Catalysts for the conversion of hydroxypropionic acid or its derivatives to acrylic acid or its derivatives
US-10106484-B2 · Oct 23, 2018 · US
US8946458B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-8946458-B2 |
| Application number | US-201213586499-A |
| Country | US |
| Kind code | B2 |
| Filing date | Aug 15, 2012 |
| Priority date | Aug 15, 2012 |
| Publication date | Feb 3, 2015 |
| Grant date | Feb 3, 2015 |
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The present invention provides catalysts, methods, and reactor systems for converting oxygenated hydrocarbons to oxygenated compounds. The invention includes methods for producing cyclic ethers, monooxygenates, dioxygenates, ketones, aldehydes, carboxylic acids, and alcohols from oxygenated hydrocarbons, such as carbohydrates, sugars, sugar alcohols, sugar degradation products, and the like, using catalysts containing palladium, molybdenum, tin, and tungsten. The oxygenated compounds produced are useful in the production of liquid fuels, chemicals, and other products.
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The invention claimed is: 1. A method for converting oxygenated hydrocarbons to lower molecular weight oxygenated compounds, the method comprising the step of reacting an aqueous feedstock solution with hydrogen, at a temperature of between about 100° C. and about 300° C., in the presence of a heterogeneous catalyst, to produce a reaction product comprising a cyclic ether and one or more oxygenated compounds selected from the group consisting of a polyol, a ketone, an aldehyde, a c…
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