Method for the production of butadiene and hydrogen from ethanol in two low-water and low-energy-consumption reaction steps
US-10358396-B2 · Jul 23, 2019 · US
US8969640B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-8969640-B2 |
| Application number | US-201113304052-A |
| Country | US |
| Kind code | B2 |
| Filing date | Nov 23, 2011 |
| Priority date | Nov 23, 2011 |
| Publication date | Mar 3, 2015 |
| Grant date | Mar 3, 2015 |
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The present invention provides methods, reactor systems, and catalysts for increasing the yield of aromatic hydrocarbons produced while converting alkanols to hydrocarbons. The invention includes methods of using catalysts to increase the yield of benzene, toluene, and mixed xylenes in the hydrocarbon product.
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The invention claimed is: 1. A method of converting alkanols to aromatic hydrocarbons comprising: partially dehydrogenating a C 1 -C 6 alkanol feedstock in the presence of a dehydrogenation catalyst at an effective dehydrogenation temperature and dehydrogenation pressure to produce hydrogen and a mixture of oxygenate components comprising (a) unreacted C 1 -C 6 alkanol and (b) a carboxylic acid, an aldehyde, an ester or any combination thereof; wherein at least a portion of the…
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