Sensitizing complexes, process for the preparation thereof, semiconductive inorganic/organic hybrid material comprising them, and photovoltaic cell comprising said material
US-9196847-B2 · Nov 24, 2015 · US
US8941008B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-8941008-B2 |
| Application number | US-201214003056-A |
| Country | US |
| Kind code | B2 |
| Filing date | Mar 6, 2012 |
| Priority date | Mar 7, 2011 |
| Publication date | Jan 27, 2015 |
| Grant date | Jan 27, 2015 |
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A photoelectric-conversion-device dye comprising a ruthenium metal complex, which includes a molecule including elemental phosphorous and the molecule forms a coordinate bond at least at the phosphorous atom, and which also includes a terpyridine derivative that forms a coordinate bond and has at least one adsorbing group that exhibits adsorptivity toward a metal oxide. The adsorbing group is selected from the group consisting of a carboxylic acid group, an ester thereof, or a salt thereof; a phosphonic acid group, an ester thereof, or a salt thereof; a hydroxyl group; an alkoxy group; and a sulfonic acid group or salt thereof. The dye exhibits absorption over a wide range from the visible light region to the near-infrared region, and as a result, a photoelectric conversion film, an electrode, and a solar cell having improved photoelectric conversion efficiency are provided.
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The invention claimed is: 1. A photoelectric-conversion-device dye comprising: a ruthenium metal complex, which includes a molecule including elemental phosphorus and the molecule forms a coordinate bond at least at the phosphorus atom, and which also includes a terpyridine derivative that forms a coordinate bond and has at least one adsorbing group that exhibits adsorptivity toward a metal oxide wherein the at least one adsorbing group is selected from the group consisting of a…
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