Amorphous platinum-rich alloys

Patent metadata

Field	Value
Publication number	US-9119447-B2
Application number	US-201313752615-A
Country	US
Kind code	B2
Filing date	Jan 29, 2013
Priority date	Feb 13, 2009
Publication date	Sep 1, 2015
Grant date	Sep 1, 2015

Abstract

According to embodiments of the present invention, an amorphous alloy includes at least Pt, P, Si and B as alloying elements, and has a Pt weight fraction of about 0.925 or greater. In some embodiments, the Pt weight fraction is about 0.950 or greater.

First claim

What is claimed is:

1. A method of manufacturing a bulk metallic glass object comprising:
melting a metallic alloy comprising at least Pt, P, Si and B as alloying elements, wherein the Pt is present in the alloy at a weight fraction of about 0.925 or greater, and wherein the alloy is configured to form the bulk metallic glass object having a thickness of at least 0.5 mm into a molten state to form a molten metallic alloy; and
quenching the molten metallic alloy at a cooling rate sufficiently rapid to prevent crystallization of the alloy.

2. The method of claim 1 , further comprising fluxing the molten alloy prior to quenching by using a reducing agent.

3. The method of claim 2 , wherein the reducing agent comprises dehydrated boron oxide (B 2 O 3 ) melt.

4. The method of claim 1 , the step of melting the metallic alloy comprising melting the metallic alloy at a temperature of at least 100° C. above the liquidus temperature of the alloy.

5. The method of claim 1 , the step of quenching the molten metallic alloy comprising quenching the molten alloy in a quartz tube by water.

6. The method of claim 5 , wherein the quartz tube has an outer diameter of about 20% larger than an inner diameter.

7. The method of claim 5 , wherein the quartz tube has wall thickness equal to about 10% of thickness of the bulk metallic glass object.

8. The method of claim 1 , further comprising forming an amorphous rod of the alloy with a diameter of at least 0.5 mm, the rod being able to be plastically bent.

9. The method of claim 1 , wherein the bulk metallic glass object comprises a jewelry.

10. The method of claim 1 , wherein the alloy comprises an additional alloying element selected from the group consisting of Cu, Ag, Ni, Pd, Au, Co, Fe, Ru, Rh, Ir, Re, Os, Sb, Ge, Ga, Al, and combinations thereof.

11. The method of claim 10 , wherein the Cu is present in an atomic fraction of about 0.015 to about 0.025, the P is present in the alloy in an atomic fraction of about 0.15 to about 0.185, the B is present in the alloy in an atomic fraction of about 0.02 to about 0.06, and the Si is present in the alloy in an atomic fraction of about 0.005 to about 0.025.

12. The method of claim 10 , wherein the atomic ratio of Cu to Ag present in the alloy ranges from about 2 to about 10.

13. The method of claim 12 , wherein the Cu is present in the alloy in an atomic fraction of about 0.01 to about 0.02, the Ag is present in the alloy in an atomic fraction of about 0.001 to about 0.01, the P is present in the alloy in an atomic fraction of about 0.15 to about 0.185, the B is present in the alloy in an atomic fraction of about 0.02 to about 0.06, and the Si is present in the alloy in an atomic fraction of about 0.005 to about 0.025.

14. The method of claim 1 , wherein the Pt is present in the alloy in a weight fraction of about 0.950 or greater.

15. The method of claim 1 , wherein the P is present in an atomic fraction ranging from about 0.10 to about 0.20.

16. The method of claim 1 , wherein the B is present in an atomic fraction ranging from about 0.01 to about 0.10.

17. The method of claim 1 , wherein the Si is present in an atomic fraction ranging from about 0.005 to about 0.05.

18. The method of claim 1 , wherein the alloy comprises an alloy selected from the group consisting of Pt 0.765 P 0.18 B 0.04 Si 0.015 , Pt 0.745 Cu 0.02 P 0.18 B 0.04 Si 0.015 , Pt 0.7435 Cu 0.0215 P 0.18 B 0.04 Si 0.015 , Pt 0.7425 Cu 0.0125 Ni 0.01 P 0.18 B 0.04 Si 0.015 , Pt 0.7456 Cu 0.0159 Ag 0.0035 P 0.18 B 0.04 Si 0.015 , Pt 0.744 Cu 0.015 Ni 0.004 Ag 0.002 P 0.18 B 0.04 Si.su-b. 0.015 , Pt 0.745 Cu 0.013 Ni 0.003 Pd 0.002 Ag 0.002 P. 0.18 B 0.04 Si 0.015 , Pt 0.747 Cu 0.015 Ag 0.003 P 0.18 B 0.04 Si 0.015 , Pt 0.71625 Cu 0.0195 Ni 0.0195 Pd 0.004875 Ag 0.004875 P 0.18 B 0.04 Si 0.015 , Pt 0.7 Cu 0.055 Ag 0.01 P 0.18 B 0.04 Si 0.015 , Pt 0.75 Cu 0.05 P 0.125 B 0.05 Si 0.025 , Pt 0.75 Cu 0.035 Ni 0.015 P 0.125 B 0.05 Si 0.025 , Pt 0.75 Cu 0.035 Pd 0.015 P 0.125 B 0.05 Si 0.025 , Pt 0.75 Cu 0.025 Ni 0.02 Pd 0.005 P 0.125 B 0.05 Si 0.025 , Pt 0.75 Cu 0.025 Ni 0.02 Cr 0.005 P 0.125 B 0.0-5 Si 0.025 , Pt 0.75 Cu 0.02 Ni 0.02 Pd 0.005 Ag 0.005 P 0.125 B 0.05 Si 0.025 , Pt 0.75 Cu 0.02 Ni 0.02 Pd 0.005 CO 0.005 P 0.125 B 0.05 Si 0.025 , Pt 0.75 Cu 0.015 Ni 0.02 Pd 0.005 Ag 0.005 Au 0.005 P 0.125 B 0.05 Si 0.025 , Pt 0.75 Cu 0.015 Ni 0.02 Pd 0.005 Ag 0.005 Pe 0.005 P 0.125 B 0.05 Si 0.025 , Pt 0.73125 Cu 0.0195 Ni 0.0195 Pd 0.004875 Ag 0.004875 P 0.115 B 0.09 Si 0.015 , Pt 0.73125 Cu 0.0195 Ni 0.0195 Pd 0.004875 Ag 0.004875 P 0.1725 B 0.02 Si 0.0275 , Pt 0.73125 Cu 0.0195 Ni 0.0195 Pd 0.004875 Ag 0.004875 P 0.14 B 0.04 Si 0.04 , Pt 0.73125 Cu 0.0195 Ni 0.0195 Pd 0.004875 Ag 0.004875 P 0.17 B 0.04 Si 0.01 , Pt 0.71125 Cu 0.0195 Ni 0.0195 Pd 0.004875 Ag 0.004875 P 0.185 B 0.04 Si 0.015 , wherein the subscripts denotes approximate atomic fractions.

19. The method of claim 1 , wherein the alloy comprises an alloy selected from the group consisting of Pt 0.765 P 0.18 B 0.04 Si 0.015 , Pt 0.745 Cu 0.02 P 0.18 B 0.04 Si 0.015 , Pt 0.7435 Cu 0.0215 P 0.18 B 0.04 Si 0.015 , Pt 0.7425 Cu 0.0125 Ni 0.01 P 0.18 B 0.04 Si 0.015 , Pt 0.7456 Cu 0.0159 Ag 0.0035 P 0.18 B 0.04 Si 0.015 , Pt 0.744 Cu 0.015 Ni 0.004 Ag 0.002 P 0.18 B 0.04 Si-su-b. 0.015 , Pt 0.745 Cu 0.013 Ni 0.003 Pd 0.002 Ag 0.002 P. 0.18 B 0.04 Si 0.015 , Pt 0.747 Cu 0.015 Ag 0.003 P 0.18 B 0.04 Si 0.015 , Pt 0.71625 Cu 0.0195 Ni 0.0195 Pd 0.004875 Ag 0.004875 P 0.18 B 0.04 Si 0.015 , Pt 0.7 Cu 0.055 Ag 0.01 P 0.18 B 0.04 Si 0.015 , wherein the subscripts denote approximate atomic fractions.

20. The method of claim 1 , wherein the alloy comprises an alloy selected from the group consisting of Pt 0.765 P 0.18 B 0.04 Si 0.015 , Pt 0.747 Cu 0.015 Ag 0.003 P 0.18 B 0.04 Si 0.015 , Pt 0.745 Cu 0.02 P 0.18 B 0.04 Si 0.015 , and Pt 0.7 Cu 0.055 Ag 0.01 P 0.18 B 0.04 Si 0.015 , wherein the subscripts denote approximate atomic fractions.

Assignees

• California Inst Of Techn

Inventors

• Demetriou Marios D
• Johnson William L

Classifications

• C22C5/04 Primary

  Alloys based on a platinum group metal · CPC title

• C22C1/11

  Making amorphous alloys · CPC title

• C22C45/003

  with one or more of the noble metals as major constituent · CPC title

• A44C27/003 Primary

  Metallic alloys (alloys in general C22C) · CPC title

• C22C1/002

  Chemistry & Metallurgy · mapped topic