Process of making modified metallocene catalyst, catalyst produced and use thereof

US9045569B2 · US · B2

Patent metadata
FieldValue
Publication numberUS-9045569-B2
Application numberUS-201213979541-A
CountryUS
Kind codeB2
Filing dateJan 12, 2012
Priority dateJan 14, 2011
Publication dateJun 2, 2015
Grant dateJun 2, 2015

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Abstract

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Olefin polymerization catalysts or catalyst systems comprising a mixture, contact product, reaction product or complex comprising as elements or components: (A) at least one metallocene pre-catalyst compound or polymerization active metallocene compound; (B) at least one titanium containing metallocene compound; and when (A) is a metallocene pre-catalyst compound, (C) at least one activator; provided however: (I) the titanium-containing metallocene compound is inactive or substantially inactive for the polymerization of olefins prior to or concurrently with the use of the catalyst system for olefin polymerization. Also disclosed are processes for producing the catalyst system and polyolefins having desirable combinations of properties, including melt index and molecular weight distribution, which properties are particularly desirable for the manufacture of polyolefin film products, especially LLDPE film A preferred catalyst comprises a zirconium or hafnium metal containing metallocene, an inactivated titanocene and a SiO2 support carrier.

First claim

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The invention claimed is: 1. An olefin polymerization catalyst or catalyst system comprising a mixture, contact product, reaction product or complex comprising as elements or components: (A) at least one metallocene pre-catalyst compound or polymerization-active metallocene compound; (B) at least one titanium-containing metallocene compound; and when (A) is a metallocene pre-catalyst compound, (C) at least one compound selected from the group consisting of: (c1) an o…

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What does patent US9045569B2 cover?
Olefin polymerization catalysts or catalyst systems comprising a mixture, contact product, reaction product or complex comprising as elements or components: (A) at least one metallocene pre-catalyst compound or polymerization active metallocene compound; (B) at least one titanium containing metallocene compound; and when (A) is a metallocene pre-catalyst compound, (C) at least one activator; pr…
Who is the assignee on this patent?
Jensen Michael D, Elder Michael J, Singleton Andrew G, and 5 more
What technology area does this patent fall under?
Primary CPC classification C08F4/76. Mapped technology areas include Chemistry & Metallurgy.
When was this patent published?
Publication date Tue Jun 02 2015 00:00:00 GMT+0000 (Coordinated Universal Time) (B2). Legal status and post-grant events are not shown on this page.
What related patents are in patentsdb?
We list 8 related publications on this page (citations in our corpus or others sharing the same primary CPC).