Anode for lithium metal battery, and electrochemical device comprising same
US-12176528-B2 · Dec 24, 2024 · US
US9105934B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9105934-B2 |
| Application number | US-201113081809-A |
| Country | US |
| Kind code | B2 |
| Filing date | Apr 7, 2011 |
| Priority date | Apr 8, 2010 |
| Publication date | Aug 11, 2015 |
| Grant date | Aug 11, 2015 |
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A superior, industrially scalable one-pot ethylene glycol-based wet chemistry method to prepare platinum-adlayered ruthenium nanoparticles has been developed that offers an exquisite control of the platinum packing density of the adlayers and effectively prevents sintering of the nanoparticles during the deposition process. The wet chemistry based method for the controlled deposition of submonolayer platinum is advantageous in terms of processing and maximizing the use of platinum and can, in principle, be scaled up straightforwardly to an industrial level. The reactivity of the Pt(31)-Ru sample was about 150% higher than that of the industrial benchmark PtRu (1:1) alloy sample but with 3.5 times less platinum loading. Using the Pt(31)-Ru nanoparticles would lower the electrode material cost compared to using the industrial benchmark alloy nanoparticles for direct methanol fuel cell applications.
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What is claimed is: 1. A process for depositing a platinum (Pt) adlayer on a ruthenium (Ru) nanoparticle which comprises a polyol reduction. 2. The process according to claim 1 , wherein the polyol reduction is an ethylene glycol reduction. 3. The process according to claim 2 , wherein the ethylene glycol reduction comprises: a. cleaning the surface of the ruthenium nanoparticles so that the surface is free of ruthenium oxide by reducing t…
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