Thermoplastic resin composition having excellent surface gloss, reflectance, anti-yellowing property and moldability

Patent metadata

Field	Value
Publication number	US-9018296-B2
Application number	US-201314044906-A
Country	US
Kind code	B2
Filing date	Oct 3, 2013
Priority date	Dec 31, 2012
Publication date	Apr 28, 2015
Grant date	Apr 28, 2015

Abstract

A thermoplastic resin composition includes (A) a thermoplastic resin; (B) an inorganic filler; (C) a white pigment; (D) a photostabilizer; and (E) sodium phosphate salt, wherein the thermoplastic resin composition comprises about 0.1 to about 4.7% by weight of the inorganic filler (B) based on 100% by weight of a base resin composition including the thermoplastic resin (A), the inorganic filler (B), and the white pigment (C), wherein the thermoplastic resin composition can have excellent surface gloss, reflectance, anti-yellowing property and moldability.

First claim

That which is claimed is:

1. A thermoplastic resin composition comprising (A) about 29.9 to about 70% by weight of a thermoplastic resin; (B) about 0.1 to about 4.7% by weight of an inorganic filler; (C) about 29.9 to about 70% by weight of a white pigment; (D) about 0.01 to about 2 parts by weight of a photostabilizer; and (E) about 0.01 to about 2 parts by weight of a sodium phosphate salt, wherein the amounts of the thermoplastic resin (A), the inorganic filler (B), and the white pigment (C) are based on 100% by weight of a base resin composition including the thermoplastic resin (A), the inorganic filler (B), and the white pigment (C), and wherein the amounts of the photostabilizer (D) and the sodium phosphate salt (E) are based on about 100 parts by weight of the base resin composition comprising (A), (B) and (C).

2. The thermoplastic resin composition of claim 1 , wherein the thermoplastic resin (A) is (a1) an aromatic polyamide resin, (a2) a high heat resistant polyester resin, or a combination thereof.

3. The thermoplastic resin composition of claim 2 , wherein the aromatic polyamide resin (a1) is manufactured by polycondensation of a dicarboxylic component comprising about 10 to about 100 mole% of an aromatic dicarboxylic acid and a diamine component including a C 4 to C 20 aliphatic, alicyclic diamine or a combination thereof.

4. The thermoplastic resin composition of claim 2 , wherein the high heat resistant polyester resin (a2) is manufactured by polycondensation of an aromatic dicarboxylic acid component and a diol component comprising alicyclic diol.

5. The thermoplastic resin composition of claim 2 , wherein the aromatic polyamide resin (a1) has a melting point of 200 to 380 ° C. and a repeating unit represented by Chemical Formula 3 as below:

wherein m is an integer from 4 to 12, and n is an integer from 50 to 500.

6. The thermoplastic resin composition of claim 2 , wherein the high heat resistant polyester resin (a2) has a melting point of 200 to 380° C. and comprises a repeating unit represented by Chemical Formula 4:

wherein 1 is an integer from 50 to 500.

7. The thermoplastic resin composition of claim 1 , wherein the inorganic filler (B) comprises carbon fiber, glass fiber, boron fiber, glass beads, glass flakes, carbon black, clay, kaolin, talc, mica, calcium carbonate, wollastonite, potassium titanate whisker, aluminum borate whisker, zinc oxide whisker, calcium whisker, or a combination thereof.

8. The thermoplastic resin composition of claim 1 , wherein the inorganic filler (B) is wollastonite.

9. The thermoplastic resin composition of claim 8 , wherein the wollastonite has an average length of about 0.1 to about 100 μm.

10. The thermoplastic resin composition of claim 1 , wherein the white pigment (C) comprises titanium oxide, zinc oxide, zinc sulfide, white lead, zinc sulfate, barium sulfate, calcium carbonate, aluminum oxide, or a combination thereof.

11. The thermoplastic resin composition of claim 1 , wherein the photostabilizer (D) comprises a benzophenone-based compound, a salicylate-based compound, a benzotriazol-based compound, an acrylonitrile-based compound, a hindered amine-based compound, a hindered phenol-based compound, or a combination thereof.

12. The thermoplastic resin composition of claim 1 , wherein the sodium phosphate salt (E) comprises sodium monohydrogen phosphate, sodium dihydrogen phosphate, sodium phosphate, sodium pyrophosphate, sodium acid pyrophosphate, or a combination thereof.

13. A molded article comprising the thermoplastic resin composition of the claim 1 .

14. The molded article of claim 13 , wherein the molded article has an initial reflectance of about 90% or more measured using a colorimeter at 440 nm wavelength;
reflectance reduction of less than about 4% measured at 440 nm wavelength before and after being left at 85° C. and 85% relative humidity for 300 hours; and a yellowing index change (ΔYI ) of less than about 4 measured before and after being left at 85° C. and 85% relative humidity for 300 hours.

15. The molded article of claim 14 , wherein the molded article is LED reflector.

16. The thermoplastic resin composition of claim 1 , wherein a molded article formed of the composition has a spiral flow length of about 200 to about 300 mm measured under a molding temperature of 130 ° C. and injection molding temperature of 330 ° C., wherein a mold has a 0.5 mm ×5 mm (thick ×width) spiral cavity.

Assignees

• Cheil Ind Inc

Inventors

• Lee Sang Hwa
• Lim Jong Cheol
• Baek In Geol
• Jung Yoo Jin

Classifications

• C08L77/06 Primary

  Polyamides derived from polyamines and polycarboxylic acids (C08L77/10 takes precedence) · CPC title

• C08L77/10 Primary

  Polyamides derived from aromatically bound amino and carboxyl groups of amino-carboxylic acids or of polyamines and polycarboxylic acids · CPC title

• C08K3/00

  Use of inorganic substances as compounding ingredients · CPC title

• C08G69/32

  from aromatic diamines and aromatic dicarboxylic acids with both amino and carboxylic groups aromatically bound · CPC title

• C08L67/00

  Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain (of polyester-amides C08L77/12; of polyester-imides C08L79/08); Compositions of derivatives of such polymers · CPC title