Electrochemical, bromination, and oxybromination systems and methods to form propylene oxide or ethylene oxide
US-2021179574-A1 · Jun 17, 2021 · US
US9133151B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9133151-B2 |
| Application number | US-201314402442-A |
| Country | US |
| Kind code | B2 |
| Filing date | Jun 21, 2013 |
| Priority date | Jun 26, 2012 |
| Publication date | Sep 15, 2015 |
| Grant date | Sep 15, 2015 |
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According to the present invention, a method for producing bis(β-epoxypropyl)sulfide or bis(β-epoxypropyl)polysulfide can be provided, which is characterized by comprising adding a metal compound selected from the group consisting of a metal hydrosulfide, a metal sulfide and a metal polysulfide to an epihalohydrin at −5 to 30° C. in such a manner that the molar ratio of the epihalohydrin to the metal compound becomes 5 to 20 to thereby cause the reaction of the epihalohydrin with the metal compound. In a preferred embodiment, the epihalohydrin is epichlorohydrin, the metal hydrosulfide is sodium hydrosulfide or potassium hydrosulfide, the metal sulfide is sodium sulfide or potassium sulfide, and the metal polysulfide is sodium polysulfide or potassium polysulfide.
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The invention claimed is: 1. A method for producing bis(β-epoxypropyl)sulfide or bis(β-epoxypropyl)polysulfide, which comprises adding a metal compound selected from the group consisting of a metal hydrosulfide, a metal sulfide and a metal polysulfide to an epihalohydrin at −5 to 30° C. in such a manner that the molar ratio of the epihalohydrin to the metal compound becomes 5 to 20 to thereby cause the reaction of the epihalohydrin with the metal compound. 2. Th…
Chemistry & Metallurgy · mapped topic
Chemistry & Metallurgy · mapped topic
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