Apparatus for selective deposition of nanotubes, using a charging element, a template and a filter
US-2016368771-A1 · Dec 22, 2016 · US
US8940937B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-8940937-B2 |
| Application number | US-201113577011-A |
| Country | US |
| Kind code | B2 |
| Filing date | Jan 28, 2011 |
| Priority date | Feb 4, 2010 |
| Publication date | Jan 27, 2015 |
| Grant date | Jan 27, 2015 |
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Disclosed is a novel method for the selective molecular conversion of raw material carbon nanotubes containing a mixture of metallic carbon nanotubes and semiconductive carbon nanotubes in a manner that is based on the electrical properties or diameter of the carbon nanotubes. The present invention causes a photoreaction of raw material carbon nanotubes containing a mixture of metallic carbon nanotubes and semiconductive carbon nanotubes with a disulfide or a sulfide of the following formula (I) or (II) (wherein R 1 and R 2 each independently represent a hydrocarbon group that may have a substituent) in an organic solvent that contains the raw material carbon nanotubes and the disulfide of the formula (I) or the sulfide of the formula (II), so as to selectively functionalize the metallic carbon nanotubes, or functionalize the carbon nanotubes diameter selectively.
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The invention claimed is: 1. A method for producing selectively functionalized metallic carbon nanotubes from a raw material carbon nanotubes containing a mixture of metallic carbon nanotubes and semiconductive carbon nanotubes, the method comprising adding a disulfide or a sulfide of the following formula (I) or (II) wherein R 1 and R 2 each independently represent a hydr…
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