Process for the chemoselective reduction of terminally saturated carboxylic esters
US-9193651-B2 · Nov 24, 2015 · US
US9051235B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9051235-B2 |
| Application number | US-201213368130-A |
| Country | US |
| Kind code | B2 |
| Filing date | Feb 7, 2012 |
| Priority date | Feb 7, 2012 |
| Publication date | Jun 9, 2015 |
| Grant date | Jun 9, 2015 |
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The present invention relates to a process for the production of ethanol using a molar excess of hydrogen. A mixed feed of acetic acid and ethyl acetate is fed to a reactor to be converted to ethanol. Hydrogen flow is increased to avoid a negative conversion of ethyl acetate.
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We claim: 1. A process for producing ethanol, comprising: (a) reacting acetic acid, ethyl acetate, and hydrogen in one reactor and in the presence of one catalyst under conditions effective to form a crude ethanol product comprising ethanol, acetic acid, ethyl acetate, and water; and (b) recovering ethanol from the crude ethanol product; wherein the molar ratio of hydrogen to acetic acid fed to the reactor is greater than 12:1; and wherein ethyl acetate conversion is greater…
Chemistry & Metallurgy · mapped topic
Chemistry & Metallurgy · mapped topic
Chemistry & Metallurgy · mapped topic
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