Dental curable composition

Patent metadata

Field	Value
Publication number	US-9125802-B2
Application number	US-201113996360-A
Country	US
Kind code	B2
Filing date	Dec 20, 2011
Priority date	Dec 20, 2010
Publication date	Sep 8, 2015
Grant date	Sep 8, 2015

Abstract

The present invention provides a dental curable composition which has excellent curability and which cures into a cured product that is less susceptible to discoloration by hydrogen sulfide in an oral environment. The present invention is a dental curable composition containing: a polymerizable monomer (a) having an acidic group, as a polymerizable monomer component; and a copper compound (b) and a benzotriazole compound (c) represented by the following general formula (1) and/or a benzimidazole compound (c) represented by the following general formula (2), as polymerization initiator components (symbols used in the formulae are as described in the description).

First claim

The invention claimed is:

1. A dental curable composition, comprising:
(a) a polymerizable monomer comprising an acidic group, as a polymerizable monomer component;
(b) a copper compound; and
(c) at least one of a benzotriazole compound represented by formula (I) and a benzimidazole compound represented by formula (II), as polymerization initiator components,

wherein R 1 to R 8 are each independently a hydrogen atom, a hydroxyl group, an alkyl group, an aryl group, an alkoxy group, an alkenyl group, an aralkyl group, or a halogen atom.

2. The dental curable composition according to claim 1 , further comprising: (d) an aromatic sulfinate.

3. The dental curable composition according to claim 2 , wherein the dental curable composition is divided into:
a first part comprising the polymerizable monomer (a) comprising an acidic group and the copper compound (b); and
a second part comprising the aromatic sulfinate (d) and (c) at least one of the benzotriazole compound and the benzimidazole compound.

4. The dental curable composition according to claim 3 , further comprising: (e) an organic peroxide in the first part.

5. The dental curable composition according to claim 4 , wherein the organic peroxide (e) is a peroxyester.

6. The dental curable composition according to claim 1 , further comprising: (f) a polymerizable monomer comprising no acidic group.

7. The dental curable composition according to claim 1 , comprising 0.00001 to 1 part by weight of the copper compound (b) per 100 parts by weight of a total amount of polymerizable monomer components.

8. The dental curable composition according to claim 1 , comprising:
the polymerizable monomer (a) comprising an acidic group and a polymerizable monomer (f) comprising no acidic group, as polymerizable monomer components; and
an inorganic peroxide (h), the copper compound (b), an amine-based reducing agent (i), an aromatic sulfinate (d), and (c) at least one of the benzotriazole compound and the benzimidazole compound, as polymerization initiator components.

9. The dental curable composition according to claim 8 , comprising 0.00001 to 1 part by weight of the copper compound (b) per 100 parts by weight of a total amount of the polymerizable monomer components.

10. The dental curable composition according to claim 8 , wherein the dental curable composition is divided into:
a first part comprising the polymerizable monomer (a) comprising an acidic group, the inorganic peroxide (h), and the copper compound (b); and
a second part comprising the polymerizable monomer (f) comprising no acidic group, the amine-based reducing agent (i), the aromatic sulfinate (d), and (c) at least one of the benzotriazole compound the benzimidazole compound.

11. The dental curable composition according to claim 10 , further comprising: (j) a sulfur-comprising reducing inorganic compound as a polymerization initiator component in the second part.

12. The dental curable composition according to claim 10 , further comprising: (e) an organic peroxide as a polymerization initiator component in the first part.

13. The dental curable composition according to claim 12 , wherein the organic peroxide (e) is a peroxyester.

14. The dental curable composition according to claim 1 , comprising said benzotriazole compound represented by formula (I).

15. The dental curable composition according to claim 1 , comprising said benzimidazole compound represented by formula (II).

16. A dental curable composition, comprising:
(a) a polymerizable monomer comprising an acidic group, as a polymerizable monomer component; and
a copper salt of (c) at least one of a benzotriazole compound represented by formula (I) and a benzimidazole compound represented by formula (II), as a polymerization initiator component,

wherein R 1 to R 8 are each independently a hydrogen atom, a hydroxyl group, an alkyl group, an aryl group, an alkoxy group, an alkenyl group, an aralkyl group, or a halogen atom.

17. The dental curable composition according to claim 16 , further comprising: (d) an aromatic sulfinate.

18. The dental curable composition according to claim 16 , comprising said copper salt of said benzotriazole compound represented by formula (I).

19. The dental curable composition according to claim 16 , comprising said copper salt of said benzimidazole compound represented by formula (II).

Assignees

• Sugiura Mariko
• Takei Mitsuru
• Kuraray Noritake Dental Inc

Inventors

• Sugiura Mariko
• Takei Mitsuru

Classifications

• A61K6/887 Primary

  Compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds · CPC title

• A61K6/00 Primary

  Preparations for dentistry · CPC title

• C08L33/02

  Homopolymers or copolymers of acids; Metal or ammonium salts thereof · CPC title

• A61K6/083

  Human Necessities · mapped topic