Catalyzed SCR filter and emission treatment system

Patent metadata

Field	Value
Publication number	US-9039982-B2
Application number	US-201414497454-A
Country	US
Kind code	B2
Filing date	Sep 26, 2014
Priority date	Aug 5, 2003
Publication date	May 26, 2015
Grant date	May 26, 2015

Abstract

Provided is a catalyst article for simultaneously remediating the nitrogen oxides (NOx), particulate matter, and gaseous hydrocarbons present in diesel engine exhaust streams. The catalyst article has a soot filter coated with a material effective in the Selective Catalytic Reduction (SCR) of NOx by a reductant, e.g., ammonia.

First claim

What is claimed is:

1. A catalyst article consisting essentially of a wall flow monolith and a catalytic material, wherein the wall flow monolith has a plurality of longitudinally extending passages formed by longitudinally extending walls bounding and defining said passages, wherein the passages comprise inlet passages having an open inlet end and a closed outlet end, and outlet passages having a closed inlet end and an open outlet end, the wall flow monolith has a porosity of from 50% to 60% and an average pore size of from 10 to 25 microns, and the wall flow monolith contains the catalytic material;
wherein the catalytic material comprises an SCR catalyst composition including a slurry-loaded washcoat of a zeolite and base metal selected from copper, the washcoat permeating the walls at a loading up to 2.4 g/in 3 , the wall flow monolith having integrated, NOx and particulate removal efficiency in which presence of the catalytic material in the wall flow monolith catalyzes the oxidation of soot.

2. The catalyst article of claim 1 , wherein the SCR catalyst composition permeates the walls of the monolith at a concentration of at least 1.3 g/in 3 .

3. The catalyst article of claim 2 , wherein there is from 1.6 to 2.4 g/in 3 of SCR catalyst composition disposed on the wall flow monolith.

4. The catalyst article of claim 1 , wherein the SCR catalyst composition is effective to catalyze the reduction of NOx at a temperature below about 600° C. and is able to aid in regeneration of the wall flow monolith by lowering the temperature at which soot captured by the wall flow monolith is combusted.

5. The catalyst article of claim 1 , wherein the SCR catalyst composition has a thermal resistance to degradation at temperatures greater than 650° C.

6. The catalyst article of claim 5 , wherein the SCR catalyst composition is effective to resist degradation upon exposure to sulfur components.

7. The catalyst article of claim 1 , wherein the SCR catalyst composition promotes the oxidation of excess NH 3 with 0 2 .

8. The catalyst article of claim 1 , wherein the base metal component is a copper component and the zeolite of the SCR catalyst composition has a silica to alumina ratio of at least about 10.

9. The catalyst article of claim 8 , wherein the zeolite of the SCR catalyst composition is selected from beta zeolite, USY and ZSM-20.

10. The catalyst article of claim 8 , wherein the zeolite of the SCR catalyst composition is a beta zeolite.

11. The catalyst article of claim 8 , wherein the zeolite of the SCR catalyst composition has pores with a pore diameter of at least about 7 Angstroms and are connected in three dimensions.

12. The catalyst article of claim 1 , wherein the SCR catalyst composition contains a copper promoter present in an amount of from about 0.1 to 30 percent by weight of the total weight of promoter plus zeolite.

13. The catalyst article of claim 1 , wherein the SCR catalyst composition contains a copper promoter present in an amount of from about 1 to 5 percent by weight of the total weight of promoter plus zeolite.

14. The catalyst article of claim 1 , wherein the wall flow monolith has a wall porosity of from 55% to 60% with an average pore size of from 10 to 25 microns.

15. The catalyst article of claim 1 , wherein the longitudinally extending walls have an inlet side and an opposing outlet side and SCR catalyst is coated on both the inlet and outlet sides of the walls.

16. A catalyst article consisting essentially of a wall flow monolith and a catalytic material, wherein the wall flow monolith has a plurality of longitudinally extending passages formed by longitudinally extending walls bounding and defining said passages, wherein the passages comprise inlet passages having an open inlet end and a closed outlet end, and outlet passages having a closed inlet end and an open outlet end, the wall flow monolith has a porosity of from 50% to 60% and an average pore size of from 10 to 25 microns, and the wall flow monolith contains the catalytic material;
wherein the catalytic material comprises an SCR catalyst composition including a slurry-loaded washcoat of a zeolite and base metal selected from a copper component, the washcoat permeating the walls at a loading up to 1.3 g/in 3 ,
the wall flow monolith having integrated, NOx and particulate removal efficiency in which presence of the catalytic material in the wall flow monolith catalyzes the oxidation of soot.

17. The catalyst article of claim 16 , wherein there is from 1.6 to 2.4 g/in 3 of SCR catalyst composition disposed on the wall flow monolith.

18. The catalyst article of claim 16 , wherein the SCR catalyst composition contains a copper promoter present in an amount of from about 0.1 to 30 percent by weight of the total weight of promoter plus zeolite.

19. The catalyst article of claim 16 , wherein the SCR catalyst composition has a thermal resistance to degradation at temperatures greater than 650° C.

20. The catalyst article of claim 19 , wherein the SCR catalyst composition in effective to resist degradation upon exposure to sulfur components.

21. The catalyst article of claim 16 , wherein the SCR catalyst composition promotes the oxidation of excess NH 3 with 0 2 .

22. A catalyst article consisting essentially of a wall flow monolith and a catalytic material,
wherein the wall flow monolith has a plurality of longitudinally extending passages formed by longitudinally extending walls bounding and defining said passages, wherein the passages comprise inlet passages having an open inlet end and a closed outlet end, and outlet passages having a closed inlet end and an open outlet end, the wall flow monolith has a porosity of from 50% to 55% and an average pore size of from 10 to 25 microns, and the wall flow monolith contains the catalytic material;
wherein the catalytic material comprises an SCR catalyst composition including a slurry-loaded washcoat of a zeolite and base metal selected from copper, the washcoat permeating the walls, the wall flow monolith having integrated, NOx and particulate removal efficiency in which presence of the catalytic material in the wall flow monolith catalyzes the oxidation of soot.

23. The catalyst article of claim 22 , wherein the SCR catalyst composition has a thermal resistance to degradation at temperatures greater than 650° C.

24. The catalyst article of claim 23 , wherein the SCR catalyst composition is effective to resist degradation upon exposure to sulfur components.

25. The catalyst article of claim 22 , wherein the SCR catalyst composition promotes the oxidation of excess NH 3 with O 2 .

26. The catalyst article of claim 22 , wherein the SCR catalyst composition contains a copper promoter present in an amount of from about 0.1 to 30 percent by weight of the total weight of promoter plus zeolite.

27. The catalyst article of claim 22 , wherein the wall flow monolith is effective to remove soot by deposition of particulate matter on the wall flow monolith and the catalytic material contains a component to promote combustion of the soot in the absence of a fine pore path layer on the wall of the wall flow monolith.

Assignees

• Basf Corp

Inventors

• Patchett Joseph A
• Dettling Joseph C
• Przybylski Elizabeth A

Classifications

• B01D53/944

  Simultaneously removing carbon monoxide, hydrocarbons or carbon making use of oxidation catalysts (three-way-catalysts [TWC] B01D53/9445) · CPC title

• B01D5/009

  Collecting, removing and/or treatment of the condensate · CPC title

• B01D2251/2062

  Ammonia · CPC title

• B01J29/7615 Primary

  Zeolite Beta · CPC title

• B01D19/0005

  with one or more auxiliary substances · CPC title