Moisture absorbing anti-fog composition and process for the use thereof

Patent metadata

Field	Value
Publication number	US-9150766-B2
Application number	US-201313833379-A
Country	US
Kind code	B2
Filing date	Mar 15, 2013
Priority date	Aug 9, 2012
Publication date	Oct 6, 2015
Grant date	Oct 6, 2015

Abstract

An anti-fog composition is provided that includes a superabsorbent polymer that along with a wetting agent are dissolved in a solvent. The superabsorbent polymer excludes hydroxylated acrylate and methacrylate polymers. The composition upon being applied to a substrate with the excess composition removed, an anti-fog film is formed on the substrate without resort to heat treatment and vacuum processing or other complex application processes associated with. The composition is well suited for formation of an end user kit for applying such a film to a substrate. Such a kit includes a container for the composition or a wipe wet with the composition. The container being a bottle or a propellant filled aerosol canister. Upon wiping residual composition from the substrate, the anti-fog film is produced without resort to prior art and complex application processes.

First claim

The invention claimed is:

1. An anti-fog composition comprising:
a superabsorbent polymer; with the proviso that said superabsorbent polymer is not a hydroxyalkyl acrylate or hydroxymethacrylate or hydroxy alkoxyalkylacrylate or hydroxy alkoxymethacrylate;
a wetting agent;
a hydrophilic film plasticizer; and
a hydrophilic solvent system comprising water and a miscible organic solvent, in which said superabsorbent polymer, said plasticizer, and said wetting agent are dissolved.

2. The composition of claim 1 wherein said superabsorbent polymer is a sodium polyacrylate.

3. The composition of claim 1 wherein said superabsorbent polymer is at least one of: acrylates, acrylonitrile, methacrylonitrile, vinyl acetates, vinylpyrrolidones, vinyl alcohol. maleic acid anhydride, itaconic acid anhydride, fumaric acid, vinylsulfonic acid and the salts, amides, N-C 1 -C 6 alcohol derivatives, N-N-dialkyl C 1 -C 6 derivatives, and copolymers containing an aforementioned monomeric group.

4. The composition of claim 1 wherein said superabsorbent polymer has a superabsorbent polymer weight and is able to absorb at least 5 times the superabsorbent polymer weight.

5. The composition of claim 1 wherein said wetting agent is a polymeric silane or a polymeric siloxane.

6. The composition of claim 5 wherein said wetting agent is at least one of methyl (propoxylhydroxide, ethoxylated) bis (trimethylsiloxy silane), siloxane polyalkynleneoxide copolymer, silo xane po lyether copolymer, polydimethyl siloxane polyethylene, oxide-propyleneoxide copolymer, polydimethyl siloxane silicone fluid, polyalkyleneoxide modified heptamethyltrisiloxane fluorinated alkylalkoxylate fluorocarbon telomere B monoether with polyethylene glycols, ethoxylated tetramethyl decanediol.

7. The composition of claim 1 wherein said solvent system is between 80-99% by weight of the composition.

8. The composition of claim 1 wherein said superabsorbent polymer, said wetting agent and said solvent are amenable to devoid of volatile organic compounds (VOCs).

9. An anti-fog composition comprising:
a superabsorbent polymer; with the proviso that said superabsorbent polymer is not a hydroxyalkyl acrylate or hydroxymethacrylate or hydroxy alkoxyalkylacrylate or hydroxy alkoxymethacrylate;
a wetting agent;
a hydrophilic film plasticizer; and
a hydrophilic solvent system comprising water and a miscible organic solvent, in which said superabsorbent polymer and said wetting agent are dissolved; and at least one additive of a defoamer and a light stabilizer.

10. An anti-fog composition consisting of:
a superabsorbent polymer;
a wetting agent;
a hydrophilic film plasticizer;
a solvent system in which said superabsorbent polymer and said wetting agent are dissolved; and
an optional additive of at least one of a biocide, a cleaning solvent, a defoamer, a light stabilizer, and a corrosion inhibitor.

11. The composition of claim 10 wherein solvent is between 80-99% by weight of the composition.

12. A process for applying an anti-fog film to a substrate consisting of:
applying the composition of claim 1 to the substrate;
and removing excess from the surface to form the film.

13. The process of claim 12 wherein the composition optionally includes at least one additive of, a biocide, a cleaning solvent, a defoamer, a light stabilizer, and a corrosion inhibitor.

14. The process of claim 12 specifically excluding a second step beyond allowing sufficient time to apply the film.

15. The composition of claim 1 wherein said plasticizer is a hydroxyethylpyrrolidone.

16. The composition of claim 9 wherein said at least one additive further comprises a biocide and a cleaning solvent.

17. The composition of claim 10 wherein said plasticizer is a hydroxyethylpyrrolidone.

Assignees

• Illinois Tool Works

Inventors

• Phang Tze Lee

Classifications

• C09D133/02

  Homopolymers or copolymers of acids; Metal or ammonium salts thereof · CPC title

• C09K3/18 Primary

  for application to surfaces to minimize adherence of ice, mist or water thereto (rendering particulate materials free flowing, in general, e.g. making them hydrophobic B01J2/30); Thawing or antifreeze materials for application to surfaces (used in liquids for heat-transfer, heat-exchange or heat-storage or for the production of heat or cold other than by combustion, e.g. radiator liquids, C09K5/00) · CPC title