Processes for producing polymer fibers by electrospinning, colloidal dispersions for use therein, and polymer fibers prepared by such processes

Patent metadata

Field	Value
Publication number	US-9005510-B2
Application number	US-81706106-A
Country	US
Kind code	B2
Filing date	Feb 18, 2006
Priority date	Feb 24, 2005
Publication date	Apr 14, 2015
Grant date	Apr 14, 2015

Abstract

Processes for forming polymer fibers, comprising: (a) providing a colloidal dispersion of at least one essentially water-insoluble polymer in an aqueous medium; and (b) electrospinning the colloidal dispersion; polymer fibers prepared by such processes; and colloidal dispersions comprising: at least one essentially water-insoluble polymer in an aqueous medium; and at least 10% by weight of a water-soluble polymer having a solubility in water of at least 0.1% by weight.

First claim

The invention claimed is:

1. A process for forming polymer fibers, the process comprising:
(a) providing a colloidal dispersion of at least one essentially water-insoluble polymer in an aqueous medium; and
(b) electrospinning the colloidal dispersion,

wherein the at least one essentially water-insoluble polymer comprises a component selected from the group consisting of polyp-xylylene), polyesters, polyethers, polyethylene, polypropylene, poly(ethylene/propylene) (EPDM), polyolefins, polycarbonates, polyurethanes, natural polymers, polycarboxylic acids, polysulfonic acids, sulfated polysaccharides, polylactides, polyglycosides, polyamides, poly(alkyl)styrenes, polyacrylonitriles, polyacrylamides, polyimides, polyphenylenes, polysilanes, polysiloxanes, polybenzimidazoles, polybenzothiazoles, polyoxazoles, polysulfides, polyesteramides, polyarylenevinylenes, polyether ketones, polyurethanes, polysulfones, ormocerenes, silicones, fully aromatic copolyesters, poly(alkyl) acrylates, poly(alkyl) methacrylates, polyhydroxyethyl methacrylates, polyethylene terephthalates, polybutylene terephthalate, polymethacrylonitriles, polyvinyl acetates, polyisoprene, neoprene, Buna N, polybutadiene, polytetrafluoroethylene, modified and unmodified celluloses, homo- and copolymers of α-olefins, and combinations thereof.

2. The process according to claim 1 , wherein the at least one essentially water-insoluble polymer has a solubility in water of less than 0.1% by weight.

3. The process according to claim 1 , wherein the at least one essentially water-insoluble polymer comprises a component selected from the group consisting of homo- and copolymers comprised of acrylates, styrenes, vinyl acetates, vinyl ethers, butadienes, isoprenes, methacrylates, a-methylstyrenes, acrylamide, vinylsulfonic acid, vinylsulfonic esters, vinyl esters, vinyl alcohol, acrylonitrile, vinyl sulfonenes and combinations thereof.

4. The process according to claim 1 , wherein the at least one essentially water-insoluble polymer in the colloidal dispersion has an average particle diameter of 1 nm to 1 μm.

5. The process according to claim 1 , wherein the colloidal dispersion further comprises a water-soluble polymer having a solubility in water of at least 0.1% by weight.

6. The process according to claim 5 , wherein the water-soluble polymer is selected from the group consisting of homopolymers, copolymers, graft copolymers, star polymers, highly branched polymers and dendrimers.

7. The process according to claim 5 , wherein the water-soluble polymer is selected from the group consisting of polyethylene oxides, hydroxymethylcelluloses, hydroxyethylcelluloses, hydroxypropylcelluloses, carboxymethylcelluloses, maleic acids, alginates, collagens, polyvinyl alcohol, poly-N-vinylpyrrolidone, combinations thereof, copolymers thereof, graft copolymers thereof, star polymers thereof, highly branched polymers thereof, and dendrimers thereof.

8. The process according to claim 1 , wherein the colloidal dispersion has a solids content of 5 to 80% by weight, based on the dispersion.

9. The process according to claim 5 , wherein the water-soluble polymer is present in the colloidal dispersion in an amount up to 120% by weight, based on the solids content of the dispersion.

10. The process according to claim 1 , wherein the polymer fibers formed are crosslinked or bonded chemically to one another.

11. A process for forming polymer fibers, the process comprising:
(a) providing a colloidal dispersion of at least one essentially water-insoluble polymer in an aqueous medium in the form of a latex produced by emulsion polymerization; and
(b) electrospinning the colloidal dispersion.

12. A process for forming polymer fibers, the process comprising:
(a) providing a colloidal dispersion of at least one essentially water-insoluble polymer in an aqueous medium; and
(b) electrospinning the colloidal dispersion,
wherein the at least one essentially water-insoluble polymer comprises a component selected from the group consisting of poly(p-xylylene), polyesters, polyethers, polyethylene, polypropylene, poly(ethylene/propylene) (EPDM), polyolefins, polycarbonates, polyurethanes, natural polymers, polycarboxylic acids, polysulfonic acids, sulfated polysaccharides, polylactides, polyglycosides, polyamides, poly(alkyl)styrenes, polyacrylonitriles, polyacrylamides, polyimides, polyphenylenes, polysilanes, polysiloxanes, polybenzimidazoles, polybenzothiazoles, polyoxazoles, polysulfides, polyesteramides, polyarylenevinylenes, polyether ketones, polyurethanes, polysulfones, ormocerenes, silicones, fully aromatic copolyesters, poly(alkyl) acrylates, poly(alkyl) methacrylates, polyhydroxyethyl methacrylates, polyethylene terephthalates, polybutylene terephthalate, polymethacrylonitriles, polyvinyl acetates, polyisoprene, neoprene, Buna N, polybutadiene, polytetrafluoroethylene, modified and unmodified celluloses, homo- and copolymers of α-olefins, and combinations thereof, and wherein the colloidal dispersion further comprises a water-soluble polymer having a solubility in water of at least 0.1% by weight.

Assignees

• Ishaque Michael
• Greiner Andreas
• Wendorff Joachim H
• Basf Se

Inventors

• Ishaque Michael
• Greiner Andreas
• Wendorff Joachim H

Classifications

• D01D5/0038

  the fibre formed by solvent evaporation, i.e. dry electro-spinning · CPC title

• D01D5/003 Primary

  the material being a polymer solution or dispersion (D01D5/0053 takes precedence) · CPC title

• B82Y40/00

  Manufacture or treatment of nanostructures · CPC title

• D01D5/00 Primary

  Formation of filaments, threads, or the like · CPC title

• Y10T428/2975

  Tubular or cellular · CPC title