High uptake sulfur solvent systems and methods for making and using same

Patent metadata

Field	Value
Publication number	US-9169717-B2
Application number	US-201213669787-A
Country	US
Kind code	B2
Filing date	Nov 6, 2012
Priority date	Nov 6, 2012
Publication date	Oct 27, 2015
Grant date	Oct 27, 2015

Abstract

Compositions for chemically removing sulfur deposits from reservoir formations, production tubing, flow lines, and other production equipment due to the production of sour gas and/or oil including reaction products of diamines and aldehydes at a mole ratio between about 1:1 and about 1:6, and methods for making and using same.

First claim

We claim:

1. A composition for chemically removing sulfur from the surface of producing formations and production equipment comprising:
at least one diamine/aldehyde reaction product,
where the diamine include the diamines have the general formula H 2 N—R 2 —NH 2 , where R 2 is selected from the group consisting of a hydrocarbon group of the general formula —(CH 2 ) n —, where n is an integer having a value between about 3 and about 20, an oxyhydrocarbon group of the general formula —((CH 2 ) m )O) n CH 2 —, where m is an integer having a value between 1 and 3 and n is an integer having a value between about 1 to about 10, a cyclic hydrocarbon group having between about 6 and about 20 carbon atoms, and mixtures or combinations thereof,
where a diamine to aldehyde mole ratio of between about 0.9:1.1 and about 1.1:0.9, and
where the composition chemically removes sulfur from formation surfaces and production equipment in contact with fluids and/or gases that deposit sulfur on formation surfaces and production equipment.

2. The composition of claim 1 , wherein the composition uptakes at least 10 wt. % sulfur at 25° C.

3. The composition of claim 1 , wherein the mole ratio is between about 0.95:1.05 and about 1.05:0.95.

4. The composition of claim 1 , wherein the mole ratio is between about 0.99:1.01 and about 1.01:0.99.

5. The composition of claim 1 , wherein the mole ratio is 1:1.

6. The composition of claim 1 , wherein the diamines are selected from the group consisting of α,ω-diamino alkanes having between about 3 and 20 carbon atoms.

7. The composition of claim 6 , wherein the diamines are selected from the group consisting of 1,3-diamine propane, 1,4-diamino butane, 1,5-diamine pentane, 1,6-diamine hexane, 1,7-diamine heptane, 1,8-diamine octane, higher α,ω-diamino alkanes and mixtures or combinations thereof.

8. The composition of claim 1 , wherein the aldehyde is selected from the group consisting of formaldehyde, paraformaldehyde, and mixtures or combinations thereof and wherein the diamines are selected from the group consisting of 1,3-diamine propane, 1,4-diamino butane, 1,5-diamine pentane, 1,6-diamine hexane, 1,7-diamine heptane, 1,8-diamine octane, and mixtures or combinations thereof.

9. The composition of claim 1 , wherein the aldehyde is selected from the group consisting of aldehyde and aldehyde donors, where the aldehydes have the general formula R 1 CHO, where R 1 is a hydrogen atom, a hydrocarbon group having between 1 and 20 carbon atoms, and mixtures or combinations thereof and when R 1 is a hydrocarbon group, then R 1 is linear, branched, cyclic, or any combination thereof.

10. The composition of claim 9 , wherein R 1 is selected from the group consisting of a hydrogen atom, alkyl groups, oxyhydrocarbon groups, aryl groups, alkaryl groups, aralkyl groups, and mixtures or combinations thereof.

11. The composition of claim 1 , wherein the aldehyde is selected from the group consisting of formaldehyde, paraformaldehyde, and mixtures or combinations thereof.

12. A method for dissolving sulfur from formation surfaces and equipment surfaces associated with a producing formation comprising:
contacting a producing formation and associated equipment with a composition including an effective amount of a sulfur dissolution system comprising at least one diamine/aldehyde reaction product,
where the diamines have the general formula H 2 N—R 2 —NH 2 , where R 2 is selected from the group consisting of a hydrocarbon group of the general formula —(CH 2 ) n —, where n is an integer having a value between about 3 and about 20, an oxyhydrocarbon group of the general formula —((CH 2 ) m )O) n CH 2 , where m is an integer having a value between 1 and 3 and n is an integer having a value between about 1 to about 10, a cyclic hydrocarbon group having between about 6 and about 20 carbon atoms, and mixtures or combinations thereof,
where a diamine to aldehyde mole ratio of between about 0.9:1.1 and about 1.1:0.9, and
where the composition dissolves sulfur from formation surfaces and production equipment in contact with fluid that deposit sulfur on formation surfaces and production equipment.

13. The method of claim 12 , wherein the composition uptakes at least 10 wt. % sulfur at 25° C.

14. The method of claim 12 , wherein the composition uptakes at least 10 wt. % sulfur at 25° C. and at least 10 wt. % sulfur at 80° C. and the mole ratio is between about 0.95:1.05 and about 1.05:0.95.

15. The method of claim 12 , wherein the composition uptakes at least 20 wt. % sulfur at 25° C. and at least 20 wt. % sulfur at 80° C. and the mole ratio is between about 0.99:1.01 and about 1.01:0.99.

16. The method of claim 12 , wherein composition uptakes at least 30 wt. % sulfur at 25° C. and at least 30 wt. % sulfur at 80° C. and the mole ratio is 1.1.

17. The method of claim 12 , wherein the composition uptakes at least 40 wt. % sulfur at 25° C. and at least 40 wt. % sulfur at 80° C. and the mole ratio is 1.1.

18. The method of claim 12 , wherein the diamines are selected from the group consisting of diamines of α,ω-diamino alkanes having between about 3 and 20 carbon atoms.

19. The method of claim 12 , wherein the diamines are selected from the group consisting of 1,3-diamine propane, 1,4-diamino butane, 1,5-diamine pentane, 1,6-diamine hexane, 1,7-diamine heptane, 1,8-diamine octane, higher α,ω-diamino alkanes and mixtures or combinations thereof.

20. The method of claim 12 , wherein the aldehyde is selected from the group consisting of formaldehyde, paraformaldehyde, and mixtures or combinations thereof and wherein the diamines are selected from the group consisting of 1,3-diamine propane, 1,4-diamino butane, 1,5-diamine pentane, 1,6-diamine hexane, 1,7-diamine heptane, 1,8-diamine octane, and mixtures or combinations thereof.

21. The method of claim 12 , wherein the aldehyde is selected from the group consisting of aldehyde and aldehyde donors, where the aldehydes have the general formula R 1 CHO, where R 1 is a hydrogen atom, a hydrocarbon group having between 1 and 20 carbon atoms, and mixtures or combinations thereof and when R 1 is a hydrocarbon group, then R 1 may be linear, branched, cyclic, or any combination thereof.

22. The method of claim 21 , wherein the R 1 group is selected from the group consisting of a hydrogen atom, alkyl groups, oxyhydrocarbon groups, aryl groups, alkaryl groups, aralkyl groups, and mixtures or combinations thereof and when R 1 is a hydrocarbon group, then R 1 is linear, branched, cyclic, or any combination thereof.

23. The method of claim 12 , wherein the aldehyde is selected from the group consisting of formaldehyde, paraformaldehyde, and mixtures or combinations thereof.

24. The method of claim 1 , wherein the composition uptakes at least 10 wt. % sulfur at 25° C. and at least 10 wt. % sulfur at 80° C. and the mole ratio is 1:1.

25. The method of claim 1 , wherein the composition uptakes at least 20 wt. % sulfur at 25° C. and at least 20 wt. % sulfur at 80° C. and the mole ratio is 1:1.

26. The method of claim 1 , wherein composition uptakes at least 30 wt. % sulfur at 25° C. and at least 30 wt. % sulfur at 80° C. and the mole ratio is 1:1.

27. The method of claim 1 , wherein the composition uptakes at least 40 wt. % sulfur at 25° C. and at least 40 wt. % sulfur at 80° C. and the mole ratio is 1:1.

Assignees

• Weatherford Lamb
• Lubrizol Oilfield Solutions Inc

Inventors

• Levey Simon
• Smith Clayton
• Murugan Pulikesi

Classifications

• C08G12/06

  Amines · CPC title

• C11D11/0041

  Chemistry & Metallurgy · mapped topic

• C11D7/3209

  Amines or imines with one to four nitrogen atoms; Quaternized amines · CPC title

• E21B37/06 Primary

  using chemical means for preventing or limiting {, e.g. eliminating,} the deposition of paraffins or like substances · CPC title

• C11D2111/20

  Industrial or commercial equipment, e.g. reactors, tubes or engines · CPC title