Olefin block copolymer and preparation method thereof

Patent metadata

Field	Value
Publication number	US-9079992-B2
Application number	US-201213980860-A
Country	US
Kind code	B2
Filing date	Jan 19, 2012
Priority date	Jan 21, 2011
Publication date	Jul 14, 2015
Grant date	Jul 14, 2015

Abstract

The present description relates to an olefin block copolymer having excellences in elasticity and heat resistance and its preparation method. The olefin block copolymer includes a plurality of blocks or segments, each of which includes an ethylene or propylene repeating unit and an α-olefin repeating unit at different weight fractions. The olefin block copolymer has a density of 0.85 to 0.92 g/cm 3 , and density X (g/cm 3 ) and TMA (Thermal Mechanical Analysis) value Y (° C.) satisfy a defined relationship.

First claim

What is claimed is:

1. An olefin block copolymer comprising a plurality of blocks or segments, each comprising an ethylene or propylene repeating unit and an α-olefin repeating unit at different weight fractions,
wherein the olefin block copolymer has a density of 0.85 to 0.92 g/cm 3 , and density X (g/cm 3 ) and TMA (Thermal Mechanical Analysis) value Y (° C.) satisfy the following Mathematical Formula 1:
Y≧ 1378.8 X− 1115,   [Mathematical Formula 1]

wherein the olefin block copolymer has a melt index of 0.7 to 4.0 g/10min under a load of 2.16 kg at 190 ° C. and a Shore hardness of 60 to 90, and
wherein the olefin block copolymer has a permanent recovery (after 300% elongation) of 20% to 60%.

2. The olefin block copolymer as claimed in claim 1 , wherein the density X (g/cm 3 ) and the TMA (Thermal Mechanical Analysis) value Y (° C.) satisfy the following Mathematical Formula 1a:
1378.8 X− 1076.3≧ Y ≧ 1378.8 X− 1115  [Mathematical Formula 1a]

3. The olefin block copolymer as claimed in claim 1 , wherein the TMA value is 70 to 140° C.

4. The olefin block copolymer as claimed in claim 1 , wherein the olefin block copolymer comprises a hard segment comprising a first weight fraction of the α-olefin repeating unit and a soft segment comprising a second weight fraction of the α-olefin repeating unit,
wherein the second weight fraction is greater than the first weight fraction.

5. The olefin block copolymer as claimed in claim 4 , wherein the weight fraction of the α-olefin repeating unit contained in the entire block copolymer has a value between the first and second weight fractions.

6. The olefin block copolymer as claimed in claim 4 , wherein the olefin block copolymer comprises 10 to 90 wt.% of the hard segment and a remaining content of the soft segment.

7. The olefin block copolymer as claimed in claim 4 , wherein the hard segment has a higher value than the soft segment in at least one property of the degree of crystallization, density, and melting temperature.

8. The olefin block copolymer as claimed in claim 1 , wherein the olefin block copolymer comprises 30 to 90 wt.% of the ethylene or propylene repeating unit and a remaining content of the a-olefin repeating unit.

9. The olefin block copolymer as claimed in claim 1 , wherein the olefin block copolymer has a melting temperature of 100 to 140 ° C.

10. The olefin block copolymer as claimed in claim 1 , wherein the olefin block copolymer has a weight average molecular weight of 50,000 to 200,000 and a molecular weight distribution of 2.0 to 4.5.

Assignees

• Noh Kyung-Seop
• Lee Nan-Young
• Kim Won-Hee
• An Sang-Eun
• Jeon Sang-Jin
• Park Cheon-Il
• Lee Choong-Hoon
• Lg Chemical Ltd

Inventors

• Noh Kyung-Seop
• Lee Nan-Young
• Kim Won-Hee
• An Sang-Eun
• Jeon Sang-Jin
• Park Cheon-Il
• Lee Choong-Hoon

Classifications

• C08F210/16 Primary

  Copolymers of ethene with alpha-alkenes, e.g. EP rubbers · CPC title

• C08F297/08 Primary

  polymerising mono-olefins · CPC title

• C08L23/14

  Copolymers of propene (C08L23/16 takes precedence) · CPC title

• C08L23/08

  Copolymers of ethene (C08L23/16 takes precedence) · CPC title

• C08F4/6592

  containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring · CPC title