Toner

Patent metadata

Field	Value
Publication number	US-9141012-B2
Application number	US-201314105162-A
Country	US
Kind code	B2
Filing date	Dec 12, 2013
Priority date	Jun 22, 2012
Publication date	Sep 22, 2015
Grant date	Sep 22, 2015

Abstract

The toner includes toner particles containing a polyester resin A, a polyester resin B and a colorant, the polyester resin A has a polyester portion including a segment capable of forming a crystal structure and a crystal nucleating agent segment, which is bonded to an end of the polyester portion, and the polyester resin B is a resin which is free of any segments capable of forming a crystal structure, the polyester resin B has a weight average molecular weight Mwb by GPC of a THF soluble matter of 3000 or more and 100000 or less, and an SP value Sa ((cal/cm 3 ) 1/2 ) of the polyester portion of the polyester resin A and an SP value Sb ((cal/cm 3 ) 1/2 ) of the polyester resin B satisfy the following relationships:

9.00≦ Sa ≦10.50

−0.40≦ Sb−Sa ≦0.80.

First claim

What is claimed is:

1. A toner comprising toner particles, each of which contains a polyester resin A, a polyester resin B and a colorant, wherein:
the polyester resin A has
a polyester portion including a segment capable of forming a crystal structure and
a crystal nucleating agent segment, which is bonded to an end of the polyester portion,
the polyester resin A is a crystalline polyester resin,
the crystal nucleating agent segment is formed by reacting (i) a compound having a hydrocarbon segment as a principal chain and having one functional group reactive with the end of the polyester portion, with (ii) the end of the polyester portion, and
the polyester resin B is a resin which is free of any segments capable of forming a crystal structure,
a THF soluble matter of the polyester resin B has a weight average molecular weight Mwb of 3000 or more and 100000 or less, and wherein:
when an SP value of the polyester portion of the polyester resin A is represented by Sa ((cal/cm 3 ) 1/2 ), an SP value of the polyester resin B is represented by Sb ((cal/cm 3 ) 1/2 ), the SP values Sa and Sb satisfy the following relationships:
9.00 ≦Sa≦ 10.50
−0.40 ≦Sb−Sa≦ 0.80.

2. The toner according to claim 1 , wherein a mass-based content ratio between the polyester resin A and the polyester resin B in the toner particles is 5:95 to 40:60.

3. The toner according to claim 1 , wherein the crystal nucleating agent segment is derived from at least one compound selected from the group consisting of aliphatic carboxylic acids having 10 or more and 30 or less carbon atoms and aliphatic alcohols having 10 or more and 30 or less carbon atoms.

4. The toner according to claim 1 , wherein when a weight average molecular weight of a THF soluble matter of the polyester resin A is represented by Mwa, the Mwa and the Mwb satisfy a relationship of Mwb<Mwa.

5. The toner according to claim 1 , wherein the polyester resin A has a quantity of heat of fusion (ΔH), obtained based on an area of an endothermic peak observed in temperature rise in measurement with a differential scanning calorimeter (DSC), of 100 J/g or more and 140 J/g or less.

6. The toner according to claim 1 , wherein the polyester resin A has a melting point of 60° C. or more and 120° C. or less.

Assignees

• Canon Kk

Inventors

• Moribe Shuhei
• Fukudome Kosuke
• Mita Satoshi
• Terauchi Kazuo
• Hotta Yojiro
• Ida Tetsuya

Classifications

• G03G9/08797

  characterised by their physical properties, e.g. viscosity, solubility, melting temperature, softening temperature, glass transition temperature · CPC title

• G03G9/08755 Primary

  Polyesters · CPC title

• G03G9/08795

  characterised by their chemical properties, e.g. acidity, molecular weight, sensitivity to reactants · CPC title