Nanoscale ionic material (NIM) compositions via acid/base reaction
US-9849451-B2 · Dec 26, 2017 · US
US8992885B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-8992885-B2 |
| Application number | US-201213714486-A |
| Country | US |
| Kind code | B2 |
| Filing date | Dec 14, 2012 |
| Priority date | Dec 22, 2011 |
| Publication date | Mar 31, 2015 |
| Grant date | Mar 31, 2015 |
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A new family of coherently grown composites of TUN and IMF zeotypes have been synthesized. These zeolites are represented by the empirical formula. Na n M m k+ T t Al 1−x E x Si y O z where “n” is the mole ratio of Na to (Al+E), M represents a metal or metals from zinc, Group 1, Group 2, Group 3 and or the lanthanide series of the periodic table, “m” is the mole ratio of M to (Al+E), “k” is the average charge of the metal or metals M, T is the organic structure directing agent or agents, and E is a framework element such as gallium. These zeolites are similar to TNU-9 and IM-5 but are characterized by unique compositions and synthesis procedures and have catalytic properties for carrying out various hydrocarbon conversion processes and separation properties for carrying out various separations.
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The invention claimed is: 1. A coherently grown composite of TUN and IMF zeotypes having a three-dimensional framework of at least AlO 2 and SiO 2 tetrahedral units and an empirical composition in the as synthesized and anhydrous basis expressed by an empirical formula of: Na n M m k+ T t Al 1−x E x Si y O z where “n” is the mole ratio of Na to (Al+E) and has a value from approximately 0.05 to 0.5, M represents at least one metal selected from the group consisti…
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