Method of recovering rare earths from a solid mixture containing a halophosphate and a rare earth compound and solid mixtures suitable for this method

Patent metadata

Field	Value
Publication number	US-9102998-B2
Application number	US-201213981306-A
Country	US
Kind code	B2
Filing date	Jan 19, 2012
Priority date	Jan 25, 2011
Publication date	Aug 11, 2015
Grant date	Aug 11, 2015

Abstract

An acid treatment, in a liquid medium, of a solid containing a halophosphate and a rare earth compound is described. Further described, is the addition of a base to the medium obtained previously and separation of a solid phase from a liquid phase; mixing and calcination of the solid obtained previously with an alkaline solid compound; redispersing the calcined product in water, separation of the solid product from the suspension obtained in the preceding step; dispersing this solid in water and acidification of the dispersion and separation of the solid from this dispersion.

First claim

The invention claimed is:

1. A method of recovering rare earths from a solid mixture containing at least one halophosphate and at least one compound of one or more rare earths, the method comprising the following steps:
(a) carrying out acid treatment of said mixture in a liquid medium having a pH;
(b) adding a base to the liquid medium so as to raise the pH of said liquid medium to a value of at least 1.5, thus obtaining a first solid phase comprising one or more rare earths at least partly as a phosphate and a first liquid phase comprising at least one alkaline-earth element of halophosphate and separating the first solid phase from the first liquid phase;
(c) mixing the first solid phase with an alkaline solid compound to form a resultant mixture and calcining the resultant mixture to form a calcined product;
(d) redispersing the calcined product in water to form a first resultant suspension;
(e) separating a second solid phase comprising one or more rare earths at least partially as a hydroxide and a second liquid phase comprising at least one alkaline element from the first resultant suspension;
(f) dispersing the second solid phase in water to form a second resultant suspension and acidifying the second resultant suspension; and
(g) separating a third solid phase and a third liquid phase comprising at least one rare earth salt from the second resultant suspension.

2. The method as defined by claim 1 , wherein a thermal treatment is carried out on at least one of:
the liquid medium after adding the base,
the first resultant suspension, or
the second resultant suspension after acidficiation.

3. The method as defined by claim 1 , wherein the acid treatment in step (a) or the acidification in step (f) is carried out with nitric acid or hydrochloric acid.

4. The method as defined by claim 1 , wherein step (a) is performed on a solid mixture comprising at least one halophosphate and at least one compound of one or more rare earths, which results from a treatment of recycling of lamps by grinding, wherein the solid mixture is in powder form having grain size below 40 μm and a silica content of at most 10% by weight, relative to the total weight of the solid mixture.

Assignees

• Braconnier Jean-Jacques
• Rollat Alain
• Rhodia Operations

Inventors

• Braconnier Jean-Jacques
• Rollat Alain

Classifications

• C01F17/271

  Chlorides · CPC title

• C01F17/276

  Nitrates · CPC title

• H01J9/52

  Recovery of material from discharge tubes or lamps (H01J9/50 takes precedence) · CPC title

• C22B59/00 Primary

  Obtaining rare earth metals · CPC title

• C09K11/01

  Recovery of luminescent materials · CPC title