Water-based ink for computer-to-plate inkjet printing and preparation method therefor

Patent metadata

Field	Value
Publication number	US-9127177-B2
Application number	US-201214343613-A
Country	US
Kind code	B2
Filing date	Sep 7, 2012
Priority date	Sep 8, 2011
Publication date	Sep 8, 2015
Grant date	Sep 8, 2015

Abstract

A water-based ink for use in a computer-to-plate inkjet printing and a preparation method therefor. A polymer of 5 to 40 wt %, an additive of 0.01 to 10 wt %, a dye or pigment of 0.01 to 10 wt %, an organic solvent of 1 to 30 wt %, an anti-foaming agent of 0 to 5 wt %, and deionized water are stirred and mixed at room temperature. When the polymer is dissolved, the mixed solution is filtered. The filtrate is the water-based ink. The water-based ink is sprayed via a computer-to-plate machine onto a surface of a metal substrate (which may be an aluminum plate, a zinc plate, or a copper plate) to form a graphic region. A printing plate allowing for computer-to-plate printing is acquired after solidification. The printing plate acquired is allowed to achieve a halftone dot reproduction rate between 2 and 99% and a recognition rate of 175 lpi.

First claim

What is claimed is:

1. A water-based ink for computer-to-plate inkjet printing, wherein based on total amount of the water-based ink, the water-based ink consists of:
5-40 wt % of a polymer,
0.01-10 wt % of an additive,
0.01-10 wt % of dye or pigment,
1 to 30 wt % of organic solvent,
0-5 wt % of anti-foaming agent, and
balance of deionized water;
the polymer is at least one selected from the group consisting of epoxy resin, water-soluble phenolic resin, polyvinyl alcohol, polyvinyl pyrrolidone, polyethylene glycol, gelatin, gum arabic, polyacrylic acid resin, alkyd resin, polymethacrylic acid resin, copolymer of acrylic acid and acrylate-based monomer, copolymer of methacrylic acid and methacrylate-based monomer, polyvinyl acetal and water-soluble cellulose;
the additive is selected from organic silicone-based leveling agent and/or organic fluorine-based leveling agent, the organic silicone-based leveling agent is at least one selected from the group consisting of polydimethylsiloxane, polyphenylmethylsiloxane and polyester-modified silicone; the organic fluorine-based leveling agent is at least one selected from the group consisting of fluorine-containing acrylic resin;
the anti-foaming agent is at least one selected from the group consisting of nature oils, polyether and higher alcohols.

2. The water-based ink for computer-to-plate inkjet printing according to claim 1 , wherein the acrylate-based monomer is at least one selected from the group consisting of methyl acrylate, ethyl acrylate, propyl acrylate, n-butyl acrylate, lauryl acrylate, octadecyl acrylate and 2-ethyl hexyl acrylate;
the methacrylate-based monomer is at least one selected from the group consisting of methyl methacrylate, butyl methacrylate, 2-phenoxy ethyl methacrylate and glycidyl methacrylate.

3. The water-based ink for computer-to-plate inkjet printing according to claim 1 , wherein the dye is one selected from the group consisting of active dye, acidic dye and basic dye;
the pigment has a particle size of 5-1000 nm; the pigment is one selected from the group consisting of pigment yellow, pigment orange, pigment red, pigment purple, pigment blue, pigment green, pigment brown, pigment black, pigment white and metal pigment.

4. The water-based ink for computer-to-plate inkjet printing according to claim 3 , wherein the active dye is one selected from the group consisting of black dye SP series and active black;
the acidic dye is one selected from the group consisting of dye acidic blue and dye acidic yellow;
the basic dye is one selected from the group consisting of basic brilliant blue and Victoria blue.

5. The water-based ink for computer-to-plate inkjet printing according to claim 4 , wherein the dye acidic blue is one selected from the group consisting of acidic blue 9, acidic blue 25, acidic blue 40, acidic blue 62, acidic blue 324, acidic blue AS, acidic blue AGG, acidic blue 2BR and acidic blue BR;
the dye acidic yellow is one selected from the group consisting of dye acidic yellow 3, dye acidic yellow 23, dye acidic yellow 49, dye acidic yellow 127 and dye acidic yellow 6G.

6. The water-based ink for computer-to-plate inkjet printing according to claim 1 , wherein the organic solvent is at least one selected from the group consisting of ethanol, propanol, isopropanol, n-butanol, tent-butanol, acetonitrile, tetrahydrofuran, 1, 4-dioxane, dimethylsulfoxide, N, N-dimethylformamide, ethylene glycol ethyl ether, propylene glycol methyl ether, propylene glycol ethyl ether, diethylene glycol methyl ether, ethylene glycol mono-n-butyl ether, ethylene glycol dimethyl ether, propylene glycol isopropyl ether, propylene glycol monobutyl ether, propylene glycol dibutyl ether, diethylene glycol monoethyl ether, diethylene glycol dimethyl ether, diethylene glycol monobutyl ether, dipropylene glycol monomethyl ether, dipropylene glycol dimethyl ether, dipropylene glycol diethyl ether, dipropylene glycol dipropyl ether, dipropylene glycol monoethyl ether, dipropylene glycol monobutyl ether, triethylene glycol monoethyl ether, triethylene glycol monobutyl ether, tripropylene glycol monomethyl ether, ethylene glycol, propylene glycol, glycerol, diethylene glycol and triethylene glycol.

7. The water-based ink for computer-to-plate inkjet printing according to claim 1 , wherein the conductivity of the deionized water is less than 10 micro Siemens/cm.

8. A method for preparing the water-based ink for computer-to-plate inkjet printing, based on the total amount of the water-based ink, wherein the method comprises the following steps: mixing 5-40 wt % of polymer, 0.01 to 10 wt % of additive, 0.01 to 10 wt % of dye or pigment, 1 to 30 wt % of organic solvent, 0 to 5 wt % of anti-foaming agent, and balance of deionized water by stirring at room temperature, when the polymer is completely dissolved, filtering the mixed solution, and obtaining filtrate as the water-based ink for computer-to-plate inkjet printing,
the polymer is at least one selected from the group consisting of, epoxy resin, water-soluble phenolic resin, polyvinyl alcohol, polyvinyl pyrrolidone, polyethylene glycol, gelatin, gum arabic, polyacrylic acid resin, alkyd resin, polymethacrylic acid resin, copolymer of acrylic acid and acrylate-based monomer, copolymer of methacrylic acid and methacrylate-based monomer, polyvinyl acetal and water soluble cellulose;
the additive is selected from organic silicone-based leveling agent and/or organic fluorine-based leveling agent, the organic silicone-based leveling agent is at least one selected from the group consisting of polvdimethvlsiloxane, polyphenylmethylsiloxane and polyester-modified silicone; the organic fluorine-based leveling agent is at least one selected from the group consisting of fluorine-containing acrylic resin;
the anti-foaming agent is at least one selected from the group consisting of nature oils, polyether and higher alcohols.

9. The method according to claim 8 , wherein the acrylate-based monomer is at least one selected from the group consisting of methyl acrylate, ethyl acrylate, propyl acrylate, n-butyl acrylate, lauryl acrylate, octadecyl acrylate and 2-ethyl hexyl acrylate;
the methacrylate-based monomer is at least one selected from the group consisting of methyl methacrylate, butyl methacrylate, 2-phenoxy ethyl methacrylate and glycidyl methacrylate.

10. The method according to claim 8 , wherein the dye is one selected from the group consisting of active dye, acidic dye and basic dye;
the pigment has a particle size of 5-1000 nm; the pigment is one selected from the group consisting of pigment yellow, pigment orange, pigment red, pigment purple, pigment blue, pigment green, pigment brown, pigment black, pigment white and metal pigment.

11. The method according to claim 10 , wherein the active dye is one selected from the group consisting of black dye SP series and active black;
the acidic dye is one selected from the group consisting of dye acidic blue and dye acidic yellow;
the basic dye is one selected from the group consisting of basic brilliant blue and Victoria blue.

12. The method according to claim 11 , wherein the dye acidic blue is one selected from the group consisting of acidic blue 9, acidic blue 25, acidic blue 40, acidic blue 62, acidic blue 324, acidic blue AS, acidic blue AGG, acidic blue 2BR and acidic blue BR;
the dye acidic yellow is one selected from the group consisting of dye acidic yellow 3, dye acidic yellow 23, dye acidic yellow 49, dye acidic yellow 127 and dye acidic yellow 6G.

13. The method according to claim 8 , wherein the organic solvent is at least one selected from the group consisting of ethanol, propanol, iso

Assignees

• Wu Wei
• Zhou Haihua
• Song Yanlin
• Chinese Acad Inst Chemistry

Inventors

• Wu Wei
• Zhou Haihua
• Song Yanlin

Classifications

• C09D11/30

  Inkjet printing inks · CPC title

• C09D11/03 Primary

  characterised by features other than the chemical nature of the binder · CPC title

• C09D11/10 Primary

  based on artificial resins · CPC title

• C09D11/328

  characterised by dyes · CPC title

• C09D11/38

  characterised by non-macromolecular additives other than solvents, pigments or dyes · CPC title