Renewable olefins from a mixture of acetic acid and propionic acid
US-9212106-B2 · Dec 15, 2015 · US
US8962882B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-8962882-B2 |
| Application number | US-201314087203-A |
| Country | US |
| Kind code | B2 |
| Filing date | Nov 22, 2013 |
| Priority date | Oct 25, 2012 |
| Publication date | Feb 24, 2015 |
| Grant date | Feb 24, 2015 |
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This invention concerns a process for obtaining lactic acid in a single stage by direct oxidation in an aqueous medium of 1,2-propanediol in the presence of a mixture of heterogeneous catalysts, in conditions of low temperature and low pressure. The reaction takes place in the presence of oxygen and a mixture of heterogeneous catalysts, consisting of a first catalyst of noble metal supported in metallic oxide, and a second basic solid catalyst. The mixture of catalysts is easily recovered by filtration at the end of the process, to be reused. The lactic acid is obtained directly, with selectivity between 50% and 97%.
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The invention claimed is: 1. Process for direct synthesis of lactic acid, which process comprises oxidation of 1,2-propanediol in the presence of oxygen and a mixture of catalysts, which mixture of catalysts comprises: a first metallic catalyst comprising a supported noble metal; and a second basic catalyst which comprises a basic oxide wherein: the oxidation takes place at a temperature of from 30° C. to 100° C.; and the first metallic catalyst comprises at least one of the noble…
Chemistry & Metallurgy · mapped topic
Chemistry & Metallurgy · mapped topic
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