process according to claim 1 wherein the weight % of cut multicomponent fibers in said cut multicomponent fiber slurry in said fiber slurry zone ranges from about 35 weight % to about 1 weight %.

5. A process according to claim 1 wherein said fiber slurry zone further comprises at least one piece of equipment selected from the group consisting of a hydro-pulper, a continuous stirred tank reactor, and an agitated batch tank.

6. A process according to claim 1 wherein said mix zone comprises at least one piece of equipment selected from the group consisting of a continuous stirred tank reactor, an agitated batch tank, and a pipe.

7. A process according to claim 1 wherein said heated multicomponent fiber slurry in said mix zone has about 10 weight % to about 1 weight % cut multicomponent fibers.

8. A process according to claim 1 wherein the temperature of said opened microfiber slurry in said fiber opening zone ranges from about 55° C. to about 100° C.

9. A process according to claim 1 wherein said primary solid liquid separation zone comprises at least one piece of equipment selected from the group consisting of perforated basket centrifuges, continuous vacuum belt filters, batch vacuum nutschfilters, batch perforated settling tanks, twin wire dewatering devices, continuous horizontal belt filters with a compressive zone, non vibrating inclined screen devices with wedge wire filter media, continuous vacuum drum filters, and dewatering conveyor belts.

10. A process according to claim 1 wherein the weight % of solids in said microfiber product stream ranges from about 10 weight % to about 65 weight %.

11. A process according to claim 1 further comprising routing at least a portion of said first mother liquor stream to: a) said fiber slurry zone; b) said mix zone; c) said fiber opening zone; d) a heat exchange zone to produce said heated aqueous stream and routing at least a portion of said heated aqueous stream to said fiber opening zone and/or said mix zone; and/or e) said primary solid liquid separation zone.

12. A process according to claim 1 further comprising routing at least a portion of said second mother liquor stream to a primary concentration zone to produce a primary polymer concentrate stream and a primary recovered water stream.

13. A process according to claim 1 further comprising routing at least a portion of said second mother liquor stream to: a) said fiber slurry zone; b) said mix zone; c) said fiber opening zone; d) a heat exchange zone to produce said heated aqueous stream and routing at least a portion of said heated aqueous stream to said fiber opening zone and/or said mix zone; and/or e) said primary solid liquid separation zone as a wash stream.

14. A process according to claim 12 further comprising purging said first mother liquor stream, said second mother liquor stream, and/or said primary recovered water stream from the process for reuse or to a wastewater treatment system.

15. A process according to claim 12 further comprising routing said primary recovered water stream to: a) fiber slurry zone; b) said mix zone; c) said fiber opening zone; d) a heat exchange zone to produce said heated aqueous stream and routing at least a portion of said heated aqueous stream to said fiber opening zone and/or said mix zone; and/or e) said primary solid liquid separation zone as a wash stream.

16. A process according to claim 12 further comprising routing at least a portion of said primary polymer concentrate stream to a secondary concentration zone to produce a vapor stream and a melted polymer stream.

Assignees

• Eastman Chem Co

Inventors

• Parker Kenny Randolph
• Klosiewicz Daniel William
• Munjal Ramesh Chand
• Rogers David J
• Tremaine Dustin A

Classifications

• D21H15/10

  Composite fibres · CPC title

• C08G63/6886

  Dicarboxylic acids and dihydroxy compounds · CPC title

• D21H21/18

  Reinforcing agents · CPC title

• D21H13/24 Primary

  Polyesters · CPC title

• B01D11/0288

  Applications, solvents · CPC title