Masterbatch, and method of preparing polyamide resin composition using masterbatch

Patent metadata

Field	Value
Publication number	US-8993655-B2
Application number	US-201214001000-A
Country	US
Kind code	B2
Filing date	Feb 22, 2012
Priority date	Feb 24, 2011
Publication date	Mar 31, 2015
Grant date	Mar 31, 2015

Abstract

Capable of being provided are [1] a master batch comprising polyamide (X) comprising a diamine unit containing 70 mole % or more of a metaxylylenediamine unit and a dicarboxylic acid unit and an alkali compound (A), wherein an average particle diameter of the alkali compound (A) contained in the master batch is 50 μm or less; a contained number of particles having a particle diameter of exceeding 80 μm in 5 square millimeter of a cross section of the master batch is 1.5 particle or less; and a sum (m) of values obtained by multiplying a mole concentration of an alkali metal atom and a mole concentration of an alkaline earth metal atom each contained per g of the master batch by valencies thereof respectively is 60 μmol/g or more and 1710 μmol/g or less and [2] a production process for a polyamide resin composition prepared by making use of the master batch described in the above item [1]. Making use of the master batch of the present invention makes it possible to provide a polyamide resin composition which has a good appearance and a good color tone and which forms less gels in mold processing.

First claim

What is claimed is:

1. A master batch, comprising:
a polyamide (X) comprising a diamine unit containing 70 mole % or more of a metaxylylenediamine unit and a dicarboxylic acid unit; and
an alkali compound (A),
wherein:
an average particle diameter of the alkali compound (A) contained in the master batch is 50 μm or less;
a contained number of particles having a particle diameter of exceeding 80 μm in 5 square millimeter of a cross section of the master batch is 1.5 particle or less; and
a sum (m) of values obtained by multiplying a mole concentration of an alkali metal atom and a mole concentration of an alkaline earth metal atom each contained per g of the master batch by valencies thereof respectively is 60 μmol/g or more and 1710 μmol/g or less.

2. The master batch according to claim 1 , wherein the alkali compound (A) is an alkali metal salt of carboxylic acid having 10 or less carbon atoms.

3. The master batch according to claim 1 , wherein the alkali compound (A) is sodium acetate.

4. The master batch according to claim 1 , wherein the polyamide (X) is polyamide comprising a diamine unit containing 70 mole % or more of a metaxylylenediamine unit and a dicarboxylic acid unit containing 70 mole % or more of an adipic acid unit.

5. The master batch according to claim 1 , wherein the polyamide (X) is polyamide comprising a diamine unit containing 70 mole % or more of a metaxylenediamine unit and a dicarboxylic acid unit containing 70 to 99 mole % of an adipic acid unit and 1 to 30 mole % of an isophthalic acid unit.

6. The master batch according to claim 1 , wherein the polyamide (X) is polyamide comprising a diamine unit containing 70 mole % or more of a metaxylenediamine unit and a dicarboxylic acid unit containing 70 mole % or more of a sebacic acid unit.

7. A production process for a polyamide resin composition prepared from the master batch according to claim 1 , the production process comprising:
(a) polycondensing a diamine comprising 70 mole % or more of metaxylylenediamine and dicarboxylic acid in the presence of an alkali metal compound (C) and a phosphorus atom-containing compound (B) to obtain the polyamide (X);
(b) melting and kneading 14 to 0.5 parts by mass of a raw material alkali compound (A) and 100 parts by mass of the polyamide (X) obtained in step (a) with an extrusion equipment to obtain the master batch comprising the polyamide (X) and the alkali compound (A)′ and
(c) melting and kneading 0.5 to 20 parts by mass of the master batch obtained in step (b) and 99.5 to 80 parts by mass of the polyamide (X) obtained in the step (a) with an extrusion equipment,
to form a polyamide resin composition.

8. The production process according to claim 7 , wherein:
the polyamide resin composition obtained in the step (c) satisfies the following equations (1) to (3):
0.03 ≦P< 0.32  (1)

2.2 ≦M≦ 26.1  (2)

5 <M/P≦ 200  (3);

P represents a mole concentration (μmol/g) of a phosphorus atom contained per g of the polyamide resin composition; and
M represents a sum (μmol/g) of values obtained by multiplying a mole concentration (μmol/g) of an alkali metal atom and a mole concentration (μmol/g) of an alkaline earth metal atom each contained per g of the polyamide resin composition by valencies thereof respectively.

9. The production process according to claim 7 , wherein:
an average particle diameter of the raw material alkali compound (A) is 150 μm or less; and
a proportion in which particles having a particle diameter of 300 μm or more are contained in the raw material alkali compound (A) is 5% or less.

10. The master batch according to claim 2 , wherein the polyamide (X) is polyamide comprising a diamine unit containing 70 mole % or more of a metaxylylenediamine unit and a dicarboxylic acid unit containing 70 mole % or more of an adipic acid unit.

11. The master batch according to claim 2 , wherein the polyamide (X) is polyamide comprising a diamine unit containing 70 mole % or more of a metaxylenediamine unit and a dicarboxylic acid unit containing 70 to 99 mole % of an adipic acid unit and 1 to 30 mole % of an isophthalic acid unit.

12. The master batch according to claim 2 , wherein the polyamide (X) is polyamide comprising a diamine unit containing 70 mole % or more of a metaxylenediamine unit and a dicarboxylic acid unit containing 70 mole % or more of a sebacic acid unit.

13. The production process according to claim 8 , wherein:
an average particle diameter of the raw material alkali compound (A) is 150 μm or less; and
a proportion in which particles having a particle diameter of 300 μm or more are contained in the raw material alkali compound (A) is 5% or less.

Assignees

• Yamamoto Takashi
• Mitsubishi Gas Chemical Co

Inventors

• Yamamoto Takashi

Classifications

• C08J2477/06

  Polyamides derived from polyamines and polycarboxylic acids (C08J2477/10 takes precedence) · CPC title

• C08J2377/06

  Polyamides derived from polyamines and polycarboxylic acids (C08J2377/10 takes precedence) · CPC title

• C08L77/06 Primary

  Polyamides derived from polyamines and polycarboxylic acids (C08L77/10 takes precedence) · CPC title

• C08J3/22 Primary

  using masterbatch techniques · CPC title

• C08G69/265 Primary

  from at least two different diamines or at least two different dicarboxylic acids · CPC title