Process for the chemoselective reduction of terminally saturated carboxylic esters
US-9193651-B2 · Nov 24, 2015 · US
US8962895B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-8962895-B2 |
| Application number | US-201214001120-A |
| Country | US |
| Kind code | B2 |
| Filing date | Feb 24, 2012 |
| Priority date | Feb 25, 2011 |
| Publication date | Feb 24, 2015 |
| Grant date | Feb 24, 2015 |
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The present invention relates to a method for the production of ethylene glycol using a feedstock comprising an oxalate and a catalyst containing copper and/or a copper oxide, comprising contacting the feedstock with the catalyst in a reactor under the conditions of a temperature in the range from about 170 to about 270° C., a weight hourly space velocity of the oxalate in the range from about 0.2 to about 5 h −1 , a molar ratio of hydrogen to the oxalate in the range from about 40:1 to about 200:1 and a reaction pressure in the range from about 1.5 to about 10 MPa, to produce an effluent containing ethylene glycol, in which the reactor is a tube-array reactor using partitioned heat exchange and adopting outer and inner tubes configured in a double-tube structure to facilitate the heat exchange of the catalyst.
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What is claimed: 1. A method for production of ethylene glycol using a feedstock comprising an oxalate and a catalyst containing copper and/or a copper oxide, comprising: contacting the feedstock with the catalyst in a reactor under conditions of a temperature in a range from about 170 to about 270° C., a weight hourly space velocity of the oxalate in a range from about 0.2 to about 7 h − , a molar ratio of hydrogen to the oxalate in a range from about 20:1 to about 200:1 and a re…
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