Initiating production of clathrates by use of thermosyphons
US-9222342-B2 · Dec 29, 2015 · US
US9004173B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9004173-B2 |
| Application number | US-201113104460-A |
| Country | US |
| Kind code | B2 |
| Filing date | May 10, 2011 |
| Priority date | May 10, 2011 |
| Publication date | Apr 14, 2015 |
| Grant date | Apr 14, 2015 |
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Wiper plugs or other shapes are made from shape memory foam in a size large enough to wipe or clean a tubular of a predetermined size. The plug or other shape is then reformed to a smaller dimension above its transition temperature and allowed to cool while holding that shape. The smaller shape allows delivery through a running string that is smaller than the tubular string to be wiped. Preferably before reaching the string to be wiped, the trigger is applied to get the wiper or other shape above its transition temperature where it then reverts to the prior larger dimension for effective wiping of the string that it will next pass through. The trigger can be well fluid temperature or composition, applied heat from the tubular, generated heat within the wiper or other shape, or heat released from agents introduced into the well acting alone or in conjunction with well fluids.
Opening claim text (preview).
We claim: 1. A wiper apparatus for subterranean location use to travel through a first and second tubulars that have different dimensions with the second tubular being larger than the dimension of the first tubular, comprising: a structural core having a passage and responsive to a stimulus initiated by an object entering said passage, while keeping said passage closed to allow the wiper apparatus to be moved with applied pressure, to increase from a first dimension, to a second dimension; an outer assembly that increases from a first dimension smaller than said second tubular to a second dimension to extend to the wall of the second tubular to wipe the second tubular. 2. The apparatus of claim 1 , wherein: said core is made of shape memory foam. 3. The apparatus of claim 1 , wherein: Said core is made from a shape memory alloy or a shape memory polymer. 4. The apparatus of claim 1 , wherein: said stimulus comprises heat. 5. The apparatus of claim 4 , wherein: said heat is produced from within said core. 6. The apparatus of claim 5 , wherein: said core comprises spaced chambers separated by a wall with reactive ingredients positioned in selective isolation from each other until said wall is compromised. 7. The apparatus of claim 6 , wherein: said reactive ingredients react exothermically when mixed. 8. The apparatus of claim 6 , wherein: said wall is broken by said object that lands in said core. 9. The apparatus of claim 1 , wherein: said outer dimension increase occurs when said core is located in the second tubular. 10. The apparatus of claim 1 , wherein: said core dimensional increase is due at least in part to heat provided by a heater, well fluid temperature, or materials added to the subterranean location to create localized heating of said core. 11. The apparatus of claim 1 , wherein: said outer assembly has weak segments to reduce resistance to growth of said core when the stimulus is applied. 12. The apparatus of claim 1 , wherein: said outer assembly comprises parallel fins, one arcuate projection, a series of arcuate projections, spaced apart extending pointed ends, or a generally cylindrical outer shape that is rectangular or a parallelogram shape in section. 13. The apparatus of claim 1 , wherein: at least one of said core and said outer assembly swells in the presence of hydrocarbons or water. 14. A method of wiping a tubular clear of cement, comprising: running a single wiper assembly through a running string and then through said tubular to be wiped, said running string having a smaller dimension than said tubular; removing material from said tubular to be wiped with said single wiper assembly; providing a structural core having a passage to receive a solid object for creation of a stimulus for said core of said assembly to change shape by breaking a barrier in said passage between reactants stored in said core that react exothermically. 15. The method of claim 14 , comprising: changing said shape with a stimulus applied before or after said assembly passes said running string. 16. The method of claim 15 , comprising: using heat as said stimulus. 17. The method of claim 16 , comprising: using shape memory foam for said core of said wiper assembly. 18. The method of claim 17 , comprising: generating said heat from within said core. 19. The method of claim 16 , further comprising: additionally getting said heat from a heater, or from well fluids or from fluids added to well fluids. 20. The method of claim 16 , comprising: providing an outer assembly around said core that grows to contact the tubular to be wiped where said outer assembly is made from the same or a different material than said core. 21. The method of claim 20 , comprising: providing weak spots in said outer assembly to reduce resistance to growth of said core. 22. The method of claim 20 , comprising: providing for said outer assembly parallel fins, one arcuate projection, a series of arcuate projections, spaced apart extending pointed ends, or a generally cylindrical outer shape that is rectangular or a parallelogram shape in section. 23. The method of claim 20 , comprising: making said core from a shape memory alloy or polymer and said outer assembly from an elastomer. 24. The method of claim 15 , comprising: making at least a portion of said wiper assembly from a material that swells in the presence of hydrocarbons or water.
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Heating, cooling or insulating arrangements for boreholes or wells, e.g. for use in permafrost zones · CPC title
operated by fluid pressure, e.g. free-piston scrapers · CPC title
Wipers; Oil savers · CPC title
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