Advanced C2-splitter feed rectifier

Patent metadata

Field	Value
Publication number	US-9103586-B2
Application number	US-63990906-A
Country	US
Kind code	B2
Filing date	Dec 16, 2006
Priority date	Dec 16, 2006
Publication date	Aug 11, 2015
Grant date	Aug 11, 2015

Abstract

Processes to separate a light hydrocarbon stream comprising ethylene, ethane, and C3+ hydrocarbons into an ethylene stream, an ethane stream, and a C3+ hydrocarbon stream, including: feeding the light hydrocarbon stream to a deethanizer; separating the light hydrocarbons in the deethanizer to form a C3+ hydrocarbon bottoms stream and a C2-rich overhead stream comprising ethylene and ethane; separating the C2-rich stream in a C2-rectifier to form a first ethylene stream and an ethane-rich bottoms stream; and separating the ethane-rich bottoms stream in a C2-splitter to form a second ethylene stream and an ethane stream.

First claim

What is claimed is:

1. A process to separate one or more light hydrocarbon streams comprising ethylene, ethane, and C3+ hydrocarbons into an ethylene stream, an ethane stream, and a C3+ hydrocarbon stream, comprising:
feeding the one or more light hydrocarbon streams to a deethanizer;
separating the light hydrocarbons in the deethanizer to form a C3+ hydrocarbon bottoms stream and a C2-rich overhead stream comprising ethylene and ethane;
separating the C2-rich overhead stream in a C2-rectifier to form a first ethylene stream and an ethane-rich bottoms stream, wherein the C2-rectifier is operated without reboiling the ethylene introduced to the C2-rectifier;
separating the ethane-rich bottoms stream in a C2-splitter to form a second ethylene stream and an ethane stream; and
mixing the first ethylene stream and the second ethylene stream to form a combined ethylene stream.

2. The process of claim 1 , wherein the C2-rich overhead stream further comprises acetylene, and the process further comprises
recovering the acetylene in an acetylene recovery unit to form an acetylene stream and a stream lean in acetylene; and
separating the stream lean in acetylene in the C2-rectifier to form the ethylene stream and the ethane-rich bottoms stream.

3. The process of claim 1 wherein the C2-rich overhead stream further comprises acetylene, the process further comprising:
contacting the C2-rich overhead stream with a hydrogen rich stream in an acetylene converter unit to convert the acetylene to ethane and ethylene to form a stream lean in acetylene; and
feeding the acetylene-lean stream to the C2-rectifier.

4. The process of claim 1 wherein the one or more light hydrocarbon streams comprise a product stream from a depropanizer, a demethanizer, a debutanizer, a demethanizer stripper, a cracker furnace effluent, or a combination thereof.

5. The process of claim 1 wherein the C2-splitter is fitted with a reboiler to further increase an amount of the second ethylene stream separated from the ethane-rich bottoms stream.

6. The process of claim 1 , further comprising refluxing a portion of the ethylene as ethylene condensate to the C2-rectifier.

7. The process of claim 1 , further comprising condensing the combined ethylene stream to provide an ethylene condensate and refluxing at least a portion of the ethylene condensate to the C2-splitter.

8. The process of claim 1 , wherein the C2 rich overhead stream is introduced to the C2 rectifier as a vapor.

9. The process of claim 1 , wherein the C2-rich overhead stream is introduced to the C2 rectifier at a location below a bottom tray of the C2 rectifier and wherein the C2 splitter comprises two reboilers and one side condenser.

10. A method to retrofit a process to separate light hydrocarbons comprising operation of a deethanizer to separate the light hydrocarbons into a C3+ hydrocarbon bottoms stream and a C2-rich overheads stream comprising ethylene and ethane, and a C2-splitter to separate the C2-rich overheads into an ethylene stream and an ethane stream, wherein the ethylene is condensed and collected in a C2-splitter overheads condensation system, and wherein the C2-splitter is capacity-limited, the method comprising:
installing a C2-rectifier to separate the C2-rich overheads stream from the deethanizer into a first ethylene stream and an ethane-rich stream, wherein the C2-rectifier is operated without reboiling the ethylene introduced to the C2-rectifier;
installing a line to transmit the C2-rich overheads stream to the C2-rectifier;
installing a line to transmit the ethane-rich stream from the C2-rectifier to the C2-splitter; and
installing a line to transmit the first ethylene stream to the C2-splitter overheads condensation system such that the first ethylene stream mixes with the ethylene stream from the C2-splitter.

11. The method of claim 10 further comprising:
installing a line to transmit a reflux from the C2-splitter overheads condensation system to the C2-rectifier.

12. The method of claim 11 further comprising installing a C2-rectifier overheads condensation system to condense and collect the ethylene in the first ethylene stream and to supply reflux to the C2-rectifier.

13. The method of claim 10 further comprising:
installing a line to transmit reflux from the C2-splitter overheads condensation system to the C2-rectifier; and
installing a line to collect the first ethylene stream as a side-draw from the C2-rectifier.

14. The method of claim 10 wherein the process to separate light hydrocarbons further comprises operating an acetylene recovery unit.

15. The method of claim 10 wherein the C2-splitter is fitted with a reboiler to further increase an amount of the ethylene stream separated from the ethane-rich stream.

16. A method for olefin production, comprising:
separating one or more light hydrocarbon streams comprising ethylene, ethane, and one or more C3+ hydrocarbons into a C2 hydrocarbon-containing stream and a C3+ hydrocarbon-containing stream;
rectifying the C2 hydrocarbon-containing stream in a C2-rectifier into a first ethylene stream and an ethane-rich bottoms stream by contacting the C2 hydrocarbon-containing stream with a liquid, ethylene rich stream, wherein the C2-rectifier is operated without reboiling the ethylene introduced to the C2-rectifier;
separating the ethane-rich bottoms stream to form a second ethylene stream and an ethane stream;
mixing the first ethylene stream and the second ethylene stream to form a combined ethylene stream; and
condensing the combined ethylene stream to provide an ethylene condensate.

17. The method of claim 16 , wherein rectifying the C2 hydrocarbon-containing stream into a first ethylene stream and an ethane-rich bottoms stream is performed in a rectifier wherein vapor from the C2 hydrocarbon-containing stream is contacted with the liquid of the liquid, ethylene rich stream.

18. The method of claim 16 , wherein rectifying the C2 hydrocarbon-containing stream into a first ethylene stream and an ethane-rich bottoms stream is performed in a rectifier having a fractional distillation zone wherein vapor from the C2 hydrocarbon-containing stream is contacted with the liquid of the liquid, ethylene rich stream.

Assignees

• Verma Vijender Kumar
• Kellogg Brown & Root Llc

Inventors

• Verma Vijender Kumar

Classifications

• F25J2290/80

  Retrofitting, revamping or debottlenecking of existing plant · CPC title

• F25J2200/78

  Refluxing the column with a liquid stream originating from an upstream or downstream fractionator column · CPC title

• C07C11/24

  Acetylene (production of acetylene gas by wet methods C10H) · CPC title

• F25J3/0219 Primary

  Refinery gas, cracking gas, coke oven gas, gaseous mixtures containing aliphatic unsaturated CnHm or gaseous mixtures of undefined nature · CPC title

• F25J3/0233

  separation of CnHm with 1 carbon atom or more · CPC title