Polyarylene sulfide and preparation method thereof

Patent metadata

Field	Value
Publication number	US-9074048-B2
Application number	US-201113582859-A
Country	US
Kind code	B2
Filing date	Mar 8, 2011
Priority date	Mar 10, 2010
Publication date	Jul 7, 2015
Grant date	Jul 7, 2015

Abstract

This disclosure relates to polyarylene sulfide that may exhibit and maintain excellent properties and a method for preparing the same, wherein the polyarylene sulfide is in the form of pellet of 2 to 10 mm size immediately after melt polymerization, and has residual solvent content of 300 ppm or less, based on the total weight of resin.
The polyarylene sulfide may exhibit and maintain excellent properties, particularly it does not generate foam in the product or stain on the surface, has excellent mechanical properties such as tensile strength, and the like, and thus, it may be usefully applied in the industrial field of preparing polyarylene sulfide and manufacturing a molded product using the same.

First claim

What is claimed is:

1. Polyarylene sulfide that is in the form of a pellet of 2 to 10 mm size immediately after polymerization, and has residual solvent content of 300 ppm or less, based on the total weight of the resin;
wherein the polyarylene sulfide is produced by a method comprising polymerizing a diiodide aromatic compound and an initial amount of a sulfur compound;
adding an additional amount of sulfur compound at a point after the addition of the initial amount of a sulfur compound; and
drying the resulting polyarylene sulfide at 120 to 160° C. for 1 to 2 hours to give polyarylene sulfide in the form of a pellet of 2 to 10 mm size immediately after polymerization, and has residual solvent content of 300 ppm or less, based on the total weight of the resin.

2. The polyarylene sulfide according to claim 1 , wherein the residual solvent includes water and an organic solvent.

3. The polyarylene sulfide according to claim 1 , wherein the polyarylene sulfide has a number average molecular weight of 3,000 to 1,000,000.

4. The polyarylene sulfide according to claim 3 , wherein the polyarylene sulfide has a number average molecular weight of 3,000 to 50,000.

5. The polyarylene sulfide according to claim 1 , wherein degree of dispersion defined by weight average molecular weight to number average molecular weight is 2.0 to 4.0.

6. The polyarylene sulfide according to claim 1 , wherein the polyarylene sulfide has a melting point of 265 to 320° C.

7. A product manufactured by molding the polyarylene sulfide according to claim 1 .

8. The product according to claim 7 , wherein the product is in the form of a film, a sheet, or fiber.

Assignees

• Kim Sung-Gi
• Lim Jae-Bong
• Lee Se-Ho
• Sk Chemicals Co Ltd

Inventors

• Kim Sung-Gi
• Lim Jae-Bong
• Lee Se-Ho

Classifications

• C08G75/14 Primary

  Polysulfides · CPC title

• Y10T428/2982

  Particulate matter [e.g., sphere, flake, etc.] · CPC title

• C08G75/02 Primary

  Polythioethers · CPC title

• C08J2381/04

  Polysulfides · CPC title

• C08J5/18

  Manufacture of films or sheets · CPC title