Fracturing fluid water reuse system and method

Patent metadata

Field	Value
Publication number	US-9027646-B2
Application number	US-201113192708-A
Country	US
Kind code	B2
Filing date	Jul 28, 2011
Priority date	Jul 28, 2010
Publication date	May 12, 2015
Grant date	May 12, 2015

Abstract

Methods of processing a fluid recovered from an oil or gas extraction operation for reuse in a hydraulic fracturing fluid are described. The methods include providing an amount of a produced fluid composition containing iron and suspended solids and controlling at least one of the conductivity, iron content, oxidative strength, and pH of the composition, such that Fenton's reagent is formed in situ. Also described are hydraulic fracturing fluids produced using fluid recovered from an oil or gas production process and treated in accordance with the methods described herein as well as systems for preparing a hydraulic fracturing fluid having, as a fluid source, fluid recovered from an oil or gas production process that has been treated in accordance with the methods described herein.

First claim

What is claimed is:

1. A method of reusing a produced fluid in a hydraulic fracturing operation, the method comprising:
receiving the produced fluid from a well as a return of at least a hydraulic fracturing fluid in a hydraulic fracturing operation;
providing a production brine recovered from an oil or gas extraction operation, the production brine having a conductivity of at least 150,000 μmhos/cm;
measuring a conductivity of the produced fluid;
treating the produced fluid by adding thereto at least the production brine to form a treated produced fluid, wherein the treating of the produced fluid comprises:
increasing the conductivity of the produced fluid to at least 100,000 μmhos/cm;
increasing an iron content of the produced fluid to at least 50 ppm; and adjusting the pH level of the produced fluid to between 5.0 and 6.5; and
thereafter increasing an oxidation-reduction potential value of the produced fluid to at least 250 mV, thereby forming Fenton's reagent in situ within the treated produced fluid;
storing the treated produced fluid for a sufficient time to allow flocculation of suspended solids in the treated produced fluid, thereby forming a clarified produced fluid from which the suspended solids have been removed; and
injecting the clarified produced fluid into a well as part of a hydraulic fracturing fluid;
wherein reaction of the Fenton's reagent causes formation of complexes of iron and the suspended solids; and wherein the formation of the complexes causes coagulation and flocculation of the suspended solids.

2. The method according to claim 1 , wherein the treating step comprises increasing the conductivity of the produced fluid to at least 150,000 μmhos/cm.

3. The method according to claim 1 , further comprising adding a friction reducer to the clarified produced fluid, the friction reducer being mixed with at least one of the clarified produced fluid or an aqueous solution for unwinding at least one hour before the step of injecting the clarified produced fluid into the well.

4. The method according to claim 3 , further comprising, prior to injecting the hydraulic fracturing fluid into the well, injecting an acid composition comprising an acid and a friction reducer into the well.

5. The method according to claim 1 , further comprising mixing the clarified produced fluid at a rate and frequency sufficient to prevent the occurrence of density-based striation.

6. The method of claim 1 , wherein the iron content is controlled through the addition of an iron salt to the produced fluid.

7. The method of claim 1 , wherein the oxidation-reduction potential value of the produced fluid is controlled by a factor selected from the group consisting of: addition of hydrogen peroxide, addition of peracetic acid, aeration of the produced fluid, and combinations thereof.

8. The method of claim 1 , wherein the suspended solids are selected from the group consisting of kerogen, asphaltenes, acrylamide solids, and combinations thereof.

9. The method of claim 1 , further comprising adding to the produced fluid a friction reducer.

10. The method of claim 9 , wherein the friction reducer is selected from the group consisting of an acrylic-acid-AMPS-polyacrylamide terpolymer, a brine dispersion AMPS-polyacrylamide copolymer, a non-ionic polyacrylamide polymer, and combinations thereof.

11. The method of claim 9 , wherein, prior to being added to the composition, the friction reducer is pre-treated in an aqueous solution to increase the hydration thereof.

12. The method of claim 1 , further comprising adding to the produced fluid a scale inhibitor.

13. The method of claim 12 , wherein the scale inhibitor is a sulphonated phosphinocarboxylic acid copolymer.

14. The method of claim 1 , further comprising adding to the produced fluid an iron dispersant.

15. The method of claim 14 , wherein the iron dispersant is a sulphonated, carboxylated, non-ionic terpolymer.

16. The method of claim 1 , further comprising mixing the produced fluid at a rate and frequency sufficient to prevent the occurrence of density-based striation.

17. A hydraulic fracturing fluid, comprising fluid recovered from an oil or gas extraction operation treated in accordance with the method of claim 1 .

18. The hydraulic fracturing fluid of claim 17 , wherein the fluid recovered from an oil or gas extraction operation comprises flow back water and production brine.

19. The hydraulic fracturing fluid of claim 17 , further comprising a hydraulic fracturing fluid material selected from the group consisting of a friction reducer, an iron dispersant, a scale inhibitor, and combinations thereof.

20. The hydraulic fracturing fluid of claim 1 , further comprising a friction reducer, wherein the friction reducer is selected from the group consisting of an acrylic-acid-AMPS-polyacrylamide terpolymer, a brine dispersion AMPS-polyacrylamide copolymer, a non-ionic polyacrylamide polymer, and combinations thereof.

21. A system for preparing a hydraulic fracturing fluid, comprising, in series for fluid flow therebetween:
a fluid source, comprising fluid recovered from an oil or gas extraction operation that has been treated in accordance with the method of claim 1 ;
a friction reducer inlet for supplying a friction reducer; and
a mixing apparatus.

22. The system of claim 21 , further comprising a friction reducer holding tank for pre-treating the friction reducer in an aqueous solution.

23. The system of claim 21 , further comprising an in-line conductivity analyzer between the fluid source and the mixing apparatus.

24. The system of claim 23 , wherein data from the conductivity analyzer is provided to a feedback control system for adjusting the amount and type of friction reducer added to the hydraulic fracturing fluid.

25. A method of hydraulic fracturing, comprising:
pre-treating a well by injecting an acid composition comprising an acid and a friction reducer into a well bore; and
injecting a hydraulic fracturing fluid into the well bore, the hydraulic fracturing fluid comprising fluid recovered from an oil or gas extraction operation treated in accordance with the method of claim 1 .

Assignees

• Svarczkopf Timothy C
• Weaver Iii Dalton R
• Bender Jon M
• Strickler Jesse J
• Chevron Usa Inc

Inventors

• Svarczkopf Timothy C
• Weaver Iii Dalton R
• Bender Jon M
• Strickler Jesse J

Classifications

• C09K8/62 Primary

  Compositions for forming crevices or fractures · CPC title

• C09K8/72

  Eroding chemicals, e.g. acids · CPC title