Method to decrease decomposition products in solutions that absorb acidic gases such as carbon dioxide and the like in the presence of oxygen

Patent metadata

Field	Value
Publication number	US-8945280-B2
Application number	US-200913132651-A
Country	US
Kind code	B2
Filing date	Dec 3, 2009
Priority date	Dec 8, 2008
Publication date	Feb 3, 2015
Grant date	Feb 3, 2015

Abstract

An amine solvent solution that is useful in absorbing acid gases from a liquid or gas feed stream may have an amine additive added thereto. Additionally or alternatively, the amine additive may be added to a liquid or gas feed stream. The addition of the amine additive decreases the presence of amine-derived contaminants and/or degradation of amine in the amine solvent solution. As such, the amine solvent solution is available for effective reuse in treating the liquid or gas feed stream and there may be a decrease in the corrosion within an amine treating system.

First claim

What is claimed is:

1. A method comprising:
treating a liquid or gas feed stream with an amine solvent solution having one or more alkanolamines;
adding an amine additive to the amine solvent solution, the liquid or gas feed stream, or both, wherein the amine additive includes tetraethylenepentamine, and wherein the tetraethylenepentamine is selected from the group consisting of: N-(2-aminoethyl)-N′-{2-{(2-aminoethyl)amino}ethyl}-1,2-ethanediamine), 4-(2-aminoethyl)-N-(2-aminoethyl)-N′-{2-{(2-aminoethyl)amino}ethyl}-1,2-ethanediamine), 1-(2-aminoethyl)-4-[[(2-aminoethyl)amino]ethyl]-piperazine), 1-[2-[[(2-aminoethyl)amino]ethyl]-amino]ethyl]-piperazine, and combinations thereof; and
in response thereto, decreasing the presence of an amine-derived contaminant, decreasing degradation of the amine in the amine solvent solution, or both as compared to that which would have occurred in an amine additive-free amine solvent solution, liquid or gas, or both.

2. The method of claim 1 wherein decreasing the presence of an amine-derived contaminant includes decreasing the presence of a heat stable salt, amine-derived degradation product, or both in an amine treating system such that the amine solvent solution containing the amine additive can be regenerated and reused within the amine treating system without requiring fresh amine to be added to replenish the amine solvent solution due to the formation of amine-derived contaminants.

3. The method of claim 2 wherein adding the amine additive to the amine solvent solution, treated liquid or gas, or both includes adding the amine additive to the amine solvent solution, treated liquid or gas, or both at any juncture in the amine treating system.

4. The method of claim 1 wherein adding an amine additive includes adding the amine additive in an amount of from 0.005% to 7% of the total composition of the amine solvent solution and the amine additive.

5. The method of claim 1 wherein adding an amine additive includes adding the amine additive in an amount of from 0.05% to 3% of the total composition of the amine solvent solution and the amine additive.

6. The method of claim 1 wherein adding an amine additive includes adding an amine additive in an amount of from 0.2% to 1% of the total composition of the amine solvent solution and the amine additive.

7. The method of claim 1 , wherein treating a liquid or gas feed stream with an amine solvent solution having one or more alkanolamines includes treating the liquid or gas feed stream with an amine solvent solution selected from the group consisting of: monoethanolamine, diethanolamine, triethanolamine, dimethylethanolamine, N-methyldiethanolamine, monomethylethanolamine, 2-(2-aminoethoxy)ethanol, aminoethylethanolamine, diisopropanolamine, derivatives thereof, and combinations thereof.

8. The method of claim 1 , wherein treating a liquid or gas feed stream with an amine solvent solution includes absorbing acid gases from the liquid or gas feed stream, and wherein adding the amine additive to the amine solvent solution includes adding an amine additive that is an amine degradation inhibitor, amine-derived contaminant inhibitor, or a corrosion inhibitor.

9. The method of claim 1 wherein decreasing the formation of amine-derived contaminants includes decreasing the formation of amine-derived heat-stable salts, amine-derived degradation products, or both.

10. A composition comprising:
an amine additive comprising tetraethylenepentamine, wherein the tetraethylenepentamine is selected from the group consisting of: N-(2-aminoethyl)-N′-{2-{(2-aminoethyl)amino}ethyl}-1,2-ethanediamine), 4-(2-aminoethyl)-N-(2-aminoethyl)-N′-{2-{(2-amino}ethyl}-1,2-ethanediamine), 1-(2-aminoethyl)-4-[[(2-aminoethyl)amino]ethyl]-piperazine), 1-[2-[[(2-aminoethyl)amino]ethyl]-amino]ethyl]-piperazine, and combinations thereof;
an amine solvent solution selected from the group consisting of: monoethanolamine, diethanolamine, triethanolamine, dimethylethanolamine, N-methyldiethanolamine, monomethylethanolamine, 2-(2-aminoethoxy)ethanol, aminoethylethanolamine, diisopropanolamine, derivatives thereof, and combinations thereof; and
water.

11. The composition of claim 10 wherein the amine additive is from 0.05% to 3% of the total composition.

12. The composition of claim 10 wherein the composition is an amine-derived contaminant inhibitor.

13. The composition of claim 10 wherein the composition is an amine degradation inhibitor.

14. The composition of claim 10 , wherein the amine solvent solution includes an amine selected from the group consisting of 2-(2-aminoethoxy)ethanol, methyldiethanolamine, and monoethanolamine.

15. The composition of claim 10 , wherein the amine additive is from 0.05% to 3% of the total composition.

16. The composition of claim 15 , wherein the amine solvent solution includes an amine selected from the group consisting of 2-(2-aminoethoxy)ethanol, methyldiethanolamine, and monoethanolamine.

17. The method of claim 1 , wherein adding an amine additive includes adding the amine additive in an amount of from 0.05% to 3% of the total composition of the amine solvent solution and the amine additive.

18. The method of claim 17 , wherein the one or more alkanolamines is selected from the group consisting of: monoethanolamine, N-methyldiethanolamine, 2-(2-aminoethoxy)ethanol, derivatives thereof, and combinations thereof.

19. A method of treating a feed stream, comprising:
mixing the feed stream with an amine solvent solution having one or more alkanolamines;
adding an amine additive to the amine solvent solution, the feed stream, or both, wherein the amine additive includes a tetraethylenepentamine, and wherein the tetraethylenepentamine is selected from the group consisting of: N-(2-aminoethyl)-N′-{2-{(2-aminoethyl)amino}ethyl}-1,2-ethanediamine), 4-(2-aminoethyl)-N-(2-aminoethyl)-N′-{2-{(2-aminoethyl)amino}ethyl}-1,2-ethanediamine), 1-(2-aminoethyl)-4-[[(2-aminoethyl)amino]ethyl]-piperazine), 1-[2-[[(2-aminoethyl)amino]ethyl]-amino]ethyl]-piperazine, and combinations thereof.

Assignees

• Holub Patrick E
• Grigsby Jr Robert A
• White Larry R
• Critchfield James E
• Huntsman Petrochemical Llc

Inventors

• Holub Patrick E
• Grigsby Jr Robert A
• White Larry R
• Critchfield James E

Classifications

• C02F2103/18

  from the purification of gaseous effluents · CPC title

• C10G2300/207

  Acid gases, e.g. H2S, COS, SO2, HCN · CPC title

• B01D53/1493

  Selection of liquid materials for use as absorbents · CPC title

• B01D2252/606

  Anticorrosion agents · CPC title

• C02F2103/343

  from the pharmaceutical industry, e.g. containing antibiotics · CPC title