Nanostructure device that enhances fluorescence and luminescence

Patent metadata

Field	Value
Publication number	US-9007575-B2
Application number	US-201414459239-A
Country	US
Kind code	B2
Filing date	Aug 13, 2014
Priority date	May 21, 2010
Publication date	Apr 14, 2015
Grant date	Apr 14, 2015

Abstract

Microstructures and nanostructures ( 100 ) consisting of a substrate ( 110 ), an array of pillars ( 120 ) capped by metallic disc ( 130 ), metallic dots (clusters or granules) ( 140 ) disposed on the sidewalls of the pillars, and a metallic backplane ( 150 ) that can interact to enhance a local electric field, the absorption of the light, and the radiation of the light are disclosed. Methods to fabricate the structures ( 100 ) are also disclosed. Applications of the structures to enhance the optical signals in the detection of molecules and other materials on a structure surface, such as fluorescence, photoluminescence and surface enhanced Raman Scattering (SERS) are also disclosed.

First claim

The invention claimed is:

1. A nanostructure device, comprising:
a substrate; and
one or a plurality of pillars extending from a surface of said substrate, wherein at least one of said pillars comprises:
a metallic disc on top of the pillar, a metallic back plane at the foot of the pillar, said metallic back plane covering a substantial portion of said substrate surface near the foot of the pillar; and at least one metallic dot structure disposed on an external sidewall surface of the pillar;
wherein the device comprises a nanogap defined by one or more of (i) said disc and said dot structure, (ii) said disc and said back plane, or (iii) said dot structure and said back plane, and
wherein said device enhances fluorescence or luminescence of a substance that is placed on or in proximity to said device.

2. The nanostructure device of claim 1 , wherein said fluorescence or luminescence has a wavelength range from 100 nm to 8000 nm.

3. The nanostructure device of claim 1 , wherein:
said at least one pillar has a height in the range from 5 nm to 7000 nm and a lateral dimension in the range from 5 nm to 8000 nm; and
the lateral dimension of said metallic disc is in the range from 70 nm to 1500 nm; and
said dot structure has a lateral size from 3 nm to 600 nm
said nanogap is in a range from 0.5 nm to 600 nm; and
the thickness of said disc is in the range of 1 nm to 500 nm; and
the thickness of said metallic back plane is selected from 1 nm to 2000 nm; and
said plurality of pillars have a spacing between two nearest neighboring pillars in the range from 2 nm to 4,000 nm.

4. The nanostructure device of claim 1 , wherein the top of said at least one pillar has approximately a round shape.

5. The nanostructure device of claim 1 , wherein the top of said at least one pillar has an approximate shape selected from the group of shapes consisting of polygonal, pyramidal, elliptical, and elongated bar shaped, and their combination thereof with round shape, and any combination thereof.

6. The nanostructure device of claim 1 , wherein said device comprises a plurality of pillars, said plurality of pillars have a spacing between two nearest neighboring pillars in the range from 2 nm to less than 200 nm, and the material of said pillars comprises a material chosen from insulators and semiconductors.

7. The nanostructure device of claim 1 , wherein the lateral dimension of said pillar is in the range of 5 nm to less than 70 nm.

8. The nanostructure device of claim 1 , wherein the height of said pillar is in the range of 12 nm to 84 nm.

9. The nanostructure device of claim 1 , wherein the height of said pillar is in the range of larger than 84 nm to less than 130 nm.

10. The nanostructure device of claim 1 , wherein the shape of said metallic disc comprises substantially the same shape as the top of said pillar that supports said metallic disc.

11. The nanostructure device of claim 1 , wherein the shape of said metallic disc comprises similar shape but larger lateral dimension than said pillar that supports said disc, and the difference in lateral dimension of the said pillar and said disc is in the range from greater than 0 to 200 nm.

12. The nanostructure device of claim 1 , wherein the lateral dimension of said disc is in the range of 5 nm to less than 50 nm.

13. The nanostructure device of claim 1 , wherein the lateral dimension of said disc is in the range of larger than 50 nm to less than 70 nm.

14. The nanostructure device of claim 1 , wherein the thickness of said disc is in the range of 1 nm to less than 40 nm.

15. The nanostructure device of claim 1 , wherein the thickness of said metallic back plane is selected from 1 nm to less than 40 nm.

16. The nanostructure device of claim 1 , wherein said nanogap is in range from 0.5 nm to 15 nm.

17. The nanostructure device of claim 1 , wherein said at least one pillar comprises an insulator.

18. The nanostructure device of claim 1 , wherein said at least one pillar comprises a semiconductor.

19. The nanostructure device of claim 1 , wherein said metallic disc comprises the metal of gold.

20. The nanostructure device of claim 1 , wherein said metallic disc comprises a metal selected from the group consisting of silver, copper, aluminum, an alloy thereof, an alloy thereof with gold, or any combination thereof.

21. The nanostructure device of claim 1 , wherein said metallic disc comprises a material that generates plasmons.

22. The nanostructure device of claim 1 , wherein the spacing between the pillars of said plurality of pillars is periodic.

23. The nanostructure device of claim 1 , wherein said at least one pillar comprises a material selected from the group consisting of silicon-dioxide, silicon-nitride, hafnium oxide, aluminum oxide, silicon, gallium arsenide, and gallium nitride.

24. The nanostructure device of claim 1 , said metallic back plane does not have a hole under each of said pillars, such that said pillars are formed directly on the back plane material.

25. The nanostructure device of claim 1 , wherein the materials, shapes and dimensions of said nanodevice are determined by the requirements of enhancing light absorption, light radiation, and/or the local field.

26. The nanostructure device of claim 1 , wherein said enhancement of fluorescence or luminescence of a substance comprises a use of plasmon resonance.

27. The nanostructure device of claim 1 , wherein said metallic disc, said metallic back plane, and said metallic dots are deposited simultaneously.

28. The nanostructure device of claim 1 , wherein said pillars are formed using a method comprising either nanoimprint or photolithography.

29. The nanostructure device of claim 1 , wherein said substance is a fluorescent or luminescent molecule.

30. The nanostructure device of claim 1 , wherein said fluorescence or luminescence of a substance is for sensing molecules, reaction, biological pathogens, or chemical species.

Assignees

• Univ Princeton

Inventors

• Chou Stephen Y
• Li Wendi

Classifications

• G01N21/6452 Primary

  Individual samples arranged in a regular 2D-array, e.g. multiwell plates · CPC title

• G01N21/554

  detecting the surface plasmon resonance of nanostructured metals, e.g. localised surface plasmon resonance · CPC title

• G01N21/59

  Transmissivity (G01N21/25 takes precedence) · CPC title

• G01N21/648

  using evanescent coupling or surface plasmon coupling for the excitation of fluorescence · CPC title

• G01N21/64 Primary

  Fluorescence; Phosphorescence · CPC title