Self assembled multi-layer nanocomposite of graphene and metal oxide materials

Patent metadata

Field	Value
Publication number	US-9017867-B2
Application number	US-46285709-A
Country	US
Kind code	B2
Filing date	Aug 10, 2009
Priority date	Aug 10, 2009
Publication date	Apr 28, 2015
Grant date	Apr 28, 2015

Abstract

Nanocomposite materials having at least two layers, each layer consisting of one metal oxide bonded to at least one graphene layer were developed. The nanocomposite materials will typically have many alternating layers of metal oxides and graphene layers, bonded in a sandwich type construction and will be incorporated into an electrochemical or energy storage device.

First claim

The invention claimed is:

1. A nanocomposite material comprising at least two layers, each layer including a metal oxide layer directly bonded to a graphene layer, wherein the graphene layer has a thickness of from about 0.5 nm to 50 nm, and the metal oxide layers and graphene layers are alternatingly positioned in the at least two layers and bonded to one another in a stacked configuration.

2. The nanocomposite material of claim 1 wherein said metal oxide is M x O y , and where M is selected from the group consisting of Ti, Sn, Ni, Mn, Si, V and combinations thereof.

3. The nanocomposite material of claim 1 wherein said metal oxide is tin oxide.

4. The nanocomposite material of claim 1 wherein said metal oxide is mesoporous.

5. The nanocomposite material of claim 1 wherein said nanocomposite material has a specific capacity of greater than about 400 mAh/g.

6. A method for forming an ordered nanocomposite material comprising the steps of:
providing graphene in a suspension;
dispersing the graphene with a surfactant;
adding a metal oxide precursor;
precipitating the metal oxide and allowing the graphene and the metal oxide to organize into self assembled structures, thereby forming a nanocomposite material precipitate having a series of ordered graphene and metal oxide layers, wherein the metal oxide layers and graphene layers are alternating positioned in a sandwich configuration and the metal oxide layers are directly bonded to the graphene layers forming the series of ordered layers.

7. The method of claim 6 , wherein the step of precipitating is maintained for about one to about 24 hours.

8. The method of claim 7 including the further step of providing the suspension as containing water.

9. The method of claim 7 further comprising the step of heating the precipitate from 50 to 500 degrees C. to condense the metal oxide layers on the graphene layers.

10. The method of claim 6 further comprising the step of heating the precipitate from 50 to 500 degrees C. to remove the surfactant.

11. An energy storage device comprising a nanocomposite material which has at least two layers, each layer including a metal oxide layer directly bonded to a graphene layer, wherein the graphene layer has a thickness of from about 0.5 nm to 50 nm, and the metal oxide layers and graphene layers are alternatingly bonded to one another in the at least two layers.

12. The energy storage device of claim 11 , wherein said nanocomposite material has a specific capacity of greater than about 400 mAh/g.

13. The energy storage device of claim 11 , wherein the energy storage device is an electrochemical device having an anode, a cathode, an electrolyte, and a current collector.

14. The energy storage device of claim 11 , wherein at least one of an electrode, an anode, a cathode, a separator, a current collector, an electrolyte, and combinations thereof includes a nanocomposite material which has at least two layers, each layer including a metal oxide layer directly bonded to the graphene layer, wherein the metal oxide layers and graphene layers alternate in position in the at least two layers forming a sandwich configuration.

15. The energy storage device of claim 13 , wherein the anode contains the nanocomposite material, and wherein the anode contains less than 10% of carbon-based material by weight.

16. The energy storage device of claim 13 , wherein the anode contains the nanocomposite material, and wherein the anode contains less than 5% of carbon-based material by weight.

17. The energy storage device of claim 13 , wherein the cathode contains the nanocomposite material, and wherein the cathode contains less than 5% of carbon-based material by weight.

18. The energy storage device of claim 13 , wherein the cathode contains the nanocomposite material, and wherein the cathode contains less than 2.5% carbon-based material by weight.

19. The energy storage device of claim 11 wherein the electrochemical device is a lithium ion battery.

20. A lithium ion battery electrode comprising a nanocomposite material which has at least two layers bonded to one another, each layer including a metal oxide layer directly bonded to a graphene layer, wherein the graphene layer has a thickness from about 0.5 nm to 50 nm, and wherein the metal oxide layers and graphene layers are alternatingly positioned in the at least two layers, and wherein said nanocomposite material has a specific capacity of greater than about 400 mAh/g, and wherein the layers are provided as an ordered, three dimensional assembly.

21. A nanocomposite material formed by the steps comprising: providing graphene in a suspension;
dispersing the suspension with a surfactant to provide multiple graphene layers wherein the graphene layer has a thickness of from about 0.5 nm to 50 nm;
adding a metal oxide precursor;
precipitating the metal oxide and allowing the graphene layers and the metal oxide to organize into self assembled structures thereby forming a series of ordered layers bonded to one another, wherein each layer comprises a metal oxide layer bonded to at least one graphene layer, wherein the metal oxide layers and graphene layers are alternatingly positioned in the ordered layers; and
heating the metal oxide layers and graphene layers to a temperature sufficient to remove the surfactant such that the metal oxide layers are directly bonded to the graphene layers.

22. The nanocomposite material of claim 21 , wherein the nanocomposite material is formed into an ordered three-dimensional superstructure having multi length and multiphase building blocks.

23. The nanocomposite material of claim 21 , wherein the graphene layers have a thickness between 3 nm and 20 nm.

24. The nanocomposite material of claim 21 , wherein the nanocomposite material has a specific capacity of greater than about 400 mAh/g.

Assignees

• Liu Jun
• Aksay Ilhan A
• Choi Daiwon
• Kou Rong
• Nie Zimin
• Wang Donghai
• Yang Zhenguo
• Battelle Memorial Institute
• Univ Princeton

Inventors

• Liu Jun
• Aksay Ilhan A
• Choi Daiwon
• Kou Rong
• Nie Zimin
• Wang Donghai
• Yang Zhenguo

Classifications

• H01M4/505

  of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy · CPC title

• H01M4/485

  of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy (H01M4/505, H01M4/525 take precedence) · CPC title

• H01M4/48 Primary

  of inorganic oxides or hydroxides · CPC title

• Y02E60/13

  Energy storage using capacitors · CPC title

• Y10T428/30

  Self-sustaining carbon mass or layer with impregnant or other layer · CPC title