Bi-layer adhesive for lens lamination

Patent metadata

Field	Value
Publication number	US-9132594-B2
Application number	US-26437608-A
Country	US
Kind code	B2
Filing date	Nov 4, 2008
Priority date	Nov 4, 2008
Publication date	Sep 15, 2015
Grant date	Sep 15, 2015

Abstract

A method for laminating a film on to an optical article and a bi-layer adhesive for use in the method. The bi-layer adhesive includes a latex adhesive layer and an HMA layer sequentially disposed on the film and dried to form a solid layer of uniform thinness throughout to provide optical quality. Various types of films may be employed to provide an optical function. Following optional pre-treatment steps, the adhesives are coated on to the film. An optical hot press technique is used to deliver heat and pressure over a short period of time to form a functionally-enhanced optical article with high adhesive strength.

First claim

What is claimed is:

1. A method for manufacturing a functionalized optical element comprising:
providing an optical base element;
providing a functionalized layered structure that includes at least one functional layer, such that the functionalized layered structure adheres to the optical base element, the providing including the steps of:
applying a first coating as a layer of latex adhesive onto one exposed surface of the at least one functional layer;
drying said first coating thereby forming a dried latex adhesive layer which bonds strongly to the at least one functional layer;
applying a second coating as a layer of hot-melt adhesive (HMA) onto the dried latex adhesive layer to form a uniformly thin bi-layer adhesive lamina of optical quality, wherein a polymer for forming the HMA layer includes only a thermoplastic polymer;
drying the second coating applied as the HMA layer before hot pressing,
each of the first coating and the second coating comprising a different adhesive layer; and

upon preparing the bi-layer adhesive lamina, hot pressing the functionalized layered structure against the optical base element with the bi-layer adhesive lamina therebetween, whereby the second coating formed as a dried HMA layer bonds with the optical base element,
the bi-layer adhesive lamina forming a functionalized optical element,
such that a high adhesive strength is thereby provided between the optical base element and the functionalized layered structure by using the latex adhesive and the HMA layer in combination to form the bi-layer adhesive lamina to address disparate material properties between the at least one functional layer and the optical base element.

2. The method of claim 1 , wherein the optical base element has a base curve, and prior to applying said first coating, the method further includes:
thermoforming the functionalized layered structure to a curve that is close to a base curve.

3. The method of claim 1 , wherein prior to applying said first coating, the method further includes:
surface treating the functionalized layered structure with a corona discharge.

4. The method of claim 1 , wherein applying said first coating comprises spin coating a liquid polyurethane latex adhesive to a final dry thickness of between about 0.5 microns and about 10 microns.

5. The method of claim 1 , wherein applying said second coating comprises spin coating a liquid polyurethane HMA to a final dry thickness of between 1 micron and 20 microns.

6. The method of claim 1 , further including the following step:
exposing the functionalized optical element to UV radiation.

7. The method of claim 1 , wherein applying said first coating comprises spin coating a liquid polyurethane latex adhesive to a final dry thickness of between 1.0 microns and 5.0 microns; and wherein applying said second coating comprises spin coating a liquid polyurethane HMA to a final dry thickness of between 1.5 microns and 10 microns to provide a bi-layer adhesive lamina at optical quality with a uniform thickness varying by less than 0.3 microns.

8. The method of claim 7 , wherein the functionalized layered structure includes a polarizing film.

9. The method of claim 7 , wherein the optical base element is a thermoset optical base element selected from the group consisting of a finished lens, a semi-finished lens, a PAL lens, an afocal lens, a plano lens, a unifocal lens, and a multifocal lens.

10. The method of claim 1 , wherein the functionalized layered structure includes one or more layers selected from the group consisting of:
an optical function layer;
an optical structured layer;
a Fresnel lens structure;
a performance function layer;
a polarizing layer;
a photochromic layer;
a hard coat layer;
a top coat layer;
an anti-fog layer;
an anti-smudge layer;
an anti-reflective layer; and
an anti-static layer.

11. The method of claim 1 , wherein the optical base element is a thermoplastic optical base element selected from the group consisting of a finished lens, a semi-finished lens, a PAL lens, an afocal lens, a plano lens, a unifocal lens, and a multifocal lens.

12. The method of claim 1 , wherein the optical base element is a polycarbonate lens, and wherein the functionalized layered structure includes a polarizing film which collectively form a laminated polarized ophthalmic lens.

13. The method of claim 1 , wherein the HMA is selected from the group consisting of polyolefins, polystyrene block elastomers, polyisoprene block elastomers, ethylene-butylene copolymer block elastomers, polyamides, polyurethanes, polyurethane-ureas, polyvinylpyrrolidones, polyesters, polyesteramides, poly(oxazolines) and poly(meth) acrylic systems.

14. The method of claim 1 , wherein the HMA is a polyurethane-based HMA.

15. The method of claim 1 , wherein the HMA is UV curable.

16. The method of claim 1 , wherein when the second coating has a final dry thickness of between 1.5 microns and 10 microns, there is a small variation in thickness that is less than 0.3 microns and 1.0 microns, respectively.

17. The method of claim 1 , wherein drying said first coating includes an introduction of heat.

18. The method of claim 1 , wherein drying the second coating includes an introduction of heat.

19. The method of claim 1 , wherein hot pressing the functionalized layered structure against the optical base element with the bi-layer adhesive lamina therebetween further comprises exposing to UV radiation.

20. The method of claim 1 , wherein the first coating forms a thermoset layer.

Assignees

• Glacet Arnaud
• Jiang Peiqi
• Keegan Bruce
• Essilor Int

Inventors

• Glacet Arnaud
• Jiang Peiqi
• Keegan Bruce

Classifications

• Y10T428/2878

  including addition polymer from unsaturated monomer · CPC title

• Y10T156/1002

  with permanent bending or reshaping or surface deformation of self sustaining lamina · CPC title

• Y10T428/28

  Web or sheet containing structurally defined element or component and having an adhesive outermost layer · CPC title

• Y10T428/265

  1 mil or less · CPC title

• C09J175/04

  Polyurethanes · CPC title