Ammonia plant

Patent metadata

Field	Value
Publication number	US-9126841-B2
Application number	US-57250705-A
Country	US
Kind code	B2
Filing date	Jul 28, 2005
Priority date	Jul 29, 2004
Publication date	Sep 8, 2015
Grant date	Sep 8, 2015

Abstract

A synthesis plant ( 309 A) includes a compression device ( 360 A) that increases a pressure differential between the bottom product pressure of a cryogenic separator ( 340 A) and the delivery pressure of the bottom product to a downstream plant component. Such increased pressure differential is employed to increase cooling in the separator ( 340 A) to thereby significantly reduce the volume of excess air. In most preferred aspects, at least part of the energy required for the compression device is provided by expansion ( 320 A) of the separator feed.

First claim

What is claimed is:

1. An ammonia plant comprising:
a raw syngas expander that is configured to receive and expand a raw syngas;
a cryogenic rectifier that is configured to receive the expanded raw syngas and to produce a bottom product at a bottom product pressure and to further produce a processed syngas overhead product;
an expansion device that is fluidly coupled to the cryogenic rectifier and that is configured to receive the bottom product at a first pressure and to expand the bottom product from the first pressure to a second pressure to thereby provide refrigeration cold to an overhead condenser of the cryogenic rectifier; and
(a) a compressor downstream of the expansion device and fluidly coupled to the expansion device to receive expanded bottom product when the first pressure is the bottom product pressure, such that the bottom product of the cryogenic rectifier flows directly from the rectifier to the expansion device and directly from the expansion device to the compressor that compresses the expanded bottom product from the second pressure to a higher pressure, or
(b) a pump upstream of the expansion device and fluidly coupled to the expansion device to receive the bottom product when the pump compresses the bottom product from the bottom product pressure to the first pressure, such that the bottom product of the cryogenic rectifier flows directly from the rectifier to the pump and directly from the pump to the expansion device; and
wherein the pump or compressor is operationally coupled to the raw syngas expander such that energy expended in the pump or compressor is produced by the raw syngas expander, and wherein a pressure differential between the first and second pressure is sufficient to increase the refrigeration cold in the overhead condenser.

2. The ammonia plant of claim 1 further comprising a raw syngas expander coupled to the cryogenic rectifier, wherein the raw syngas expander is configured to provide expanded raw syngas to the cryogenic rectifier.

3. The ammonia plant of claim 2 wherein the pump or compressor is coupled to the raw syngas expander to thereby provide at least part of a compression energy.

4. The ammonia plant of claim 3 wherein the expansion device is located upstream of the compressor.

5. The ammonia plant of claim 4 wherein the expansion device is configured to expand the bottom product to a pressure between atmospheric pressure and 30 psig.

6. The ammonia plant of claim 3 wherein the expansion device comprises a JT valve.

7. The ammonia plant of claim 3 wherein the expansion device is located downstream of the pump.

8. The ammonia plant of claim 7 wherein the pump increases the bottom pressure by an amount of 30 to 50 psi.

9. A method of operating an ammonia plant, comprising:
expanding a raw syngas in a raw syngas expander to form an expanded raw syngas and to produce energy;
separating the expanded raw syngas in a cryogenic rectifier into a bottom product having a bottom product pressure and a processed syngas overhead product;
expanding in an expander the entire bottom product from a first pressure to a second pressure to thereby provide refrigeration cold to an overhead condenser of the cryogenic rectifier; and
compressing in a compressor the entire bottom product from the bottom product pressure to the first pressure such that the entire bottom product flows directly from the cryogenic rectifier to the compressor and from the compressor to the expander, or
compressing in a compressor the entire bottom product from the second pressure to a higher pressure when the bottom product pressure is the first pressure such that the entire bottom product flows directly from the cryogenic rectifier to the expander and from the expander to the compressor;
wherein energy required for the step of compressing the entire bottom product is provided by the expansion of the raw syngas in the raw syngas expander; and
wherein an increase in a pressure differential between the first and second pressure is sufficient to increase generation of the refrigeration cold in the overhead condenser.

10. The method of claim 9 wherein the expander is a JT valve.

11. The method of claim 10 wherein the raw syngas expander is operationally coupled to the compressor that compresses the bottom product.

12. The method of claim 9 wherein the bottom product is expanded from the bottom product pressure to a pressure that is between atmospheric pressure and 30 psig.

13. The method of claim 12 wherein the higher pressure is a pressure suitable for feeding to a reformer furnace.

14. The method of claim 9 wherein the bottom product is pumped to the first pressure and then expanded to the second pressure, wherein the first pressure is higher than an operating pressure of the cryogenic rectifier.

15. A method of operating an ammonia plant, comprising:
expanding raw syngas in an expander to produce work and refrigeration for cryogenic separation of the raw syngas into a bottom product and a processed syngas overhead product;
operationally coupling the expander to (i) a compressor that is located downstream of an expansion device and compresses expanded bottom product to a delivery pressure or (ii) a pump that is located upstream of the expansion device;
using the work from the expander to drive the pump or compressor that compresses the bottom product to thereby allow for an increase in a pressure differential between a pressure of the bottom product of a cryogenic rectifier and the delivery pressure of the bottom product to a plant component downstream of the cryogenic rectifier; and
wherein the increased pressure differential is used to generate refrigeration duty for an overhead condenser of the cryogenic rectifier.

16. The method of claim 15 wherein the step of using the work comprises compressing the bottom product using the pump to increase the pressure, wherein the pump is located upstream of an expansion device that expands the pumped bottom product to the delivery pressure.

17. The method of claim 16 wherein the pump increases the pressure by an amount of 30 to 50 psi.

18. The method of claim 15 wherein the compressor is downstream of the expansion device and wherein the expansion device reduces the pressure of the bottom product to a pressure between atmospheric pressure and 30 psig.

19. The method of claim 18 wherein the expanded bottom product further provides refrigeration in at least one heat exchanger.

Assignees

• Reddy Satish
• Bhakta Mukund
• Scherffius Jeffrey
• Fluor Tech Corp

Inventors

• Reddy Satish
• Bhakta Mukund
• Scherffius Jeffrey

Classifications

• F25J2235/60

  the fluid being (a mixture of) hydrocarbons · CPC title

• F25J3/0276

  separation of H2/N2 mixtures, i.e. of ammonia synthesis gas (in general C01B3/00) · CPC title

• F25J2210/20

  H2/N2 mixture, i.e. synthesis gas for or purge gas from ammonia synthesis · CPC title

• F25J2240/02

  Expansion of a process fluid in a work-extracting turbine (i.e. isentropic expansion), e.g. of the feed stream · CPC title

• C01B3/025

  Preparation or purification of gas mixtures for ammonia synthesis · CPC title