Chemically amplified positive resist composition and resist pattern forming process
US-12164231-B2 · Dec 10, 2024 · US
US8986918B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-8986918-B2 |
| Application number | US-201314081075-A |
| Country | US |
| Kind code | B2 |
| Filing date | Nov 15, 2013 |
| Priority date | Nov 10, 2011 |
| Publication date | Mar 24, 2015 |
| Grant date | Mar 24, 2015 |
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The present invention relates to a hybrid photoresist composition for improved resolution and a pattern forming method using the photoresist composition. The photoresist composition includes a radiation sensitive acid generator, a crosslinking agent and a polymer having a hydrophobic monomer unit and a hydrophilic monomer unit containing a hydroxyl group. At least some of the hydroxyl groups are protected with an acid labile moiety having a low activation energy. The photoresist is capable of producing a hybrid response to a single exposure. The patterning forming method utilizes the hybrid response to form a patterned structure in the photoresist layer. The photoresist composition and the pattern forming method of the present invention are useful for printing small features with precise image control, particularly spaces of small dimensions.
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What is claimed is: 1. A method of forming a patterned structure on a substrate, comprising: providing a substrate with a material layer; applying a photoresist composition to the substrate to form a photoresist layer on the material layer, the photoresist composition comprising a first photoacid generator having a first activation energy level, a second photoacid generator having a second activation energy level that is different than the first activation energy level, a negati…
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