Method and apparatus for manufacturing group 13 nitride crystal
US-2016177468-A1 · Jun 23, 2016 · US
US8999060B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-8999060-B2 |
| Application number | US-201313794877-A |
| Country | US |
| Kind code | B2 |
| Filing date | Mar 12, 2013 |
| Priority date | Nov 23, 2009 |
| Publication date | Apr 7, 2015 |
| Grant date | Apr 7, 2015 |
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Millimeter-scale GaN single crystals in filamentary form, also known as GaN whiskers, grown from solution and a process for preparing the same at moderate temperatures and near atmospheric pressures are provided. GaN whiskers can be grown from a GaN source in a reaction vessel subjected to a temperature gradient at nitrogen pressure. The GaN source can be formed in situ as part of an exchange reaction or can be preexisting GaN material. The GaN source is dissolved in a solvent and precipitates out of the solution as millimeter-scale single crystal filaments as a result of the applied temperature gradient.
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What is claimed is: 1. A low pressure and low temperature process for growing gallium nitride whiskers from solution, comprising: (a) charging a reaction vessel with a gallium composition comprising gallium mixed with at least one of bismuth and antimony, a Group IA element material, and gallium nitride; (b) placing the charged reaction and vessel into a chamber; (c) applying a nitrogen gas pressure of 0.1 to 20 MPa to the reaction vessel; (d) applying a temperature of betwe…
Chemistry & Metallurgy · mapped topic
Chemistry & Metallurgy · mapped topic
Chemistry & Metallurgy · mapped topic
Chemistry & Metallurgy · mapped topic
Chemistry & Metallurgy · mapped topic
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