Process for the manufacture of methyl limonitrile
US-9458096-B2 · Oct 4, 2016 · US
US9061970B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9061970-B2 |
| Application number | US-86410109-A |
| Country | US |
| Kind code | B2 |
| Filing date | Jan 12, 2009 |
| Priority date | Jan 25, 2008 |
| Publication date | Jun 23, 2015 |
| Grant date | Jun 23, 2015 |
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Compounds containing at least one nitrile functional group are produced by hydrocyanation of an organic compound having at least one site of non-conjugated unsaturation, having from 2 to 20 carbon atoms, by reaction with hydrogen cyanide in the presence of a catalytic system containing a complex of nickel having the oxidation state of zero with at least one organophosphorus ligand selected from the group consisting of organophosphites, organophosphonites, organophosphinites and organosphosphines and a cocatalyst of the Lewis acid type of formula: in which M1 and M2 are each elements selected from the group consisting of zinc, boron, aluminum, cadmium, gallium, indium and tin.
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The invention claimed is: 1. A process for the preparation of a compound containing at least one nitrile functional group, comprising the hydrocyanation of an organic compound having at least one site of non-conjugated unsaturation, having from 5 to 20 carbon atoms, by reaction with hydrogen cyanide in the presence of a catalytic system which comprises a complex of nickel having the oxidation state of zero with at least one organophosphorus ligand selected from the group consisting…
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