Hydrotreating catalyst, process for producing same, and process for hydrotreating hydrocarbon oil

US8962514B2 · US · B2

Patent metadata
FieldValue
Publication numberUS-8962514-B2
Application numberUS-201013138774-A
CountryUS
Kind codeB2
Filing dateMar 18, 2010
Priority dateMar 23, 2009
Publication dateFeb 24, 2015
Grant dateFeb 24, 2015

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Abstract

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A hydrotreating catalyst that exhibits excellent levels of both desulfurization activity and denitrification activity. The hydrotreating catalyst is prepared by supporting molybdenum, cobalt and nickel on a carrier comprising aluminum, silicon, phosphorus and boron, and then performing a presulfiding treatment, and has an average stacking number for molybdenum sulfide slab that is greater than 1.0 but not more than 1.9. Also, a process for producing a hydrotreating catalyst that enables a hydrotreating catalyst having excellent levels of both desulfurization activity and denitrification activity to be produced with comparative ease. The process includes a first step of mixing an acidic aluminum salt aqueous solution and a basic aluminum salt aqueous solution in the presence of phosphate ions and silicate ions to achieve a pH of 6.5 to 9.5, thereby obtaining a hydrate, a second step of adding boron to the hydrate to prepare a carrier-forming material, a third step of molding and calcining the carrier-forming material to obtain a carrier, a fourth step of supporting molybdenum, cobalt and nickel on the carrier to obtain a catalyst precursor, and a fifth step of performing a presulfiding treatment by bringing the catalyst precursor into contact with a mixed gas containing hydrogen and hydrogen sulfide under conditions including a pressure of not less than 2.0 MPa and a maximum temperature of 240 to 380° C.

First claim

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The invention claimed is: 1. A hydrotreating catalyst being a calcined product comprising: a carrier comprising aluminum, silicon, phosphorus and boron; and molybdenum, cobalt and nickel supported on the carrier; wherein, relative to 100% by mass of the carrier, (a) an aluminum content in the carrier in terms of aluminum oxide (Al 2 O 3 ) is 75% or more, (b) a silicon content in the carrier in terms of silicon oxide (SiO 2 ) is 0.2% or more and 10.0% or less, (c) a phospho…

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What does patent US8962514B2 cover?
A hydrotreating catalyst that exhibits excellent levels of both desulfurization activity and denitrification activity. The hydrotreating catalyst is prepared by supporting molybdenum, cobalt and nickel on a carrier comprising aluminum, silicon, phosphorus and boron, and then performing a presulfiding treatment, and has an average stacking number for molybdenum sulfide slab that is greater than …
Who is the assignee on this patent?
Seki Hiroyuki, Fukui Yoshiaki, Yoshida Masanori, and 1 more
What technology area does this patent fall under?
Primary CPC classification B01J23/883. Mapped technology areas include Operations & Transport.
When was this patent published?
Publication date Tue Feb 24 2015 00:00:00 GMT+0000 (Coordinated Universal Time) (B2). Legal status and post-grant events are not shown on this page.
What related patents are in patentsdb?
We list 8 related publications on this page (citations in our corpus or others sharing the same primary CPC).