Method for producing fats and oils

Patent metadata

Field	Value
Publication number	US-8968815-B2
Application number	US-201013254996-A
Country	US
Kind code	B2
Filing date	Mar 8, 2010
Priority date	Mar 6, 2009
Publication date	Mar 3, 2015
Grant date	Mar 3, 2015

Abstract

The present invention discloses a safer, more effective and industrially suitable method for producing fats and oils rich in a XUX triglyceride wherein the contents of a XXX triglyceride and a XX diglyceride are low which comprises, upon removing by crystallization a XXX triglyceride and a XX diglyceride each of which is contained in fats and oils comprising 50 to 90 mass % of a XUX triglyceride in total triglycerides, the step of conducting such removing by crystallization in the presence of a fatty acid lower alkyl ester. This method is a more efficient and industrially suitable method for producing fats and oils rich in a XUX triglyceride wherein the contents of a XXX triglyceride and a XX diglyceride are low.

First claim

What is claimed is:

1. A method for producing fats and oils which comprises the steps of cooling fats and oils in a molten state comprising 50 to 90 mass % of a XUX triglyceride in total triglycerides and containing 0.5 to 6 mass % of a XXX triglyceride in the presence of 7-23 mass % of a fatty acid lower alkyl ester to precipitate crystals; and conducting solid-liquid separation to obtain fats and oils wherein a XXX triglyceride and a XX diglyceride are decreased in an olein part (a liquid part), wherein the XUX triglyceride is a triglyceride comprising saturated fatty acid residues on the first and third positions and an unsaturated fatty acid residue on the second position; the XXX triglyceride is a triglyceride comprising saturated fatty acid residues on all of the first to third positions; and the XX diglyceride is a diglyceride comprising saturated fatty acid residues on any two positions among the first to third positions.

2. The method for producing fats and oils according to claim 1 , wherein the fats and oils comprising 50 to 90 mass % of a XUX triglyceride in total triglycerides and containing 0.5 to 6 mass % of a XXX triglyceride are derived from a distillation residue obtained by following steps A to C:
A: a step of mixing a fatty acid lower alkyl ester and fats and oils comprising triglycerides rich in unsaturated fatty acid residues on the second position thereof to obtain a mixture;
B: a step of transesterifying the mixture with 1,3-selective lipase to obtain a transesterified reactant; and
C: a step of conducting distillation to the transesterified reactant and distilling a part or all of the fatty acid lower alkyl ester to obtain a distillation residue.

3. The method for producing fats and oils according to claim 1 , wherein the fats and oils comprising 50 to 90 mass % of a XUX triglyceride in total triglycerides and containing 0.5 to 6 mass % of a XXX triglyceride are derived from a distillation residue of a multistage transesterification reactant obtained by conducting A-B-C and then repeating D-B-C once or more in following steps A to D:
A: a step of mixing a fatty acid lower alkyl ester and fats and oils comprising triglycerides rich in unsaturated fatty acid residues on the second position thereof to obtain a mixture;
B: a step of transesterifying the mixture with 1,3-selective lipase to obtain a transesterified mixture;
C: a step of conducting distillation to the transesterified mixture and distilling a part or all of the fatty acid lower alkyl ester to obtain a distillation residue; and
D: a step of mixing the distillation residue of above C and a fatty acid lower alkyl ester to obtain a mixture.

4. The method for producing fats and oils according to claim 1 , wherein, fats and oils comprising a XUX triglyceride and a fatty acid lower alkyl ester are dissolved by heating and the dissolved fats and oils are cooled with stirring and/or still standing to precipitate crystals comprising a XXX triglyceride and/or a XX diglyceride, wherein a XXX triglyceride or a XX diglyceride is crystallized at the temperature at which a XUX triglyceride hardly crystallizes; and the solid-liquid separation is conducted to obtain an olein part (a liquid part).

5. The method for producing fats and oils according to claim 4 , wherein the crystallization is conducted at 20 to 35° C.

6. The method for producing fats and oils according to claim 4 , wherein the solid-liquid separation is conducted by pressure filtration.

7. A hard butter comprising the fats and oils produced according to claim 1 .

8. A food comprising the hard butter according to claim 7 .

Assignees

• Suganuma Tomomi
• Takaba Masato
• Nisshin Oillio Group Ltd

Inventors

• Suganuma Tomomi
• Takaba Masato

Classifications

• C11B3/008

  by filtration, e.g. including ultra filtration, dialysis (C11B3/005 takes precedence) · CPC title

• C11B7/00

  Separation of mixtures of fats or fatty oils into their constituents, e.g. saturated oils from unsaturated oils · CPC title

• C11B7/0025

  in solvents containing oxygen in their molecule · CPC title

• A23D9/00

  Other edible oils or fats, e.g. shortenings or cooking oils (preservation of other edible oils A23B20/30) · CPC title

• C11C3/10 Primary

  Ester interchange · CPC title