Hydrogen generator

Patent metadata

Field	Value
Publication number	US-9005572-B2
Application number	US-90390110-A
Country	US
Kind code	B2
Filing date	Oct 13, 2010
Priority date	Dec 10, 2009
Publication date	Apr 14, 2015
Grant date	Apr 14, 2015

Abstract

A device includes a chemical hydride fuel pellet having a plurality of holes extending from a first end to a second end. A plurality of tubes formed of water vapor permeable and hydrogen impermeable material extend from the first end to the second end through the tubes. A container has an inlet for water vapor containing gas coupled to the first end of the tubes and an outlet coupled to the second end of the tubes. A hydrogen outlet is coupled to the fuel pellet.

First claim

The invention claimed is:

1. A device comprising:
a chemical hydride fuel pellet having a plurality of holes extending from a first end to a second end, wherein the fuel pellet is surrounded by a particulate filter;
a plurality of tubes formed of water vapor permeable and hydrogen impermeable material extending from the first end to the second end through the holes;
a container having an inlet for water vapor containing gas coupled to the first end of the tubes and an outlet coupled to the second end of the tubes; and
a hydrogen outlet coupled to the fuel pellet.

2. The device of claim 1 wherein the fuel pellet is porous to hydrogen.

3. The device of claim 1 wherein the tubes comprise sulfonated tetrafluoroethylene (STFE).

4. The device of claim 1 wherein the pellet includes a membrane to prevent hydrogen from escaping from the container except through the hydrogen outlet.

5. The device of claim 1 wherein the pellet is formed of a pressed lithium aluminum hydride powder.

6. The device of claim 1 wherein the pellet includes at least one chemical hydride selected from the group consisting of LiAlH 4 , NaAlH 4 , KAlH 4 , MgAlH 4 , CaH 2 , LiBH 4 , NaBH 4 , LiH, MgH 2 , Li 3 Al 2 , CaAl 2 H 8 , Mg 2 Al 3 , alkali metals, alkaline earth metals, and alkali metal silicides.

7. The device of claim 1 wherein the tubes are substantially uniformly distributed throughout the fuel pellet.

8. The device of claim 1 wherein the container is formed of light weight plastic that is hydrogen impermeable.

9. The device of claim 8 and further comprising plates sealed against the inlet and outlet of the container to contain the fuel, the plates having openings sealed against the corresponding ends of the tubes.

10. The device of claim 9 wherein the plates comprise pairs of plates compressing an o-ring between them around each end of the tubes.

11. The device of claim 1 wherein the size of the inlet and outlet are adapted to be at least as large in area as a combined area of the tubes.

12. The device of claim 1 wherein the fuel pellet is cylindrical in shape having an axis that is substantially parallel to the tubes.

13. A device comprising:
a hydrogen generating fuel pellet having a plurality of holes extending from a first end to a second end, wherein the fuel pellet is surrounded by a particulate filter;
a plurality of tubes formed of water vapor permeable and hydrogen impermeable material extending from the first end to the second end through the holes to provide water vapor containing airflow through the fuel pellet;
a container surrounding the fuel pellet and tubes and having an inlet for water vapor containing gas coupled to the first end of the tubes and an outlet coupled to the second end of the tubes; and
a hydrogen outlet coupled to the fuel pellet.

14. The device of claim 13 wherein the fuel pellet is porous to hydrogen, and wherein the tubes comprise sulfonated tetrafluoroethylene (STFE).

15. The device of claim 14 wherein the pellet includes a membrane to prevent hydrogen from escaping from the container except through the hydrogen outlet.

16. The device of claim 15 wherein the pellet is formed of a pressed lithium aluminum hydride powder.

17. he device of claim 16 wherein the tubes are substantially uniformly distributed throughout the fuel pellet to both uniformly distribute water vapor to the fuel and to remove heat from the fuel.

18. The device of claim 16 and further comprising plates sealed against the inlet and outlet of the container to contain the fuel, the plates having openings sealed against the corresponding ends of the tubes.

19. The device of claim 13 wherein the pellet includes at least one chemical hydride selected from the group consisting of LiAlH 4 , NaAlH 4 , KAlH 4 , MgAlH 4 , CaH 2 , LiBH 4 , NaBH 4 , LiH, MgH 2 , Li 3 Al 2 , CaAl 2 H 8 , Mg 2 Al 3 , alkali metals, alkaline earth metals, and alkali metal silicides.

20. A method comprising:
flowing humid air through a plurality of tubes formed of water vapor permeable and hydrogen impermeable material extending from a first end to a second end of the tubes;
permeating the water vapor through walls of the tubes into a chemical hydride fuel pellet through which the tubes extend, the chemical hydride fuel pellet surrounded by a particulate filter; and
producing hydrogen via a reaction of fuel with the water vapor and exhausting the hydrogen through a hydrogen outlet.

21. The method of claim 20 wherein the fuel pellet is formed by:
placing a chemical hydride powder in a fixture with rods;
pressing the powder into the fixture to form the pellet;
removing the resulting pellet and inserting it into a hydrogen impermeable container; and
inserting the tubes through holes in the pellet corresponding to the rods.

Assignees

• Eickhoff Steven J
• Honeywell Int Inc

Inventors

• Eickhoff Steven J

Classifications

• C01B3/065

  by reaction of inorganic compounds with hydrides · CPC title

• B01J8/009

  Membranes, e.g. feeding or removing reactants or products to or from the catalyst bed through a membrane · CPC title

• B01J7/02 Primary

  by wet methods · CPC title

• C01B3/08

  by reaction of inorganic compounds with metals · CPC title

• B01J8/0242

  the fluid flow within the bed being predominantly vertical · CPC title