Sensitizing complexes, process for the preparation thereof, semiconductive inorganic/organic hybrid material comprising them, and photovoltaic cell comprising said material
US-9196847-B2 · Nov 24, 2015 · US
US8940917B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-8940917-B2 |
| Application number | US-201214005436-A |
| Country | US |
| Kind code | B2 |
| Filing date | Mar 16, 2012 |
| Priority date | Mar 17, 2011 |
| Publication date | Jan 27, 2015 |
| Grant date | Jan 27, 2015 |
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The present invention relates to the ruthenium complexes comprising paracyclophane and carbonyl ligands, methods for the preparation thereof and uses of the complexes in isomerization, hydrogenation, transfer hydrogenation, hydroformylation and carbonylation reactions.
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The invention claimed is: 1. A ruthenium complex of formula (1a), (1b), (1c) or (1d): [Ru Hal 2 L CO S] (1a) [Ru 2 Hal 4 L 2 (CO) 2 ] (1b) [Ru 2 Hal 4 L 2 CO] (1c) [Ru Hal 2 L (CO) 2 ] (1d) wherein: Hal is a halogen ligand, L is a substituted or unsubstituted paracyclophane ligand of formula (2): wherein X 1 and X 2 are linking groups co…
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