Method for separating 1-chloro-3,3,3-trifluoropropene and hydrogen fluoride, and method for producing 1-chloro-3,3,3-trifluoropropene by using same
US-9221732-B2 · Dec 29, 2015 · US
US9102580B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9102580-B2 |
| Application number | US-201214357345-A |
| Country | US |
| Kind code | B2 |
| Filing date | Nov 9, 2012 |
| Priority date | Nov 10, 2011 |
| Publication date | Aug 11, 2015 |
| Grant date | Aug 11, 2015 |
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The present disclosure provides a fluorination process which involves reacting a hydrohaloalkene of the formula R f C—Cl═CH 2 with HF in a reaction zone in the presence of a fluorination catalyst selected from the group consisting of TaF 5 and TiF 4 to produce a product mixture containing a hydrohaloalkane of the formula R f CFClCH 3 , wherein R f is a perfluorinated alkyl group.
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What is claimed is: 1. A process comprising: reacting a hydrohaloalkene of the formula R f CCl═CH 2 with HF in a reaction zone in the presence of a fluorination catalyst selected from the group consisting of TaF 5 and TiF 4 to produce a product mixture comprising a hydrohaloalkane of the formula R f CFClCH 3 , wherein R f is a perfluorinated alkyl group, in an amount effective to form R f CFClCH 3 without substantially forming R f CF 2 CH 3 or R f CHClCH 2 F.…
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