Resin composition, method for production thereof and multilayered structure

Patent metadata

Field	Value
Publication number	US-9073293-B2
Application number	US-201113637287-A
Country	US
Kind code	B2
Filing date	Mar 23, 2011
Priority date	Mar 25, 2010
Publication date	Jul 7, 2015
Grant date	Jul 7, 2015

Abstract

An object of the present invention is to provide an EVOH-containing resin composition which has superior appearance characteristics and long-run workability in melt molding and enables occurrence of yellowing etc., in melt molding to be inhibited particularly, even in melt molding at high temperatures of, for example, no less than 260° C. Further provided is a multilayered structure molded from the composition. The present invention provides a resin composition containing (A) an ethylene-vinyl alcohol copolymer, (B) a carboxylic acid and/or a carboxylate ion, and (C) a metal ion, wherein the component (B) includes (B2) a multivalent carboxylic acid and/or a multivalent carboxylate ion, and the molar ratio (B2/C) of the multivalent carboxylic acid and the multivalent carboxylate ion (B2) to the metal ion (C) is 0.002 or greater and 2 or less.

First claim

The invention claimed is:

1. A resin composition, comprising:
(A) an ethylene-vinyl alcohol copolymer;
(B) a carboxylic acid, a carboxylate ion, or a mixture thereof; and
(C) a metal ion,
wherein
the component (B) comprises (B2) a multivalent carboxylic acid, a multivalent carboxylate ion, or a mixture thereof,
the metal ion (C) comprises (C1) an alkali metal ion, (C2) an alkaline earth metal ion, or a combination thereof,
a content of the component (B2) ranges from 0.01 μmol/g to 20 μmol/g,
a content of the component (C) ranges from 2.5 μmol/g to 22 μmol/g, and
a molar ratio of the multivalent carboxylic acid and the multivalent carboxylate ion (B2) to the metal ion (C), (B2/C), ranges from 0.002 to 2.

2. The resin composition of claim 1 , wherein at least a pair of carboxyl groups in the component (B2) are linked to each other via a linking group comprising 1 or 2 carbon atom(s).

3. The resin composition of claim 1 , wherein the component (B2) comprises at least three carboxyl groups.

4. The resin composition of claim 1 , wherein the component (C) comprises (C2) an alkaline earth metal ion.

5. The resin composition of claim 1 , further comprising:
(D) a phosphate compound,
wherein a content of the phosphate compound (D) in the resin composition ranges from 5 ppm to 500 ppm in a value of phosphate radical.

6. The resin composition of claim 1 , further comprising:
(E) a boron compound,
wherein a content of the boron compound (E) in the resin composition ranges from 5 ppm to 2,000 ppm in a value of boron element.

7. The resin composition of claim 1 , wherein a content of (B1) a monocarboxylic acid and a monocarboxylate ion as the component (B) in the resin composition is less than 2 μmol/g.

8. The resin composition of claim 1 , wherein
the component (B) further comprises (B1) a monocarboxylic acid, a monocarboxylate ion, or a mixture thereof, and
a content of the monocarboxylic acid and the monocarboxylate ion (B1) in the resin composition is no less than 2 μmol/g.

9. The resin composition of claim 1 , being adapted for use in co-extrusion molding.

10. The resin composition of claim 1 , wherein the component (B2) comprises at least one functional group selected from the group consisting of a hydroxy group, an amino group, and a ketone group.

11. The resin composition of claim 10 , wherein the component (B2) comprises a hydroxy group.

12. The resin composition of claim 1 , wherein the component (C) comprises (C1) an alkali metal ion.

13. The resin composition of claim 12 , wherein a content of the component (C1) in the resin ranges from 2.5 μmol/g to 22 μmol/g.

14. The resin composition of claim 12 , wherein a molar ratio of the component (B2) to the component (C1), (B2/C1), ranges from 0.002 to 2.

15. A method for producing the resin composition of claim 1 , the method comprising:
(I) copolymerizing ethylene and a vinyl ester, to obtain an ethylene-vinyl ester copolymer;
(II) saponifying the ethylene-vinyl ester copolymer, to obtain an ethylene-vinyl alcohol copolymer; and
(III) later than (I), mixing the ethylene-vinyl ester copolymer or the ethylene vinyl alcohol copolymer with (B2′) a multivalent carboxylic acid, a salt of a multivalent carboxylic acid, or a mixture thereof.

16. The method of claim 15 , wherein the mixing is carried out in a system in which the concentration of the vinyl ester is no greater than 1,000 ppm.

17. The method of claim 15 , wherein the mixing step is carried out in the saponifying.

18. The method of claim 15 , further comprising:
(IV) pelletizing a solution comprising the ethylene-vinyl alcohol copolymer obtained in (II), to obtain a water-comprising pellet comprising the ethylene-vinyl alcohol copolymer; and
(V) drying the water-comprising pellet, to obtain a resin composition comprising an ethylene-vinyl alcohol copolymer,
wherein the mixing is carried out after the pelletizing.

19. The method of claim 18 , wherein the mixing is carried out between the pelletizing and the drying by immersing the water-comprising pellet in a solution containing the component (B2′).

20. The method of claim 18 , wherein the mixing is carried out in the pelletizing.

21. A multilayered structure, comprising a layer comprising the resin composition of claim 1 .

Assignees

• Yamasaki Yoshikazu
• Nonaka Yasuhiro
• Somemiya Kazuyuki
• Kuraray Co

Inventors

• Yamasaki Yoshikazu
• Nonaka Yasuhiro
• Somemiya Kazuyuki

Classifications

• B32B27/306 Primary

  comprising vinyl acetate or vinyl alcohol (co)polymers · CPC title

• C08K5/092

  Polycarboxylic acids · CPC title

• C08K5/09

  Carboxylic acids; Metal salts thereof; Anhydrides thereof · CPC title

• C08K5/098

  Metal salts of carboxylic acids · CPC title

• C08L23/0861

  Saponified copolymers, e.g. ethylene vinyl alcohol copolymers · CPC title