ZPGM Diesel Oxidation Catalysts and methods of making and using same
US-9511350-B2 · Dec 6, 2016 · US
US8961829B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-8961829-B2 |
| Application number | US-45081808-A |
| Country | US |
| Kind code | B2 |
| Filing date | Apr 23, 2008 |
| Priority date | Apr 27, 2007 |
| Publication date | Feb 24, 2015 |
| Grant date | Feb 24, 2015 |
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The invention relates to a process of making a syngas mixture containing hydrogen, carbon monoxide and carbon dioxide, comprising a step of contacting a gaseous feed mixture containing carbon dioxide and hydrogen with a catalyst, which catalyst substantially consists of Mn oxide and an oxide of at least one member selected from the group consisting of Cr, Ni, La, Ce, W, and Pt. This process enables hydrogenation of carbon dioxide into carbon monoxide with high selectivity, and good catalyst stability over time and under variations in processing conditions. The process can be applied separately, but can also be integrated with other processes, both up-stream and/or down-stream; like methane reforming or other synthesis processes for making products like alkanes, aldehydes, or alcohols.
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The invention claimed is: 1. A process of making a syngas mixture containing hydrogen, carbon monoxide, and carbon dioxide, comprising contacting a gaseous feed mixture containing carbon dioxide and hydrogen with a catalyst consisting essentially of oxides of Mn and La and optionally an oxide of at least one member selected from the group consisting of Cr, Ni, Ce, W, and Pt, to form the carbon monoxide. 2. The process according to claim 1 , wherein the catalyst…
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