High-nickel ternary core-shell precursor, positive electrode material and preparation method therefor
US-2024166533-A1 · May 23, 2024 · US
US8993775B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-8993775-B2 |
| Application number | US-201113250439-A |
| Country | US |
| Kind code | B2 |
| Filing date | Sep 30, 2011 |
| Priority date | Jul 5, 2010 |
| Publication date | Mar 31, 2015 |
| Grant date | Mar 31, 2015 |
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The present invention refers to the synthesis of precatalysts and the use of such precatalysts in ethylene oligomerization reactions for the selective production of alpha-olefins. More specifically, it refers to the preparation and use of coordination compounds containing polydentate ligands comprising Group 6 and 10 transition metal compounds, in particular chromium (III) and nickel (II). Such catalytic precursors present high catalytic activity and selectivity for the production of alpha-olefins.
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The invention claimed is: 1. A catalyst of the general formula LMX n , where “M” is a metal, “X” is an anion, and “n” is the number of anions “X” present in each molecule, varying from 1 to 3, and “L” is a polydentate nitrogen ligand of formula: wherein “E” is a heterocycle pyridine ring, an imidazole ring or an element selected from among oxygen or sulfur, R 1 , R 2…
Chemistry & Metallurgy · mapped topic
Chemistry & Metallurgy · mapped topic
Chemistry & Metallurgy · mapped topic
Chemistry & Metallurgy · mapped topic
Chemistry & Metallurgy · mapped topic
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