Magnesium alloy for room temperature and manufacturing method thereof

Patent metadata

Field	Value
Publication number	US-9085815-B2
Application number	US-201113053816-A
Country	US
Kind code	B2
Filing date	Mar 22, 2011
Priority date	Mar 29, 2010
Publication date	Jul 21, 2015
Grant date	Jul 21, 2015

Abstract

Provided is a magnesium alloy for room temperature, which is manufactured by adding CaO onto a surface of a molten magnesium alloy and exhausting the CaO through a reduction reaction of the CaO with the molten magnesium alloy. Resultantly, the magnesium alloy with CaO added has more improved room-temperature mechanical properties (tensile strength, yield strength, elongation) than magnesium alloys without using CaO. Furthermore, as the added amount of CaO increases, room-temperature mechanical properties (tensile strength, yield strength, elongation) increase as well.

First claim

What is claimed is:

1. A magnesium-based alloy for a die-casting product, characterized by that the magnesium-based alloy is manufactured by adding 0.05% to 1.2% by weight of CaO into a molten magnesium or magnesium alloy,
wherein the magnesium-based alloy contains a compound formed through a reaction of Ca with the Mg, or other alloy elements of the magnesium alloy to have greater values of room-temperature mechanical properties than those of magnesium or magnesium alloy into which the CaO is not added,
wherein the magnesium-based alloy includes Al whose composition is between about 5% and about 10% by weight of the magnesium-based alloy,
wherein the magnesium-based alloy has a finer and denser microstructure than a microstructure of the magnesium or magnesium alloy before adding the CaO to the magnesium or magnesium alloy,
wherein the room-temperature mechanical properties comprise a room temperature yield strength, a room-temperature tensile strength, and a room-temperature elongation, and
wherein values of the room-temperature yield strength, the room-temperature tensile strength, and the room-temperature elongation all continue to increase as the added amount of CaO increases.

2. The magnesium-based alloy of claim 1 , wherein the added amount of the CaO is greater than 0.3 wt % and no more than 0.9 wt %.

3. The magnesium-based alloy of claim 2 , wherein the added amount of the CaO is greater than 0.3 wt % and no more than 0.7 wt %.

4. The magnesium-based alloy of claim 1 , wherein the compound formed through the reaction of the Ca with the Mg or other alloy elements comprises at least one of Mg 2 Ca, Al 2 Ca and (Mg, Al) 2 Ca.

5. The magnesium-based alloy of claim 1 , wherein the magnesium-based alloy includes Al whose composition is between about 5.45% and about 9.7% by weight of the magnesium-based alloy.

6. The magnesium-based alloy of claim 1 , wherein the microstructure of the magnesium-based alloy continues to become finer and denser as the added amount of CaO increases.

7. A magnesium-based alloy comprising aluminum and an intermetallic compound including Ca, the aluminum being at least about 5% by weight of the magnesium-based alloy, the intermetallic compound including Ca and Mg or other alloy elements of the magnesium-based alloy, the Ca being greater than 0.21% and no more than 0.45% by weight of the magnesium-based alloy,
wherein the magnesium-based alloy has a finer and denser microstructure than a microstructure of the magnesium or magnesium alloy before adding CaO to the magnesium or magnesium alloy to provide the magnesium-based alloy,
wherein the magnesium-based alloy contains the intermetallic compound formed through a reaction of Ca with the Mg, or other alloy elements of the magnesium alloy to have greater values of room-temperature mechanical properties than those of magnesium or magnesium alloy into which the CaO is not added,
wherein the room-temperature mechanical properties comprise a room-temperature yield strength, a room-temperature tensile strength, and a room-temperature elongation, and
wherein values of the room-temperature yield strength, the room-temperature tensile strength, and the room-temperature elongation all continue to increase as an added amount of CaO increases.

8. The magnesium-based alloy of claim 7 , wherein the intermetallic compound is formed by providing a melt including magnesium or magnesium alloy, or both, applying CaO on a surface of the melt, stirring an upper portion of the melt to induce a reduction reaction between the melt and the CaO proximate the surface of the melt, exhausting the CaO proximate the surface of the melt through the reduction reaction between the melt and the CaO, and reacting Ca produced by the exhaustion of the CaO with the at least one of Mg and other alloy elements of the magnesium alloy.

9. The magnesium-based alloy of claim 8 , wherein formation of β-Mg 17 Al 12 phase is suppressed to increase a value of a room-temperature elongation of the magnesium-based alloy.

10. The magnesium-based alloy of claim 7 , wherein the microstructure of the magnesium-based alloy becomes finer and denser in proportion to the added amount of the CaO.

11. The magnesium-based alloy of claim 7 , wherein at least 90% of the intermetallic compound is formed at grain boundaries of the magnesium-based alloy, and no more than 10% of the intermetallic compound is formed within grains of the magnesium-based alloy.

12. The magnesium-based alloy of claim 7 , wherein the magnesium-based alloy includes Al whose composition is at least 5.45% by weight of the magnesium-based alloy.

13. The magnesium-based alloy of claim 12 , wherein the magnesium-based alloy includes Al whose composition is no more than 9.7% by weight of the magnesium-based alloy.

14. A magnesium-based alloy consisting essentially of aluminum, Ca, and an intermetallic compound including Ca, the aluminum being at least about 5% by weight of the magnesium-based alloy, the intermetallic compound including Ca and Mg or other alloy elements of the magnesium-based alloy, the Ca being greater than 0.21% and no more than 0.45% by weight of the magnesium-based alloy,
wherein the magnesium-based alloy has a finer and denser microstructure than a microstructure of the magnesium or magnesium alloy before adding CaO to the magnesium or magnesium alloy to provide the magnesium-based alloy,
wherein the magnesium-based alloy contains the intermetallic compound formed through a reaction of Ca with the Mg, or other alloy elements of the magnesium alloy to have greater values of room-temperature mechanical properties than those of magnesium or magnesium alloy into which the CaO is not added,
wherein the room-temperature mechanical properties comprise a room-temperature yield strength, a room-temperature tensile strength, and a room-temperature elongation, and
wherein values of the room-temperature yield strength, the room-temperature tensile strength, and the room-temperature elongation all continue to increase as an added amount of CaO increases.

Assignees

• Kim Shae K
• Seo Jung-Ho
• Korea Ind Tech Inst

Inventors

• Kim Shae K
• Seo Jung-Ho

Classifications

• C22C23/02 Primary

  with aluminium as the next major constituent · CPC title

• C22C23/00 Primary

  Alloys based on magnesium · CPC title

• C22C1/02

  by melting {(C22C1/1036 takes precedence)} · CPC title