Biodisintegratable composite foils

Patent metadata

Field	Value
Publication number	US-8956497-B2
Application number	US-201113191982-A
Country	US
Kind code	B2
Filing date	Jul 27, 2011
Priority date	Jul 29, 2010
Publication date	Feb 17, 2015
Grant date	Feb 17, 2015

Abstract

A method for producing biodisintegratable composite foils with an aqueous polyurethane dispersion adhesive. The method involves adhesive-bonding a first substrate to a second substrate with use of the aqueous polyurethane dispersion adhesive. At least one of the first substrate and the second substrate is made of a biodisintegratable polymer foil, and at least 60% by weight of the polyurethane contains diisocyanates, polyesterdiols, and bifunctional carboxylic acids. The bifunctional carboxylic acids are dihydroxycarboxylic acids or diaminocarboxylic acids.

First claim

The invention claimed is:

1. A method, comprising:
adhesive-bonding at least one first substrate to at least one second substrate with an adhesive comprising a biodegradable aqueous dispersed polyurethane, thereby forming a biodisintegratable composite foil,
wherein at least one of the at least one first substrate and the at least one second substrate is a biodisintegratable polymer foil, and
at least 60% by weight of the biodegradable aqueous dispersed polyurethane comprises:
(a) a diisocyanate;
(b) a polyesterdiol; and
(c) a bifunctional carboxylic acid selected from the group consisting of a dihydroxycarboxylic acid and a diaminocarboxylic acid,
wherein said biodegradable aqueous dispersed polyurethane exhibits a ratio of gaseous carbon liberated therefrom in the form of CO 2 to a total carbon content of a material of at least 30% after 20 days, and
wherein at most 10% of an original dry weight of said biodisintegratable composite foil is found to be present after aerobic composting for a period of at most 12 weeks in a sieve fraction >2 mm.

2. The method of claim 1 ,
wherein at least 80% by weight of the biodegradable aqueous dispersed polyurethane is the polyesterdiol.

3. The method of claim 1 ,
wherein the polyesterdiol comprises from 10 to 100 mol % of a polyesterdiol with a molar mass of from 500 to 5000 g/mol, based on a total amount of the polyesterdiol, and from 0 to 90 mol % of a polyesterdiol having a molar mass of from 60 to 500 g/mol, based on a total amount of the polyesterdiol.

4. The method of claim 1 ,
wherein the adhesive further comprises an external crosslinking agent.

5. The method of claim 4 ,
wherein the external crosslinking agent is at least one selected from the group consisting of an isocyanurate formed from a diisocyanate and having at least two isocyanate groups, a compound having at least one carbodiimide group, a chemically capped isocyanate, an encapsulated isocyanate, an encapsulated uretdione, a biuret, an allophanate, an aziridine, an oxazoline, and an epoxide.

6. The method of claim 1 ,
wherein the at least one first substrate is at least one selected from the group consisting of lignin, starch, cellulose, polylactic acid, polyglycolic acid, an aliphatic polyester, an aliphatic-aromatic copolyester, a polyhydroxyalkanoate, and polypropylene carbonate, and
the at least one second substrate is at least one selected from the group consisting of paper, lignin, starch, cellulose, polylactic acid, polyglycolic acid, an aliphatic polyester, an aliphatic-aromatic copolyester, a polyhydroxyalkanoate, and polypropylene carbonate.

7. The method of claim 1 ,
wherein the at least one first substrate is paper and
the at least one second substrate is polylactic acid or a mixture comprising polylactic acid and an aliphatic-aromatic copolyester.

8. The method according to claim 1 ,
wherein the method is suitable for producing flexible packaging.

9. The method according to claim 1 ,
wherein the method is suitable for producing a composite foil.

10. A method for producing a composite foil, the method comprising:
applying a biodisintegratable polymer as at least one first substrate, via extrusion coating to at least one second substrate, and
applying, as an intermediate layer, an adhesive comprising a biodegradable aqueous dispersed polyurethane,
wherein at least 60% by weight of the biodegradable aqueous dispersed polyurethane comprises
(a) a diisocyanate;
(b) a polyesterdiol; and
(c) a bifunctional carboxylic acid selected from the group consisting of a dihydroxycarboxylic acid and a diaminocarboxylic acid,
wherein said biodegradable aqueous dispersed polyurethane exhibits a ratio of gaseous carbon liberated therefrom in the form of CO 2 to a total carbon content of a material of at least 30% after 20 days, and
wherein at most 10% of an original dry weight of said biodisintegratable composite foil is found to be present after aerobic composting for a period of at most 12 weeks in a sieve fraction >2 mm.

11. The method of claim 3 ,
wherein the biodegradable aqueous dispersed polyurethane further comprises:
a polyfunctional compound different from monomers a) to c), and
the polyfunctional compound has at least one reactive group selected from the group consisting of an alcoholic hydroxy group, a primary or secondary amino group, and an isocyanate group.

12. The method of claim 3 ,
wherein the biodegradable aqueous dispersed polyurethane further comprises:
a monofunctional compound differs from monomers a) to c), and
the monofunctional compound has at least one reactive group selected from the group consisting of an alcoholic hydroxy group, a primary or secondary amino group, and an isocyanate group.

13. The method of claim 11 ,
wherein the biodegradable aqueous dispersed polyurethane further comprises:
a monofunctional compound differs from monomers a) to c), and
the monofunctional compound has at least one reactive group selected from the group consisting of an alcoholic hydroxy group, a primary or secondary amino group, and an isocyanate group.

14. The method of claim 1 ,
wherein at least 80% by weight of the biodegradable aqueous dispersed polyurethane comprises the diisocyanates, the polyesterdiols, and the bifunctional carboxylic acids.

Assignees

• Beyers Cornelis Petrus
• Diehl Heiko
• Dahmen Stefan
• Kriegisch Volker
• Licht Ulrike
• Meyer Axel
• Yamamoto Motonori
• Basf Se

Inventors

• Beyers Cornelis Petrus
• Diehl Heiko
• Dahmen Stefan
• Kriegisch Volker
• Licht Ulrike
• Meyer Axel
• Yamamoto Motonori

Classifications

• B32B2307/7163

  Biodegradable · CPC title

• C08G18/792

  formed by oligomerisation of aliphatic and/or cycloaliphatic isocyanates or isothiocyanates · CPC title

• C08G18/6659

  with compounds of group C08G18/34 · CPC title

• C08G18/3821

  Carboxylic acids; Esters thereof with monohydroxyl compounds · CPC title

• B32B37/14 Primary

  characterised by the properties of the layers · CPC title