Ester compound
US-2024025838-A1 · Jan 25, 2024 · US
US8969404B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-8969404-B2 |
| Application number | US-201313758080-A |
| Country | US |
| Kind code | B2 |
| Filing date | Feb 4, 2013 |
| Priority date | Jun 22, 2012 |
| Publication date | Mar 3, 2015 |
| Grant date | Mar 3, 2015 |
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A process for purifying a crude furan 2,5-dicarboxylic acid composition (cFDCA) by hydrogenation of a FDCA composition dissolved in a hydrogenation solvent such as water, and hydrogenating under mild conditions, such as at a temperature within a range of 130° C. to 225° C. by contacting the solvated FDCA composition with hydrogen in the presence of a hydrogenation catalyst under a hydrogen partial pressure within a range of 10 psi to 900 psi. A product FDCA composition is produced having a low amount of tetrahydrofuran dicarboxylic acid, a low b*, and a low amount of 5-formyl furan-2-carboxylic acid (FFCA).
Opening claim text (preview).
What we claim is: 1. A process for purifying a crude furan 2,5-dicarboxylic acid composition (cFDCA) comprising: a) providing a cFDCA composition comprising furan 2,5-dicarboxylic acid (FDCA) solids, 5-formyl furan-2-carboxylic acid (FFCA), and a oxidation solvent composition; b) combining a hydrogenation solvent composition with said FDCA solids and dissolving at least a portion of the FDCA solids to thereby produce a solvated FDCA (sFDCA) composition comprising dissolved FDCA,…
Chemistry & Metallurgy · mapped topic
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