Rubber composition including an organosilane coupling agent

Patent metadata

Field	Value
Publication number	US-8987353-B2
Application number	US-201013321824-A
Country	US
Kind code	B2
Filing date	May 20, 2010
Priority date	May 20, 2009
Publication date	Mar 24, 2015
Grant date	Mar 24, 2015

Abstract

A rubber composition that can be used for the manufacture of tires, based on at least one diene elastomer; one sulphur-based crosslinking system; one inorganic filler as reinforcing filler; one coupling agent of general formula I below: (HO) 3-n R 1 n Si—Z—S m —R 2 wherein in which: R 1 , which are identical or different, each represent a monovalent hydrocarbon-based group chosen from alkyls, which are linear or branched, cycloalkyls or aryls, having from 1 to 18 carbon atoms; R 2 represents a monovalent hydrocarbon-based group chosen from alkyls, which are linear or branched, cycloalkyls or aryls, having from 1 to 30 carbon atoms; Z represents a divalent bonding group comprising from 1 to 18 carbon atoms; n is an integer equal to 0, 1 or 2; and m is a number greater than or equal to 2.

First claim

The invention claimed is:

1. A rubber composition that can be used for the manufacture of tires, based on at least:
one diene elastomer;
one sulphur-based crosslinking system;
one inorganic filler as reinforcing filler;
one coupling agent of general formula I below:
(HO) 3-n R 1 n Si—Z —S m —R 2

wherein:
R 1 , which are identical or different, each represent a monovalent hydrocarbon group chosen from alkyls, which are linear or branched, cycloalkyls or aryls, having from 1 to 18 carbon atoms;
R 2 represents a monovalent hydrocarbon group chosen from alkyls, which are linear or branched, cycloalkyls or aryls, having from 1 to 30 carbon atoms;
Z represents a divalent bonding group comprising from 1 to 18 carbon atoms;
n is an integer equal to 0, 1 or 2; and
m is a number greater than or equal to 2.

2. The composition according to claim 1 , wherein n is equal to 1.

3. The composition according to claim 1 , wherein Z contains one or more heteroatoms chosen from O S and N.

4. The composition according to claim 1 , wherein m is equal to 2.

5. The composition according claim 1 , wherein:
R 1 is chosen from methyl, ethyl, n-propyl and isopropyl;
Z is chosen from C 1 -C 18 alkylenes and C 6 -C 12 arylenes.

6. The composition according to claim 5 , wherein Z is chosen from C 1 -C 10 alkylenes.

7. The composition according to claim 6 , wherein Z is chosen from C 1 -C 4 alkylenes.

8. The composition according to claim 5 , wherein R 1 is a methyl.

9. The composition according to claim 5 , wherein R 2 is chosen from alkyls having from 1 to 18 carbon atoms.

10. The composition according to claim 8 , wherein R 2 is an octyl.

11. The composition according to claim 5 , wherein m is equal to 2, R 1 is a methyl, R 2 is an octyl and Z is a propylene.

12. The composition according to claim 1 , wherein the diene elastomer being chosen from the group consisting of polybutadienes, synthetic polyisoprenes, natural rubber, butadiene copolymers, isoprene copolymers and mixtures of these elastomers.

13. The composition according to claim 1 , wherein the reinforcing inorganic filler is the predominant reinforcing filler.

14. The composition according to claim 1 , wherein the reinforcing inorganic filler is a siliceous or aluminous filler.

15. The composition according to claim 1 , wherein the amount of reinforcing inorganic filler is greater than 50 phr, parts by weight per hundred parts of elastomer.

16. The composition according to claim 1 , wherein the content of coupling agent represents between 2% and 20% by weight relative to the amount of reinforcing inorganic filler.

17. The composition according to claim 1 , wherein the zinc content is less than 0.5 phr.

18. A process for preparing a composition, wherein, incorporated at least, by kneading, into at least (i) one diene elastomer, are (ii) an inorganic filler as reinforcing filler, (iii) a coupling agent of general formula I below:
(HO) 3-n R 1 n Si —Z —S m —R 2

wherein:
R 1 , which are identical or different, each represent a monovalent hydrocarbon group chosen from alkyls, which are linear or branched, cycloalkyls or aryls, having from 1 to 18 carbon atoms;
R 2 represents a monovalent hydrocarbon group chosen from alkyls, which are linear or branched, cycloalkyls or aryls, having from 1 to 30 carbon atoms;
Z represents a divalent bonding group comprising from 1 to 18 carbon atoms;
n is an integer equal to 0, 1 or 2; and
m is a number greater than or equal to 2,
and (iv) a sulphur-based vulcanization system.

19. The process according to claim 18 , comprising the steps of:
incorporating into the diene elastomer, in a mixer, the reinforcing filler and the coupling agent by thermomechanically kneading all the ingredients, one or more times, until a maximum temperature between 130° C. and 200° C. is reached;
cooling the mixture down to a temperature below 100° C.;
then incorporating: the vulcanization system;
kneading all the ingredients up to a maximum temperature below 120° C.; and
extruding or calendering the rubber composition thus obtained.

20. A tire or semi-finished product comprising a rubber composition according to claim 1 .

21. A tire tread comprising a rubber composition according to claim 1 .

22. The composition according claim 1 , wherein:
R1 is chosen from methyl and ethyl.

Assignees

• Longchambon Karine
• Araujo Da Silva José Carlos
• Seeboth Nicolas
• Michelin Rech Tech
• Michelin & Cie

Inventors

• Longchambon Karine
• Araujo Da Silva José Carlos
• Seeboth Nicolas

Classifications

• C08L21/00

  Compositions of unspecified rubbers · CPC title

• C08K5/548

  containing sulfur {(C08K5/5477 takes precedence)} · CPC title

• C08L2666/08

  Homopolymers or copolymers according to C08L7/00 - C08L21/00; Derivatives thereof · CPC title

• C08K3/36 Primary

  Silica · CPC title

• B60C1/0016

  Compositions of the tread · CPC title