Methods and systems for catalyst delivery

Patent metadata

Field	Value
Publication number	US-9023958-B2
Application number	US-201214357704-A
Country	US
Kind code	B2
Filing date	Oct 25, 2012
Priority date	Nov 30, 2011
Publication date	May 5, 2015
Grant date	May 5, 2015

Abstract

A method for the delivery of a catalyst to a polymerization reactor is disclosed, comprising: contacting a catalyst with a carrier fluid comprising an inert hydrocarbon in gaseous form, the inert hydrocarbon having a normal boiling point of about −1° C. to about 81° C.; and flowing the carrier fluid to the polymerization reactor such that the carrier fluid transports the catalyst to the polymerization reactor. A catalyst delivery system is disclosed, comprising: a catalyst vessel for containing a catalyst; a catalyst injection line for delivering the catalyst to a polymerization reactor, the catalyst injection line being in fluid communication with the catalyst vessel and the polymerization reactor; and a carrier fluid line in fluid communication with the catalyst injection line for delivering a carrier fluid comprising an inert hydrocarbon to the catalyst injection line, the inert hydrocarbon having a normal boiling point of about −1° C. to about 81° C.

First claim

What is claimed is:

1. A method for the delivery of a catalyst to a polymerization reactor, comprising:
heating a fluid comprising an inert liquid hydrocarbon in a heat exchanger to vaporize at least a portion of the inert liquid hydrocarbon and form an inert hydrocarbon in gaseous form;
contacting a catalyst with a carrier fluid comprising the inert hydrocarbon, the inert hydrocarbon having a normal boiling point of about −1° C. to about 81° C.; and
flowing the carrier fluid to the polymerization reactor such that the carrier fluid transports the catalyst to the polymerization reactor, wherein the inert hydrocarbon is present in the carrier fluid in a gaseous form or a combination of liquid and gaseous form.

2. The method of claim 1 , wherein the inert hydrocarbon comprises n-butane.

3. The method of claim 1 , wherein the inert hydrocarbon comprises isopentane.

4. The method of claim 1 , wherein the inert hydrocarbon comprises a saturated C5 or a saturated C6 hydrocarbon.

5. The method of claim 1 , wherein the carrier fluid further comprises nitrogen.

6. The method of claim 1 , wherein the inert hydrocarbon in gaseous form at least partially condenses as the carrier fluid flows to the polymerization reactor.

7. The method of 1 , wherein at least about 90% of the liquid hydrocarbon is vaporized by the heat exchanger.

8. The method of claim 1 , further comprising flashing a fluid comprising an inert liquid hydrocarbon across a valve to form the inert hydrocarbon in gaseous form present in the carrier fluid.

9. The method of claim 8 , comprising heating the fluid comprising the liquid hydrocarbon in a heat exchanger prior to flashing the fluid across the valve.

10. The method of claim 1 , further comprising heating a catalyst injection line, wherein the carrier fluid flows to the reactor in the catalyst injection line.

11. A polymerization process comprising: polymerizing an olefin in the polymerization reactor in the presence of the catalyst, wherein the catalyst is introduced into the polymerization reactor in accordance with claim 1 .

12. The polymerization process of claim 11 , wherein the process is a gas phase process and the reactor is a fluidized bed reactor.

13. The polymerization process of claim 11 , wherein the catalyst is introduced into the reactor continuously.

14. A catalyst delivery system, comprising:
a catalyst vessel for containing a catalyst;
a catalyst injection line for delivering the catalyst to a polymerization reactor, the catalyst injection line being in fluid communication with the catalyst vessel and the polymerization reactor;
a carrier fluid line in fluid communication with the catalyst injection line for delivering a carrier fluid comprising an inert hydrocarbon in gaseous form to the catalyst injection line, the inert hydrocarbon having a normal boiling point of about −1° C. to about 81° C.;
a hydrocarbon feed line in fluid communication with the carrier fluid line;
and a heat exchanger coupled to the hydrocarbon feed line for heating an inert hydrocarbon in the hydrocarbon feed line.

15. The catalyst delivery system of claim 14 , further comprising a valve coupled to the hydrocarbon feed line for flashing liquid inert hydrocarbon in the hydrocarbon feed line.

Assignees

• Univation Tech Llc

Inventors

• Wright Dale A
• Parrish John R
• Swecker Ii James L
• Goode Mark G

Classifications

• C08F110/02 Primary

  Ethene · CPC title

• Y10S526/919

  Catalyst injection technique in addition polymerization processes · CPC title

• C08F10/00

  Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond · CPC title

• B01J8/24

  according to "fluidised-bed" technique (B01J8/20 takes precedence) · CPC title

• B01J2219/00042

  Features relating to reactants and process fluids · CPC title